| 研究生: |
蘇俊龍 Su, Jun-Long |
|---|---|
| 論文名稱: |
Al.32Ga.68N/GaN異質結構場效電晶體之研製 Investigation and Fabrication of Al.32Ga.68N/GaN Heterostructure Field Effect Transistor |
| 指導教授: |
許渭州
Hsu, Wei-Chou |
| 學位類別: |
碩士 Master |
| 系所名稱: |
電機資訊學院 - 微電子工程研究所 Institute of Microelectronics |
| 論文出版年: | 2004 |
| 畢業學年度: | 92 |
| 語文別: | 中文 |
| 論文頁數: | 63 |
| 中文關鍵詞: | 氮化鋁鎵 、異質結構場效電晶體 |
| 外文關鍵詞: | HFET, GaN, Etch, AlGaN |
| 相關次數: | 點閱:71 下載:10 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本論文中,我們分別利用氯氣、三氯化硼和氬氣的混和氣體作為感應耦合電漿源,對氮化鋁鎵做蝕刻特性探討。首先,我們以氯氣和氬氣的混合氣體作電漿實驗,得到當氯氣和氬氣含量分別為30及10sccm(即3:1)時會有最大蝕刻速率620nm/min,並且在感應耦合電漿功率提高的狀況下,也能獲得較高的蝕刻速率。而在氯氣、三氯化硼和氬氣的混合電漿中,當氯氣含量增加時,能得到較高的蝕刻速率,這是因為在三種混合氣體的蝕刻機制中,氯為主宰蝕刻反應的主要離子,其次為氬離子,最後才是三氯化硼離子。因此,如果想利用較低的蝕刻速率在製程上,可以使用純三氯化硼的電漿,其蝕刻速率為70nm/min。另外,蝕刻表面經過退火後表面粗糙度亦可大幅改善。
此外,我們也成功的製作出氮化鋁鎵異質結構電晶體,並分析其直流和高頻特性。我們磊晶成長了三種不同通道厚度的結構來探討其特性的變化,其中通道厚度分別為1800Å、1500 Å和1200 Å。在直流方面,由於通道厚度1800Å為三者中最大所以通道內載子量為最多,使得其在三者中擁有最大飽和電流密度160mA/mm和最高轉導74mS/mm。我們也利用了嵌入埋藏鎂摻雜氮化鎵和氮化鋁鎵來做絕緣層以降低漏電流的發生,因此而得到相當好的截止特性。高頻特性方面,1800Å和1500Å結構的單一增益截止頻率分別為1.82GHz和1.69GHz。另外我們也做了一組變溫的量測,發現隨著溫度升高,轉導值和飽和電流都會因為高溫造成雜質散射效應降低了電子移動率而下降。不過當溫度達200oC時,仍保有很好的電晶體特性且轉導值仍有48mS/mm,證明這材料適於高溫的應用。
In this thesis, we utilized Cl2, BCl3 and Ar mixtures as the inductively coupled plasma source to research the etching characteristics of AlGaN. At first, we used Cl2 and Ar mixtures as inductively coupled plasma, and we obtained the result that the highest etching rate 620nm/min can be got when the flow rate Cl2 : Ar = 30 : 10 sccm (3:1). Furthermore, we can get higher etching rate at higher ICP power. Besides, in the Cl2, BCl3 and Ar mixed plasma, the ratio of Cl2 increase, the higher etching rate can be obtained. This is because during the etching mechanism of the three mixed plasma, the dominant ion of the whole etching reaction is Cl, the next is Ar, and BCl3 is the weakest in the reaction. Therefore, if someone wants to make use of the lower etching rate in fabrication process, the pure BCl3 plasma is a very good choice, and the etching rate is about 70nm/min. In addition, the surface roughness of the etched samples can be substantially improved after RTA annealing.
Besides, we have successfully fabricated the AlGaN/GaN heterostructure field effect transistor and analyzed the DC and RF characteristics. We grew three kinds of heterostructures with different channel thickness to discuss the characteristic variations of them. In DC characteristics, the maximum drain current density (Idss) 160mA/mm and the highest transconductance (Gm Max) 74 mS/mm can be obtained in the structure of channel thickness 1800Å. In addition, we inserted the Mg-doped insulating GaN layer to eliminate the leakage current. In RF characteristics, the unity gain cut-off frequency of structure 1800Å and 1500Å are 1.82GHz and 1.69GHz, respectively. Moreover, we also measured the DC characteristics at different temperatures and found that transconductance and drain current density decreased with the increase of temperatures. However, the device can still normally operate at 200oC with transconductance 48mS/mm. It proves that this material suits the applications at high temperature.
