鍗化銻半導體可應用於CdS/CdTe太陽能電池上的電子接觸器。本論文利用EMI•Cl•BF4室溫離子液體來電鍍鍗化銻半導體。以玻璃碳電極研究鍗化銻的電化學行為，發現Sb在Te上有UPD的行為。以ITO導電玻璃為基材，以定電位法來共鍍鍗化銻，藉由改變鍍液中濃度比例、電鍍電位以及溫度來控制鍍層中的比例與合金的晶形。當在100℃時，電位選擇在UPD電位下電鍍可得到有較好晶形的Sb2Te3。利用室溫離子熔鹽電鍍Sb2Te3可解決在水溶液中電鍍溫度需達90℃以上所造成的困難。

　　Polycrystalline Antimony Tellruide (Sb2Te3) layer is suitable for back contact systems in CdS/CdTe thin film solar cell. In this work, electrodeposition of antimony telluride is studied in a basic 1-ethyl-3-methylimidazolium chloride-tetrafluoroborate room temperature ionic liquid. The electrochemistry of Antimony Telluride on a glassy carbon electrodes and UPD(underpotential deposition) of antimony on tellurium have be observed. Antimony telluride is electrodeposited on ITO(Indium Tin Oxide) substrates by controlled-potentail electrolysis. The stoichiometry and crystalline of electrodeposited Antimony Telluride can be controlled by changing the bath composition, deposition, and temperature. At 100℃, the polycrystalline antimony telluride can be prepared in the potential range of the UPD of antimony on Tellurium. The temperature limitation of electrodepoisition in the aqueous solution could be avoided by using ionic liquid.

第六章 參考文獻
1.P. Walden, Bull. Acad. Imper. Sci.(St. Petersburg), 1800(1914).
2.F. H. Hurley, J. P. Wier, J. Electrochem. Soc., 98, 203(1951).
3.P. Wassercheid, T. Welton, Editor “ Ionic Liquids in Synthesis”, Wiley-VCH Verlag GmbH&Co. KGaA(2002).
4.R. J. Gale, B. Gilbert, R. A. Osteryoung, Inorg. Chem., 17, 2728(1978).
5.J. C. Nardi, C. L. Hussey, L. A. King, U.S. Patent 4,122,245 (1978)
6.J. S. Wilkes, J. A. Levisky, R. A. Wilson, C. L. Hussey, Inorg. Chem., 21, 1263(1982).
7.E. I. Cooper, E. J. M. O’Sullivan, in” Proceeding of the eighth International Symposium of Molten Salts, Physical and High Temperature Materials Division Proceeding”, PV92-16, R. J. Gale, G. Blomgren and H. Kojima, Editors, PP. 386, J. Electrochem. Soc., Pennington, NJ(1992).
8.J. S. Wilkes, , M. J. Zaworotko, J. Chem. Soc. Chem. Commun., 965(1992).
9.P. A. Z. Suarez, J. E. L. Dullius, S. Einloft, R. F. De Souza, J. Dupont, Polyhedron, 15, 1217(1996).
10.C. F. Poole, J. Chromatogr. A, 1037, 49(2004).
11.D. R. Macfarlane, S. A. Forsyth, J. Golding, G. B. Deacon, Green Chem., 4, 444(2002)
12.J. Sun, D. R. Macfarlane, M. Forsyth, Electrochim. Acta, 48, 1707(2003)
13.A. E. Visser, J. R. Holbrey, R. D. Roger, Chem. Commun., 2484(2001)
14.Y. R. Mirzaei, B. Teamley, J. M. Shreeve, J. Org. Chem., 67, 9340(2002)
15.R. M. Pomaville, S. K. Poole, L. J. Davis, F. F. Poole, J. Chromatogr., 438, 1(2003)
16.S. Carda-Broch, A. Berthod, D. W. Armstrong, Rapid Commun. Mass Spectrom, 17, 553(2003)
17.N. M. M. Mateus, L. C. Branco, N. M. T. Loureneo, C. A. M. Afonso, Green Chem.,5 ,347(2003)
18.J. H. Davis, P. A. fox, Chem. Commun., 1209(2003)
19.Solvent-Innovation, http://www.solvent-innovation.de.
20.Merck, http://www.ionicliquids-merck.de/servlet/PB/menu/1014040/index.html
21.A. R. Katritzky, R. Jain A. Lomaka, R. Oetrukhin, M. Karelson, A. e. Visser, R. D. Rogers, J. Chem. Inf. Comput. Sci., 42, 225(2002).
22.E. A. Turner, C. C. Pye, R. D. Singer, J. Phys. Chem. A, 107, 2277(2003).
23.H. L. Ngo, K. Lecompte, L. Hargens, A. B. Mcewen, Thermochimica Acta, 357-358, 97(2000).
24.A. Elaiwi, P. B. Hitchcock, K. R. Seddon, N. Srinivasan, Y. M. Tan, Dalton Trans., 3467(1995).
25.J. G. Huddleston, A. E. Visser, W. M. Reicert, H. D. Willauer, G. A. Broker, R. D. Rogers, Green Chem., 3, 156(2001)
26.P. Bonhôte, A.-P. Dias, N. Papageogiou, K. Kalyanasundaram, M. Grätzel, Inorg. Chem., 35, 1168(1991)
27.J. D. Jolbrey, K. R. Seddon, J. Chem. Soc., Dalton Trans., 2133(1999).
