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研究生: 施仲隆
Shih, Chung-Lung
論文名稱: Co(Nb1–xTax)2O6陶瓷在微波頻段之研究與應用
Study and Applications of Co(Nb1–xTax)2O6 Ceramics at Microwave Frequency
指導教授: 黃正亮
Huang, Cheng-Liang
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: 111
中文關鍵詞: 陶瓷微波濾波器
外文關鍵詞: ceramics, microwave, filter
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  • 在此篇論文中主要介紹兩大部分,第一部份將介紹低損耗的介電材料,並嘗試著調整共振頻率溫度飄移係數使其為零;第二部份將介紹其在被動元件之應用,並實作於不同基板上探討元件尺寸的改善。
    第一部份首先要介紹CoNb2O6陶瓷系統之微波介電特性。並使用與Nb5+相同離子半徑的Ta5+來微量取代Nb5+位置,形成Co(Nb1-xTax)2O6(x=0.02-0.1)固溶體,研究其材料特性及微波介電性質。由實驗中可得知Co(Nb0.95Ta0.05)2O6在1210°C燒結4小時可得到最佳之介電特性εr ~ 22.6,Q׃~ 132,100 GHz(at 9.245 GHz),τf ~ –62 ppm/°C。由於此系統之τf為負值,我們添加具正值共振頻率溫度飄移係數的TiO2(τf ~ +420 ppm/°C),探討共振頻率溫度飄移係數趨近零之最佳比例。
    第二部份我們設計及實作一操作在2.4 GHz的微帶線帶通濾波器,濾波器主要採用一反對稱饋入磁場耦合濾波器為主體,並在共振器內加入一開路殘段(open-stub),藉此使得頻寬變窄。在饋入端上也加上一開路殘段來抑制倍頻寄生響應。最後,我們將此電路實作在FR4、氧化鋁和0.84Co(Nb0.95Ta0.05)2O6–0.16TiO2基板上,並量測其頻率響應。由量測的結果可得知,利用高介電係數及低損耗的材料做為電路基板時,確實能達到提升效能和縮小面積的需求。

    There are two main subjects in this thesis. The first one discussed was the low loss dielectric material, and to adjusted temperature coefficient of resonant frequency to closed zero. Second, passive components and improvement of circuit size in different substrates will be discussed.
    First, used Ta5+ ions to substituted Nb5+ ions for the the same ionic radius and form the Co(Nb1-xTax)2O6 (x=0.02-0.1)solid solutions. According to the experiment results of microwave dielectric properties showed that Co(Nb0.95Ta0.05)2O6 ceramics has the superior properties at sintering temperature 1210°C for 4 hours, and the dielectric properties are εr~ 22.6, Q×f ~ 132,100(at 9.245 GHz)and τf ~ –62 ppm/°C. Concerning about the negative value of τf, choosed the TiO2(τf ~ +420 ppm/°C)to adjust the value, then made an the temperature coefficient of resonant frequency to closed zero.
    Second, designed and fabricated a microstrip band-pass filter which resonator at 2.4 GHz. The filter was a magnetic coupling filter using skew-symmetric feed structure, and tapped open stub in this design to obtained a narrow bandwidth. Finally, an open-stub was added to suppress the spurious response. The pattern was printed on FR4, Al2O3 and 0.84Co(Nb0.95Ta0.05)2O6–0.16TiO2 substrates. By measured their frequency responses, the substrate with high dielectric constant and low loss, can improve the performance and reduce the size of filter.

    摘要 I Abstract II 誌謝 IV 目錄 V 表目錄 VIII 圖目錄 IX 第一章 緒論 1 1-1 前言 1 1-2 研究目的 2 第二章 介電材料原理 3 2-1 介電共振器(dielectric resonator,DR)原理 3 2-2 介電材料之微波特性 6 2-2-1 介電係數(dielectric constant,K、εr) 6 2-2-2 品質因數(quality factor,Q) 10 2-2-3 共振頻率溫度飄移係數(temperature coefficient of resonant frequency,τf) 12 2-3 燒結原理 13 2-3-1 材料燒結之擴散方式 13 2-3-2 燒結的種類 14 2-3-3 燒結的過程 14 2-4 鈮鐵礦之結構 16 2-5 金紅石之結構 17 第三章 微帶線及濾波器原理 18 3-1 濾波器原理 18 3-1-1 濾波器簡介 18 3-1-2 濾波器之種類及其頻率響應 18 3-2 微帶線原理 22 3-2-1 微帶傳輸線簡介 22 3-2-2 微帶線的傳輸模態 22 3-2-3 微帶線各項參數公式計算及考量 23 3-2-4 微帶線的不連續效應 26 3-2-5 微帶線的損失 33 3-3 微帶線諧振器種類 34 3-3-1 λ/4短路微帶線共振器 34 3-3-2 λ/2開路微帶線共振器 35 3-4 共振器間的耦合形式 37 3-4-1 電場耦合: 37 3-4-2 磁場耦合: 41 3-4-3 混和耦合: 45 3-5 四分之一波長的阻抗轉換器與開路殘段(open stub) 48 3-6 反對稱饋入磁場耦合濾波器研究與設計 50 第四章 實驗方法及步驟 53 4-1 微波介電材料的製備 53 4-1-1起始原料的配置及球磨 54 4-1-2 粉末的煆燒成相 54 4-1-3 燒結體的製備 55 4-2 微波介電材料的量測與分析 56 4-2-1 燒結體密度量測(Archimedes) 56 4-2-2 X-Ray相鑑定 56 4-2-3 SEM、EDS 分析 57 4-2-4 微波介電性質量測與分析 57 4-2-5 共振頻率溫度飄移係數之量測 63 4-3 濾波器的製作與量測 64 第五章 實驗結果與討論 66 5-1 Co(Nb1–xTax)2O6之微波介電特性 66 5-1-1 Co(Nb1–xTax)2O6之XRD分析 66 5-1-2 Co(Nb1–xTax)2O6之EDS與SEM分析 68 5-1-3 Co(Nb1–xTax)2O6之密度分析 77 5-1-4 Co(Nb1–xTax)2O6之介電係數分析 78 5-1-5 Co(Nb1–xTax)2O6之品質因數分析 79 5-1-6 Co(Nb1–xTax)2O6之共振頻率溫度飄移係數分析 80 5-2 (1–x)Co(Nb0.95Ta0.05)2O6–xTiO2之微波介電特性探討 82 5-2-1 (1–x)Co(Nb0.95Ta0.05)2O6–xTiO2之XRD分析 82 5-2-2 (1–x)Co(Nb0.95Ta0.05)2O6–xTiO2之EDS與SEM分析 84 5-2-3 (1–x)Co(Nb0.95Ta0.05)2O6–xTiO2之密度分析 93 5-2-4 (1–x)Co(Nb0.95Ta0.05)2O6–xTiO2之介電係數分析 94 5-2-5 (1–x)Co(Nb0.95Ta0.05)2O6–xTiO2之品質因數分析 95 5-2-6 (1–x)Co(Nb0.95Ta0.05)2O6–xTiO2之共振頻率溫度飄移係數分析 96 5-3 濾波器的模擬與實作 98 5-3-1 使用FR4(玻璃纖維基板)之模擬與實作結果 99 5-3-2 使用Al2O3之模擬與實作結果 101 5-3-3 使用0.84Co(Nb0.95Ta0.05)2O6–0.16TiO2之模擬與實作結果 104 第六章 結論 108 參考文獻 109

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