簡易檢索 / 詳目顯示

研究生: 李國輝
Li, Guo-Hui
論文名稱: MIS結構電容添加Mn之BaxSr1-xTiO3高介電薄膜之製備與特性分析
Fabrication and Analysis of Mn-doped(BaxSr1-x)TiO3 Thin Film Used as the Insulating Layer for MIS Structure Capacitors
指導教授: 李炳鈞
Li, Bing-Jing
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年: 2007
畢業學年度: 95
語文別: 中文
論文頁數: 105
中文關鍵詞: 電容薄膜
外文關鍵詞: capacitor, thin film
相關次數: 點閱:49下載:4
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 在半導體的發展過程中,為了增加元件的速度及效能,使得元件必須不斷縮小尺寸,二氧化矽絕緣層厚度則將微縮至奈米左右,而產生漏電流大量增加使遷移率降低的問題,為了維持電性不變採用高介電係數材料作為絕緣層,降低因微縮帶來的漏電流問題。
    隨本論文採用濺鍍法製作MIS 電容,薄膜沉積分別討論五種情況,分別為不同基板溫度、不同濺鍍功率、不同通氣(OMR= Ar2/(O2 +Ar2))比例、BST 薄膜添加錳的影響、及回火所造成的影響,製作出MIS 電容。實驗中發現OMR 為0.5(氬:氧=6:6)腔體壓力10m torr、濺鍍功率100 瓦、機板溫度550 度具有最佳的特性,漏電流值約為0.41uA/cm2(at 5V)。在薄膜添加錳後,討論錳添加量對於薄膜電性影響,測結果發現,隨錳含量的增加,使薄膜表面粗糙度降低,有助於薄膜緻密性,在電性方面量測的結果,則會使漏電流因此降低,其中在1Wt%時所製作出的MIS 電容有最低的漏電流88.5n A/cm2(at 5V),並由回火650 度得到最低之漏電流62.3n A/cm2(at 5V)。

    During developing semiconductor process, the IC must scaling size for enchance IC velocity and affect .The SiO2 insulator layer will scale to narosize . Because the leakeage current becomes large , IC mobilty decreases and current drive is not enough to push next cuircuit. The insulator layer uses high k to reduce scaling size current
    problem.The deposited method in thesis was adopted the R.F. supptering .The thesis discusses five diffrence type of BST thin films deposition. It are variable deposited
    temperture、variable deposited power、variable OMR、variable dopped manganese on BST thin film、and anneling temperture of the BST thin film. In the only BST thin
    film discussion, the bast electric charateristic is OMR(Ar:O2=6:6)that I measure ; on the contrary , although in the fewer O2 concentration was deposted vary fast , the BST thin film which dielectric content and leakage currence was poor . Dopping Mn in the thin film was found when it increases Mn to decrease rms and enhace
    deposition quality . So we discussed dopping Mn on thin film and oxygen vacancies , relation. Afrer dopping 1wt% Mn ,and leakage current was 8.85E-8 A/cm2,and used
    annealing to get the best leakage current 6.23E-8 A/cm2.

    第一章 序論 1 1-1-1DRAM發展 1 1-2研究動機與目的 3 1-3預期目標 4 第二章 文獻探討及相關理論 8 2-1高介電材料 8 2-1-1簡介 8 2-1-2介電效應 8 2-1-3半導體製程之絕緣層材料 11 2-1-4添加物的影響 16 2-2電容結構 19 2-2-1 MIS堆疊結構 19 2-3量測理論 21 2-3-1 C-V簡介: 21 2-3-2 I-V量測: 23 2-3-3介電損(Dissipation factor,DF): 26 2-3-4 AFM原子力顯微鏡: 27 2-3-5 X-ray: 27 2-3-6掃描式電子顯微鏡: 28 2-4回火 29 第三章 實驗程序與量測方法 30 3-1元件結構 30 3-2製作流程 30 第四章 實驗結果與討論 37 4-1 比較不同濺鍍功率 37 4-2 基板溫度對BST薄膜生長之影響探討 51 4-3 比較不同氣體流量 60 4-4 比較不同錳添加比例 70 4-5回火 80 4-6綜合討論實驗結果與文獻比較 90 第五章 結論與未來展望 91 參考文獻 93 附錄 97

