本研究以電紡絲法噴覆銀前驅物/高分子複合電紡絲，再搭配後處理製程來製備銀網狀結構透明導電薄膜，銀前驅物為三氟醋酸銀(silver trifluoroacetate, STA)，高分子為聚甲基丙烯酸甲酯(poly(methyl methacrylate), PMMA)，而後處理有三種，分別為熱處理法(thermal treatment)、紫外光處理法(UV treatment)與無電鍍(electroless plating)銀法。
以熱處理法製備透明導電薄膜，加熱有兩階段，第一階段為100oC，促使纖維中銀奈米顆粒的熱還原，第二階段為500oC，引發了PMMA高分子的熱裂解與銀奈米顆粒的燒結。以熱處理製作之透明導電薄膜，穿透度與高分子濃度以及銀前驅物摻雜量有關，高分子濃度、銀前驅物摻雜量越低，穿透度越高；而片電阻與熱裂解氣氛以及銀前驅物摻雜量有關，在保護氣氛下、高銀前驅物摻雜時，可得較低的片電阻。當PMMA為15 wt%、Ag/PMMA重量比為0.7、氮氣氣氛下熱處理時，可得片電阻為1000 Ω/sq、穿透度63%的銀網狀結構透明導電薄膜。
以紫外光處理法製備透明導電薄膜，紫外光之照射不僅可光裂解PMMA，也可同時光還原纖維中的銀奈米顆粒並使其堆疊成一維導電路徑。以紫外光處理法製作之透明導電薄膜，片電阻與紫外光照射時間以及銀前驅物摻雜量有關，照射時間越短、摻雜量越低，穿透度越高；而片電阻亦與紫外光照射時間以及銀前驅物摻雜量有關，照射時間越長、摻雜量越高，片電阻越低。當PMMA濃度為15 wt%、Ag/PMMA重量比為0.5、照射時間為120分鐘時，可得片電阻500 Ω/sq、穿透度83.0%的銀網狀結構透明導電薄膜。此外本研究調查銀還原與PMMA裂解的機制，顯示銀奈米顆粒在極短的時間內還原於纖維中，並隨照射時間增加有集中於纖維中心的趨勢，亦發現短時間的紫外光照射即可使PMMA有效率的光裂解。
以無電鍍法製備透明導電薄膜，概念為在PMMA纖維表面無電鍍沉積銀薄膜，藉由可溶性基板的使用，改善無電鍍銀非選擇性沉積特性的影響，使銀顆粒僅生成於PMMA電紡絲表面，並藉由奈米銀晶種嵌於PMMA纖維表面的輔助，增進無電鍍銀沉積均勻性。最終可製備片電阻260 Ω/sq、穿透度為80.0%的的銀網狀結構透明導電薄膜。此薄膜承受一萬週期之反覆撓曲後，其片電阻值變化率僅60.5%，而經150℃、150小時與90℃、250小時的溫度測試，其前後片電阻值比例皆小於1.3。

Silver networks with high transmittance and low sheet resistance were prepared via a polymer-assisted electrospinning technique and several post treatments, including thermal, ultraviolet, and electroless plating processes. Nonaqueous media containing poly(methyl methacrylate) (PMMA) and silver trifluoroacetate (STA) were formulated as polymer/metal electrospinning precursor. Nanofibers randomly deposited on substrates formed a plane scaffold, which served as the raw material for silver networks. Post treatments not only reduced the STA precursors to silver nanoparticles (Ag NPs), but also triggered connection of the Ag NPs into a one-dimensional (1D) domain. Silver fibers formed continuous conducting networks on the substrate surface. The sheet resistances and optical transmittance of these silver networks revealed strong correlations with the original STA/PMMA ratios and with the silver network morphologies. The material fabrication was carefully investigated, and the fiber morphologies, electrical and optical properties as well as bending reliability of the products were examined.

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