[1]. M. A. Khan, Q. Chen, J. W. Yang, M. S. Shur, B. T. Dermott, and J. A. Hinggins, “Microwave operation of GaN/AlGaN-doped channel heterostructure field effect transistors,” IEEE Electron Device Lett., vol. 17, pp. 325, 1996.
[2]. Y. F. Wu, B. P. Keller, P. Fini, S. Keller, T. J. Jenkins, L. T. Kehias, S. P. Denbaars, and U. K. Mishra, “High Al-content AlGaN/GaN MODFET’s for ultrahigh performance,” IEEE Electron Device Lett., vol. 19, pp. 50, 1998.
[3]. C. H. Chen, S. Keller, G. Parish, R. Vetury, P. Kozodoy, E. L. Hu, S. P. Denbaars, and U. K. Mishra, “High-transconductance self-aligned AlGaN/GaN modulation -doped field-effect transistors with regrown ohmic contacts,” Appl. Phys. Lett., vol. 73, pp. 3147, 1998.
[4]. R. Li, S. J. Cai, L. Wong, Y. Chen, K. L. Wang, R. P. Smith, S. C. Martin, K. S. Boutros, and J. M. Redwing, “An AlxGa1-xN/GaN undoped channel hetero- structure field effect transistor with F of 107 GHz,” IEEE Electron Device Lett., vol. 20, pp. 323, 1999.
[5]. J. M. Redwing, M. A. Tischler, J. S. Flynn, S. Elhamri, M. Ahoujja, R. S. Newrock, and W. C. Mitchel, “Two-dimensional electron gas properties of AlGaN/GaN heterostructures grown on 6H-SiC and sapphire substrates,” Appl. Phys. Lett., vol. 69, pp. 963, 1996.
[6]. X. A. Cao, H. Cho, S. J. Pearton, G. T. Dang, A. P. Zhang, F. Ren, R. J. Shul, L. Zhang, R. Hickman, and J. M. Van Hove, “Depth and thermal stability of dry etch damage in GaN Schottky diodes,” Appl. Phys. Lett., vol. 75, pp. 232, 1999.
[7]. J. M. Lee, K. M. Chang, S. W. Kim, C. Huh, I. H. Lee, and S. J. Park, “Dry etch damage in n-type GaN and its recovery by treatment with an N2 plasma,” J. Appl. Phys., vol. 87, pp. 7667, 2000.
[8]. D. G. Kent, K. P. Lee, A. P. Zhang, B. Luo, M. E. Overberg, C. R. Abernathy, F. Ren, K. D. Mackenzie, S. J. Pearton, and Y. Nakagawa, “Electrical effects of N2 plasma exposure on dry-etchdamage in p- and n-GaN Schottky diodes,” Solid-State Electron., vol. 45, pp. 1837, 2001.
[9]. D. G. Kent, K. P. Lee, A. P. Zhang, B. Luo, M. E. Overberg, C. R. Abernathy, F. Ren, K. D. Mackenzie, S. J. Pearton, and Y. Nakagawa, “Effect of N2 plasma treatments on dry etch damage in n- and p-type GaN,” Solid-State Electron., vol. 45, pp. 467, 2001.
[10]. J. Y. Chen, C. J. Pan, and G. C. Chi, “Electrical and optical changes in the near surface of reactively ion etched n-GaN,” Solid-State Electron., vol. 43, pp. 649, 1999.
[11]. B. Rong, R. J. Reeves, S. A. Brown, M. M. Alkaisi, E. van , R. Cheung, and W. G. Sloof, “A study of reactive ion etching damage effects in GaN,” Microelectron. Eng., vol. 57, pp. 585, 2001.
[12]. B. Molnar, C. R. Eddy Jr., and K. Doverspike, “The influence of CH4/H2/Ar plasma etching on the n-type gallium nitride,” J. Appl. Phys., vol. 78, pp. 6132, 1995.
[13]. I. Adessida, A. Mahajan, E. Andideh, M. A. Kahn, D. T. Olson, and J. N. Kuznia, “Reactive ion etching of gallium nitride in silicon tetrachloride plasmas,” Appl. Phys. Lett., vol. 63, pp. 2777, 1993.
[14]. R. J. Shul, G. B. McClellan, S. A. Casalnuovo, and D. J. Rieger, “Inductively coupled plasma etching of GaN,” Appl. Phys. Lett., vol. 69, pp. 1119, 1996.
[15]. C. F. Zhu, W. K. Fong, B. H. Leung, C. C. Cheng, and C. Surya “Effects of Rapid Thermal Annealing on the Structural Properties of GaN Thin Films,” IEEE Trans. Electron Devices, vol. 48, pp. 1225, 2001.
