| 研究生: |
廖繼滄 Liaw, Jih-Tsang |
|---|---|
| 論文名稱: |
鈮酸鋰、鈮酸鈉、鈮酸鉀陶瓷系列之研製 及其特性探討 The Fabrication of LiNbO3, NaNbO3, KNbO3 Based Ceramics and Investigation of Their Characteristics |
| 指導教授: |
朱聖緣
Chu, Sheng-Yuan |
| 學位類別: |
碩士 Master |
| 系所名稱: |
電機資訊學院 - 電機工程學系 Department of Electrical Engineering |
| 論文出版年: | 2002 |
| 畢業學年度: | 90 |
| 語文別: | 中文 |
| 論文頁數: | 91 |
| 中文關鍵詞: | 鈮酸鋰 、鈮酸鈉 、鈮酸鉀 |
| 外文關鍵詞: | NaNbO3, KNbO3, LiNbO3 |
| 相關次數: | 點閱:94 下載:2 |
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鈮酸鉀為一強電性之鈣鈦礦結構材料,在製作其陶瓷體時,由於其燒結溫度需接近其熔點之高溫(1054℃),在此高溫時造成大量氧化鉀的揮發而使其不易燒結,因此我們可藉由摻雜少量鋰作為助熔劑降低其燒結溫度助其燒結,並就此一鈮酸鋰鉀系列之陶瓷體做其物性及電性分析。
鈮酸鈉為一反強電性材料,在此我們將之與強電性之鈮酸鉀組成鈮酸鉀鈉之多元之陶瓷體,實驗結果顯示在鈉與鋰為1:1時,可得到高達34.55%之徑向振動耦合因數。
最後我們將由前兩多元系統結果中,試圖研製綜合二者優點之多元陶瓷體,並就其壓電特性做一討論。
Potassium niobate (KNbO3) is a ferroelectric material of perovskite structure. However, it is difficult to synthesize pure KNbO3 ceramics since the sintering temperature (1054˚C) is very close to the melting point of KNbO3 ceramics that causes severe volatilization of K2O. Li dopant is introduced as an additive, which forms liquid phase to help to reduce the sintering temperature. Characteristics of material and electrical properties of the Lithium potassium niobate (LixK1-xNbO3) ceramics are investigated.
Sodium niobate (NaNbO3) is an antiferroelectric material. In the second phase of our research, we introduce Sodium niobate in the Potassium niobate system to form Sodium Potassium niobate (NaxK1-xNbO3) ceramics. According to our experimental results, high radial coupling coefficients (34.55%) are obtained for the compound having up to 50mol% sodium niobate.
Finally, the ternary system that mixes Lithium potassium niobate and Sodium Potassium niobate ceramic is introduced. The characteristics of the piezoelectric property are investigated, also.
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