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研究生: 陳榮晉
Chen, Jung-Chin
論文名稱: (Mg1-xM2+x)4Nb2O9 (M = Co、Ni) 微波介電材料之研究與應用
Study and Applications of (Mg1-xM2+x)4Nb2O9 (M = Co、Ni) Microwave Dielectric Materials
指導教授: 黃正亮
Huang, Cheng-Liang
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年: 2009
畢業學年度: 97
語文別: 中文
論文頁數: 116
中文關鍵詞: 微波陶瓷
外文關鍵詞: ceramic, microwave
相關次數: 點閱:65下載:0
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  • 在本論文中首先將探討以 (Mg1-xM2+x)4Nb2O9 (M = Co、Ni)的微波介電特性及材料的微結構。由實驗結果可知 (Mg1-xCox)4Nb2O9與 (Mg1-xNix)4Nb2O9在燒結溫度 1340℃持溫4小時可得到最佳之介電特性。當M = Co且x = 0.04時,可得到 (Mg1-xCox)4Nb2O9之最佳介電特性 εr = 12.79,Q׃ = 235000 GHz (at 11.82GHz), τƒ = -63.93 ppm/℃。當M = Ni且x = 0.05時,可得到 (Mg1-xNix)4Nb2O9的最佳介電特性 εr = 12.55,Q׃ = 233000 GHz (at 12.27 GHz),τƒ = -68.56 ppm/℃。為了實現材料的溫度穩定性,我們在 (Mg0.96Co0.04)4Nb2O9與 (Mg0.95Ni0.05)4Nb2O9微波介電材料中選擇添加 為正值的 SrTiO3 (εr ~ 205、Q׃ ~ 4200GHz、τƒ~ +1700ppm/℃)[1]。
    此外,本論文將分別以 FR4、 Al2O3及 0.6(Mg0.96Co0.04)4Nb2O9-0.4SrTiO3作為基板來設計一曲折式步階阻抗帶通濾波器,濾波器的規格為:中心頻率 2.4GHz、頻寬為 6%,並使用電磁模擬軟體 HFSS來進行電腦模擬。

    Frist, the microwave dielectric properties and the microstructures (Mg1-xM2+x)4Nb2O9 (M = Co、Ni) were investigated in this paper. The experiment results show that (Mg1-xCox)4Nb2O9 and (Mg1-xNix)4Nb2O9 have the best properties at sintering temperature 1340℃ for four hours. When M = Co and x = 0.04, we can obtain the best dielectric propertyes of (Mg1-xCox)4Nb2O9: εr = 12.79, Q׃ = 235000 GHz (at 11.82GHz), τƒ = -63.93 ppm/℃. With M = Ni and x = 0.05, the best dielectric properties εr = 12.55, Q׃ = 233000 GHz (at 12.27GHz), τƒ = -68.56 ppm/℃ were obtained for (Mg1-xNix)4Nb2O9. In order to achieve a temperature-stable material, we choose to add the positive temperature-coefficient material SrTiO3 (εr ~ 205、Q׃ ~ 4200 GHz、 τƒ ~ +1700 ppm/℃) to (Mg0.96Co0.04)4Nb2O9 and (Mg0.95Ni0.05)4Nb2O9 microwave dielectric materials.
    Besides, a bandpass filter using meandering stepped impedance resonators have been designed on FR4、Al2O3 and 0.6(Mg0.96Co0.04)4Nb2O9-0.4SrTiO3 substrates. The band-pass frequency is 2.4GHz, the bandwidth is 6% and simulated by electromagnetic simulation software, HFSS.

    摘要.................................................................................................................I Abstract........................................................................................................II 誌謝..............................................................................................................IV 目錄..............................................................................................................VI 表目錄..........................................................................................................IX 圖目錄...........................................................................................................X 第一章 緒論................................................................................................1 1-1 前言.....................................................................................................................1 1-2 研究目的.............................................................................................................1 第二章 介電材料原理................................................................................3 2-1微波陶瓷材料之介電特性分析...........................................................................3 2-1-1 介電常數(Dielectric constant:K、εr)..................................................3 2-1-2 介電品質因數(Quality factor:Q).........................................................6 2-1-3 共振頻率之溫度係數(τƒ).....................................................................8 2-2 介電共振器(Dielectric Resonator, DR)原理....................................................9 2-3 燒結原理...........................................................................................................12 2-3-1 燒結的種類............................................................................................12 2-3-2 液相燒結理論........................................................................................14 2-3-3 陶瓷體燒結的三過程............................................................................15 2-4 Corundum結構.................................................................................................16 2-5 鈣鈦礦之結構...................................................................................................19 第三章 微帶線及濾波器之原理..............................................................20 3-1 濾波器簡介.......................................................................................................20 3-2 微帶線原理.......................................................................................................23 3-2-1 微帶傳輸線及其傳輸組態....................................................................23 3-2-2 微帶線各項參數公式計算及考量........................................................24 3-3 微帶線諧振器種類...........................................................................................31 3-4 共振器間的耦合形式.......................................................................................34 3-4-1 電場耦合................................................................................................35 3-4-2 磁場耦合................................................................................................38 3-4-3 混和耦合................................................................................................41 3-5 諧振器間耦合量...............................................................................................43 3-6 基本步階阻抗諧振器.......................................................................................44 3-7 曲折式步階阻抗帶通濾波器...........................................................................46 3-7-1 Dual-finger饋入結構.............................................................................47 3-7-2 阻抗比(K=Z2/Z1)的影響..................................................................48 3-7-3 長度比的影響........................................................................................49 3-7-4 間隙(spacing)g1之變化的影響............................................................51 第四章 實驗程序與量測方法..................................................................53 4-1 微波介電材料的製備.......................................................................................53 4-1-1 原始粉末之配置與球磨........................................................................53 4-1-2 煆燒成相................................................................................................53 4-1-3 壓模........................................................................................................53 4-1-4 燒結........................................................................................................54 4-2 微波介電材料的特性分析與量測...................................................................56 4-2-1 XRD分析................................................................................................56 4-2-2 環境式電子顯微鏡(ESEM)分析........................................................56 4-2-3 密度之量測............................................................................................56 4-2-4 微波介電特性之量測............................................................................57 4-3 濾波器之製作與量測.......................................................................................63 4-3-1 濾波器設計規格....................................................................................63 4-3-2 濾波器製作............................................................................................64 4-3-3 濾波器量測............................................................................................65 第五章 實驗結果與討論..........................................................................66 5-1 (Mg1-xCox)4Nb2O9微波特性之探討.................................................................67 5-2 (Mg1-xNix)4Nb2O9微波特性之探討..................................................................77 5-3 (1-x)(Mg0.96Co0.04)4Nb2O9-xSrTiO3微波特性之探討.....................................86 5-4 (1-x)(Mg0.95Ni0.05)4Nb2O9-xSrTiO3微波特性之探討......................................93 5-5 濾波器的響應.................................................................................................101 5-5-1 FR4基板...............................................................................................102 5-5-2 Al2O3基板.............................................................................................104 5-5-3 0.6(Mg0.96Co0.04)4Nb2O9-0.4SrTiO3基板............................................107 第六章 結論與未來展望........................................................................111 參考文獻....................................................................................................113

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