    [1]"International Technology Roadmap For Semiconductor, 2004 Update, Process Integration, Devices, and Structure," <http://www.itrs.net/Links/2004Update/2004_03_PIDS.pdf>, 2004).
    [2]M. Daisaburo Takashima, IEEE and H. Nakano, "Cell Transistor Scalable DRAM Array Architecture," IEEE JOURNAL OF SOLID-STATE CIRCUITS, vol. 37, pp. 587-592, 2002.
    [3]A. I. Kingon, J.-P. Maria, and S. K. Streiffer, "Alternative dielectrics to silicon dioxide for memory and logic devices," Nature, vol. 406, pp. 1032-1038, 2000.
    [4]魏炯權, 電子陶瓷材料: 全華科技圖書股份有限公司, 2004.
    [5]魏炯權, 電子材料工程: 全華科技圖書股份有限公司, 2005.
    [6]吳泰伯, "電子材料, 清華大學.
    [7]李建財, "鉭電極與鈦酸鍶鋇薄膜電容之可靠性與製程整合研究, 交通大學, 2005.
    [8]S. Ezhilvalavan and T.-Y. Tseng, "Progress in the developments of (Ba,Sr)TiO3 (BST) thin films for Gigabit era DRAMs," Materials Chemistry and Physics, vol. 65, pp. 227-248, 2000.
    [9]T. Hu, T. J. Price, D. M. Iddles, A. Uusim¨aki, and H. Janunen, "The effect of Mn on the microstructure and properties of BaSrTiO3 with B2O3–Li2CO3," Journal of the European Ceramic Society, vol. 25, pp. 2531-2535, 2005.
    [10]D.-K. Lee, H.-I. Yoo, and K. D. Becker, "Nonstoichiometry and defect structure of Mn-doped BaTiO3-d," Solid State Ionics, vol. 154-155, pp. 189-193, 2002.
    [11]C. S. Hwang, "(BaSr)TiO3 thin films for ultra large scale dynamic random access menory.A review on the process intergation," Materials science and Engineering vol. B56, pp. 178-190, 1998.
    [12]A. I. Kingon, J.-P. Maria, and S. K. Streiffer, "Alternative dielectrics to silicon dioxide for memory and logic devices," Nature, vol. 406, pp. 1032-1040, 2000.
    [13]J. Robertson and C. W. Chen, "Schottky barrier heights of tantalum oxide, barium strontium titanate lead titanate and strontium bismuth tantalate," APPLIED PHYSICS LETTERS, vol. 74, pp. 1168-1170, 1999.
    [14]Y.-B. Chen and C.-L. Huang, "Properties of MgTiO3 thin films prepared by RF magnetron sputtering for microwave application," Journal of Crystal Growth, vol. 282, 2005.
    [15]陳逸書, "以稀土元素Y2O3為金氧半場效電晶體閘極氧化層之研究, 中原大學, 2002.
    [16]J. S. LEE, S. C. SUN, S. J. CHANG, J. F. CHEN, C. H. LIU, and U. H. LIAW3, "Effects of Interfacial Oxide Layer for the Ta2O5 Capacitor After High-Temperature Annealing," Jpn. J. Appl. Phys., vol. 41, pp. 690-693, 2002.
    [17]J. S. Lee, S. J. Chang, J. F. Chena, S. C. Sun, C. H. Liu, and U. H. Liawd, "Effects of O2 thermal annealing on the properties of CVD Ta2O5 thin films," Materials Chemistry and Physics, vol. 77, pp. 242-247, 2001.
    [18]M. Stephen A. Campbell, IEEE, D. C. Gilmer, X.-c. Wang, M.-t. Hsieh, H.-S. Kim, W. L. Gladfelter, and M. Jinhua Yan, IEEE, "MOSFET Transistors Fabricated with High Permitivity TiO2 Dielectrics," IEEE TRANSACTIONS ON ELECTRON DEVICES,, vol. 44, pp. 104-110, 1997.
    [19]R. B. v. Dovera, "Amorphous lanthanide-doped TiOx dielectric films," APPLIED PHYSICS LETTERS, vol. 74, pp. 3041-3044, 1999.
    [20]Y. Tarui, T. Hirai, K. Teramoto, and H. Koike, "Application of the ferroelectric materials to ULSI memories," Applied surface Science, vol. 113-114, pp. 656-663, 1997.
    [21]P. C. Fazan, "Trends in the development of ULSI DRAM capacitors " Integrated Ferroelectrics, vol. 4, pp. 247-256, 1994.
    [22]K. ABE and S. Komatsu, "Epitaxial Growth of SrTiO3 Films on Pt electrodes and Their Electrial Properties," Jpn. J. Appl. Phys., vol. 31, pp. 2985-2988, 1992.