28.R.Hagiwara, Y. Ito, J. Fluor. Chem., 105, 221(2000).
29.K. R. Seddon, A. Stark, M.-J. Torres, Pure Appl. Chem., 72, 2275(2000).
30.J. A. Boon, J. A. Levisky, J. L. Pflug, J. S. Wilkes, J. Org. Chem., 51, 480(1986).
31.J. D. Holbrey, K. R. Seddon, Clean Prod. Process., 1, 223(1999) .
32.H. Olivier, J. Mol. Catal., 146, 285(1999).
33.T. Welton, Chem. Rev., 99, 2071(1999).
34.P. Wasserscheid, W. Keim, Angew. Chem. Int. Ed., 39, 3772(2000).
35.C. M. Gordon, Appl. Catal.,101, 222(2001).
36.R. Sheldon, Chem. Commun, 2399(2001).
37.F. Endres, CHEMPHYSCHEM, 3, 144(2002).
38.R. T. Carlin, H. C. De Long, J. Fuller and P. C. Trulove, J. Electrochem. Soc., 141, L73(1994).
39.J. Fuller, R. T. Carlin, R. A. Osteryoung, J. Electrochem. Soc., 144, 3881(1997).
40.J. Sun, M. Forsyth, D. R. MacFarlane, J. Phy. Chem. B, 102, 8858(1998).
41.D. R. MacFarlane, P. Meakin, J. Sun, N. Amini, M. Forsyth, J. Phy. Chem. B, 103, 4164(1999).
42.H. Matsumoto, M. Yanagida, K. Tanimoto, M. Nomura, Y. Kitagawa, Y. Miyazaki, Chem. Lett., 922(2000).
43.C. Nanjundiah, S. F. McDevitt, V. R. Koch, J. Electrochem. Soc., 144, 3392(1997).
44.V. R. Koch, L. A. Dominey, C. Nanjundiah, J. Electrochem. Soc., 143 798(1996).
45.A. B. McEwen, S. F. McDevitt, V. R. Koch, J. Electrochem. Soc., 144, L87(1997).
46.A. B. McEwen, H. L. Ngo, K. LeCompte, J. L. Coldman, J. Electrochem. Soc., 146, 1687(1999).
47.P. A. Z. Suarez, V. M. Selbach, J. E. L. Dullius, S. Einloft, C. M. S. Piatnicki, D. S. Azambuja, R. F. de Souza, J. Dupont, Electrochim. Acta, 42, 2533(1997).
48.N. Papageorgiou, Y. Athanassov, M. Armand, P. Bonhôte, H. Pettersson, A. Azam, M. Grätzel, J. Electrochem. Soc., 143, 3099(1996).
49.R. Kawano, M. Watanabe, Chem. Commun., 330(2003).
50.Md. A. B. H. Susan, A. Noda, S. Mitsushima, M. Watanabe, Chem. Commun., 938(2003).
51.A. Noda, Md. A. B. H. Susan, K. Kudo, S. Mitsushima, K. Hayamizu, M. Watanabe, J. Phy. Chem. B, 107, 4024(2003).
52.A. C. Cole, J. K. Jensen, I. Ntai, K, L. T. Tran, K. J. Weaver, D. C. Forbes, J. H. Davis, J. Am. Chem. Soc., 124, 5962(2002) .
53.N. Romeo, A. Bosio, R. Tedeschi, A. Romeo, V. Canevari, Sol. Energy Mater. Sol. Cells, 58, 209(1999).
54.A. Bruckl, Monatsh. Chem., 45, 483(1925).
55.A. Oppenheimer, J. Prakt. Chem., 71, 277(1857).
56.A. Giani, A. Boulouz, F. Pascal-Delannoy, A. Foucaran, A. Boyer, B. Aboulfarah, A. Mzerd, J. Mater. Sci. Lett., 18, 541(1999).
57.T. C. Patel, P. G. Patel, Mater. Lett., 3(1.2), (Nov. 1984).
58.N. Romeo, Universita’ di Parma, Italy (2001), Personal communication.
59.G. Leimkühler, I. Kerkamm, R. Reineke-Koch, J. Electrochem. Soc., 149, C474(2002).
60.A. E. Abken, J. Mater. Sci.Lett., 21, 845-847 (2002).
61.E. G.-S Jeng, I-W. Sun, J. Electrochem. Soc., 144, 2369(2002).
62.M-H. Yang, I-W. Sun, J. Appl. Electrochem., 22, 1077(2003)
63.J. R. Sanders, in ” An Investigations of Transport properties and Ion Association in Room Temperature Haloaluminate Molten Salt ”, Ph.D. Dissertation, The University of Mississippi (1987)
64.A. J. Bard, L. R. Faulkner, “ Electrochemical Methods; Fundamentals and Applications ”, John Wiley&Sons, New York(2001)
65.許淑愛，室溫離子熔液中電沉積鍗化鎘及鈀銦合金，碩士論文，國立成功大學。
66.M.-H. Yang, M.-C. Yang, I-W. Sun, J. Electrochem. Soc., 150, C544(2003).
67.M. P. R. Panicker, M. Knaster, F. A. Krögers, J. Electrochem. Soc., 125, 566 (1998)
68.F. A. Krögers, J. Electrochem. Soc., 125, 2028 (1978)