[16]. S. J. Cai, Y. S. Tang, R. Li, Y. Y. Wei, L. Wong, Y. L. Chen, K. L. Wang, M. Chen, Y. F. Zhao, R. D. Schrimpf, J. C. Keay, and K. F. Galloway “Annealing Behavior of a Proton Irradiated AlxGa1-xN/GaN High Electron Mobility Transistor Grown by MBE,” IEEE Trans. Electron Devices, vol. 47, no. 304, 2000.
[17]. S. T. Pearton, and C.R. Abernathy, “Low bias electron cyclotron resonance plasma etching of GaN, AIN, and InN,” Appl. Phys. Lett., vol. 87, pp. 7667, 2000.
[18]. X. A. Cao, H. Cho, S. J. Pearton, G. T. Dang, A. P. Zhang, F. Ren, R. J. Shul, L. Zhang, R. Hickman, and J. M. Van Hove “Depth and thermal stability of dry etch damage in GaN Schottky diodes,” Appl. Phys. Lett., vol. 75, pp. 232, 1999.
[19]. J. M. Lee, K. M. Chang, S. W. Kim, C. Huh, I. H. Lee, and S. J. Park, “Dry etch damage in n-type GaN and its recovery by treatment with an N2 plasma,” J. Appl. Phys., vol. 87, pp. 7667, 2000.
[20]. D. G. Kent, K. P. Lee, A. P. Zhang, B. Luo, M. E. Overberg, C. R. Abernathy, F. Ren, K. D. Mackenzie, S. J. Pearton, and Y. Nakagawa, “Effect of N2 plasma treatments on dry etch damage in n- and p-type GaN,” Solid-State Electron., vol. 45, pp. 467, 2001.
[21]. J. Y. Chen, C. J. Pan, and G. C. Chi, “Electrical and optical changes in the near surface of reactively ion etched n-GaN,” Solid-State Electron., vol. 43, pp. 649, 1999.
[22]. B. Rong, R. J. Reeves, S. A. Brown, M. M. Alkaisi, E. van , R. Cheung, and W. G. Sloof, “A study of reactive ion etching damage effects in GaN,” Microelectron. Eng., vol. 57, pp. 585, 2001.
[23]. B. Molnar, C. R. Eddy Jr., and K. Doverspike, “The influence of CH4/H2/Ar plasma etching on the n-type gallium nitride,” J. Appl. Phys., vol. 78, pp. 6132, 1995.
[24]. B. H. Lee, S. D. Lee, S. D. Kim, I. S. Hwang, H. C. Park, H. M. Park, and J. Rhee, J. Electrochem. Soc., vol. 148, pp. 592, 2001.
[25]. M. A. Khan, Q. Chen, J. W. Yang, M. S. Shur, B. T. Dermott, and J. A. Hinggins, “Microwave operation of GaN/AlGaN-doped channel heterostructure field effect transistors,” IEEE Electron Device Lett., vol. 17, pp. 325, 1996.
[26]. A. Ozgur, W. Kim, Z. Fan, A. Botchkarev, A Salvador, S. N. Mohammad, B. Sverdlov, and H.Morkoc, “ High transconductance-nomally-off GaN MODFETs,” Electron. Lett., vol. 31, pp. 1389, 1995.
[27]. W. Q. Chen and S. K.Hark “Strain-induced effects in (111)-oriented InAsP/InP, InGaAs/InAlAs quantum wells on InP substrates,” J. Appl. Phys., vol. 77, pp. 5747, 1995.
[28]. A. Bykhovski, B. L. Gelmont, and M. S. shur “Elastic strain relaxation and piezoeffect in GaN-AlN, GaN-AlGaN and GaN-InGaN superlattices,” J. Appl. Phys., J. Appl. Phys., vol. 81, pp. 6332, 1997.
[29]. J. M. Redwing, M. A. Tischler, J. S. Flynn, S. Elhamri, M. Ahoujja, R. S. Newrock, and W. C. Mitchel, “Two-dimensional electron gas properties of AlGaN/GaN heterostructures grown on 6H-SiC and sapphire substrates,” Appl. Phys. Lett., vol. 69, pp. 963, 1996.
[30]. S. Arulkumaran, M. Sakai, T. Egawa. H. Ishikawa, and Jimbo “Improved dc characteristics of AlGaN/GaN high-electron-mobility transistors on AlN/sapphire templates,” Appl. Phys. Lett., vol. 81, pp. 1131, 2002.
[31]. T. Egawa, G. Y. Zhao, H. Ishikawa, M. Umeno, and T. Jimbo “Characterizations of Recessed Gate AlGaN/GaN HEMTs on Sapphire,” IEEE Trans. Electron Devices, vol. 48, pp. 603, 2001.
[32]. 國立成功大學碩士論文 ”Investigation and Fabrication of AlGaN/GaN MODFET by ICP System” by Tzu-hsuan Hsu.