    [23]史德智, "低溫製程技術應用於動態隨機存取記憶體之鈦酸鍶鋇薄膜電容器之研究, 交通大學, 2005.
    [24]B. Jaffe, W. R. Cook, and H.CJaffe, Piezoelectric ceramics. India 1971.
    [25]王祥明, "應用於Giga-bit 奈米級DRAM的BST高介電薄膜研究, 雲林科技大學, 2004.
    [26]蔡昀達, "以氧電漿處理於建度成長鈦酸鍶鋇薄膜之研究, 雲林科技大學, 2003.
    [27]H.-I. Yoo and C.-R. Song, "Defect structure and chemical diffusion in BaTiO3-d," Solid State Ionics, vol. 135, pp. 619-623, 2000.
    [28]D.-K. Lee and H.-I. Yoo, "Oxygen nonstoichiometry of undoped BaTiO3-d," Solid State Ionics, vol. 144, pp. 87-97, 2001.
    [29]Y.-K. Sun and S.-H. Jin, "Synthesis and electrochemical characteristics of spinel phase LiMn2O4-based cathode materials for lithium polymer batteries," J. Mater. Chem., vol. 8, pp. 2399-2404, 1998.
    [30]H.-W. Wang, S.-W. Nien, K.-C. Lee, and M.-C. Wu, "Improvement in crystallization and electrical properties of barium strontium titanate thin films by gold doping using metal-organic deposition method," Thin Solid Films, vol. 489, pp. 31-36, 2005.
    [31]A. Srivastava, D. Kumar, and R. K. Singh, "Improvement in electrical and dielectric behavior of „Ba,Sr…TiO3 thin films by Ag doping," PHYSICAL REVIEW B, vol. 61, pp. 7305-7308, 2000.
    [32]D.-K. Lee, H.-I. Yoo, and K. D. Becker, "Nonstoichiometry and defect structure of Mn-doped BaTiO3 " Solid State Ionics, vol. 154-155, pp. 189-193, 2002.
    [33]P. C. Joshi, S. Ramanathan, S. B. Desu, S. Stowell, and S. Sengupta, "CHARACTERIZATION OF Ba0.6Sr0.4TiO3 THIN FILMS WITH Mg ADDITIVE FABRICATED BY METALORGANIC DECOMPOSITION TECHNIQUE," Integrated Ferroelectrics, vol. 19, pp. 141-148, 1998.
    [34]K.-T. Kim and C.-I. Kim, "Electrical and dielectric properties of Ce-doped Ba0.6Sr0.4TiO3 thin films," Surface & Coatings Technology, vol. 200, pp. 4708-4712, 2006.
    [35]C. Fitz, M. Goldbach, A. Dupont, and S. Schmidbauer, "Silicides as contact material for DRAM applications," Microelectronic Engineering, vol. 82, pp. 460-466, 2005.
    [36]T. Horikawa, T. Makita, T. Kurorwa, and N. Mikami, "Dielectric Relaxation of (Ba,Sr)TiO3 films," Jpn. J. Appl. Phys., vol. 34, pp. 5478-5482, 1195.
    [37]Y. Fukuda, K. Aoki, K. Numata, and A. Nishimura, "Current-Voltage Characteristics of Electron-Cyclotron-Resonance Sputtering-Deposited SrTiO3 Thin Films," Jpn. J. Appl. Phys., vol. 33, pp. 5255-5258, 1994.
    [38]C. S. Hwang, B. T. Lee, C. S. Kang, K. H. Lee, H.-J. Cho, H. Hideki, W. D. K. I. Lee, and M. Y. Lee, "Depletion layer thickness and Schottky type carrier injection at the interface between Pt electrodes and BaSrTiO3 thin films," JOURNAL OF APPLIED PHYSICS, vol. 85, pp. 287-296, 1999.
    [39]陳毅驊, "以Y2O3為矽閘極介電層之金氧半特性之研究, 中原大學, 2003.
    [40]蔡伩哲, "以高介電值材料作為矽基板上閘極介電層之研製與特性分析, 中原大學, 2004.
    [41]S. M. Sze, Physics of Semiconductor Devices: John Wiley and Sons, P442, 1983.
    [42]蔡明憲, "以RF磁控濺鍍法研制高品質的(TiO2)-(TaO5)薄膜之研製," 碩士論文, 雲林科技大學, 2002.
    [43]G. W. Dietz and R. Waser, "Charge injection in SrTiO3 thin films," Thin Solid Films, vol. 299, pp. 53-58, 1997.
    [44]M. S. Tsai, S. C. Sun, and T. Y. Tseng, "Effect of oxygen to argon ratio on properties of (Ba,Sr)TiO3 thin films prepared by radio-frequency magnetron sputtering," J. Appl. Phys., vol. 82, pp. 3482-3488, 1997.
    [45]楊天賜, "Fe3+摻雜對TiO2薄膜的顯微組織與光學性質的影響, 聯合大學, 2005.

    下載圖示 校內:2009-07-24公開
    校外:2012-07-24公開
    QR CODE