戴奧辛是世界各國一致公認強烈的致癌物質，是目前備受關注的污染物，而研究土壤中的戴奧辛含量可代表該地區戴奧辛暴露量的長期性指標，當土壤中檢測出高濃度戴奧辛時，週遭地區若無空氣污染來源，則有可能為該地區曾有石化燃料燃燒、鹼氯工業及相關化學製造過程、火災等污染源。本研究係針對三座大型都市垃圾焚化廠周遭環境土壤中戴奧辛背景含量及特徵剖面進行調查、一污染廠址廠外道路下可能受污染之土壤中戴奧辛含量及特徵剖面進行調查，期望能建立調查地區土壤中戴奧辛濃度及特徵，評估焚化廠對該地區土壤之影響，並與污染廠址廠外道路可能污染之土壤比較以了解是否真正遭受污染，所得結果歸納如下：1. T焚化廠土壤PCDD/Fs之含量介於0.38~398 ng/kg d.m.之間，平均值為73.63 ng/kg d.m. ；總I-TEQ濃度介於0.138~2.36 ng I-TEQ/kg，平均值濃度為0.892 ng I-TEQ/kg。2. Y焚化廠土壤PCDD/Fs之含量介於12.9 ~221 ng/kg d.m.之間，平均值為75.87 ng/kg d.m.；總I-TEQ濃度介於 0.128~ 5.26 ng I-TEQ/kg，平均值濃度為2.50 ng I-TEQ/kg。3. S焚化廠土壤PCDD/Fs之含量介於 73.4~ 922ng/kg d.m.之間，平均值為239.22 ng/kg d.m.；總I-TEQ濃度介於 0.592~ 11.8 ng I-TEQ/kg，平均值為4.00 ng I-TEQ/kg。4. N廠廠外道路土壤中污染物五氯酚含量測值皆低於偵測極限；PCDD/Fs之含量介於 115~86200000 ng/kg d.m.之間；總I-TEQ含量介於0.85~156000 ng I-TEQ/kg之間。5.N廠廠外道路土壤中NA9（6850 ng I-TEQ/kg）、NA12-1（65900 ng I-TEQ/kg）、NA16（65900 ng I-TEQ/kg）、NA3（1360 ng I-TEQ/kg）、NB2（156000 ng I-TEQ/kg）、NB6（6770 ng I-TEQ/kg）超過土壤中戴奧辛污染管制標準。

　It is that countries all over the world generally take Polychlorinated Dibenzo-p-dioxins / Dibenzofurans（PCDD/Fs） the strong carcinogen. It is the pollutant that everybody concern. To investigate the levels of PCDD/Fs in soil can be use to describe long–term exposure.The characteristics of PCDD/Fs in soil from the surrounding locations of three municipal solid waste incineration plants and the road outside a polluted factory.The conclusions of this study are summarize as follows：1.The PCDD/Fs concentration in soil of T area are between 0.38 and 398 ng/kg d.m. with a mean value of 73.63 ng /kg. The toxic equivalency (TEQ) concentration in soil of PCDD/Fs were from 0.138 to 2.36 ng I-TEQ/kg with a mean value of 0.892 ng I-TEQ/kg. 2. The PCDD/Fs concentration in soil of y area are between12.9 and 221 ng/kg d.m. ith a mean value of 75.87 ng /kg.The toxic equivalency (TEQ) concentration in soil of PCDD/Fs were from 0.128 to 5.26 ng I-TEQ/kg with a mean value of 2.50 ng I-TEQ/kg. 3. The PCDD/Fs concentration in soil of S area are between 73.4 and 922 ng/kg d.m. with a mean value of 239.22 ng /kg.The toxic equivalency (TEQ) concentration in soil of PCDD/Fs were from 0.592 to 11.8 ng I-TEQ/kg with a mean value of 4.00 ng I-TEQ/kg. 4. The PCP concentration in soil of the road outside of the N factory are all lower than detection limits.The PCDD/Fs concentration in soil of the road outside of the N factory are between 115 and 86200000 ng/kg d.m. .The toxic equivalency (TEQ) concentration in soil of PCDD/Fs were from 0.85 to 156000 ng I-TEQ/kg. 5. Some samples of the N factory, for example, NA9（6850 ng I-TEQ/kg）、NA12-1（65900 ng I-TEQ/kg）、NA16（65900 ng I-TEQ/kg）、NA3（1360 ng I-TEQ/kg）、NB2（156000 ng I-TEQ/kg）、NB6（6770 ng I-TEQ/kg）Exceed the standard of dioxin soil pollution .

Alcock, R. E.; Gemmill, R.; Jones, K. C. “Improvements to the UK PCDD/F and PCB Atmospheric Emission Inventory following An Emissions Measurement Programme” Chemosphere, Vol. 38, pp. 759-770, 1999.
Alcock, R. E.; Jones, K. C. “Dioxins in the Environment: a Review of Trend Data” Environmental Science & Technology Vol. 30, pp. 3133-3143, 1996.
Altwicker, E. R. “Formation of Precursors to Chlorinated Dioxin/furans under Heterogeneous Conditions” Combustion Science and Technology, Vol. 88, pp. 349-368, 1993.
Ana Maria C.B. Braga.; Thomas Krauss.; Cláudia R. Reis dos Santos.; Priscila Mesquita de Souza “PCDD/F-contamination in a hexachlorocyclohexane waste site in Rio di Janeiro, Brazil” Chemosphere, Vol.46, pp. 1329-1333, 2002.
Ballschmiter, K.; Zoller, W.; Buchert, H.; Class, T. F. Z. Analytical Chemistry, Vol. 322, pp. 587, 1985.
Braga, A. M. C. B., Krauss, T., Santos, C. R. R. D., Souza, P. M. D., PCDD/F-contamination in a Hexachlorocyclohexane Waste Site in Rio de Janeiro, Brazil, Chemosphere 46, pp.1329-1333, 2002
Blifford, I. H.; Meeker, G. O. “A Factor Analysis Model of Large Scale Pollution”, Atmospheric Environment, Vol. 1, pp. 147-157, 1967.
Caserini, S.; Monguzzi, A. M. “PCDD/Fs Emissions Inventory in the Lombardy Region: Results and Uncertainties” Chemosphere, Vol.48, pp. 779-786, 2002.
Cleverly, D.; Schaum, J.; Winter, D.; Schweer, G.; O'Rourke, K. “The Inventory of Sources of Dioxin in the United States”, Organohalogen Compounds, Vol. 36, pp. 1-6, 1998.
Dickson, L. C.; Lenoir, D.; Hutzinger, O. “Quantitative Comparison of de Novo and Formation of Polychlorinated Dibenzo-p-dioxins under Simulated Municipal Solid Waste Incinerator Postcombustion Conditions” Environmental Science and Technology, Vol. 26, pp. 1822-1828, 1992.
Dickson, L. C.; Lenoir, D.; Hutzinger, O. “Surface-catalyzed Formation of Chlorinated Dibenzodioxins and Dibenzofurans during Incineration”, Chemosphere, Vol. 19, pp. 277-282, 1989.
Domingo, J. L.; Granero, S.; Schuhmacher, M. “Congeners Profiles of PCDD/Fs in Soil and Vegetation Samples Collected near to a Manucipal Waste Incinerator” Chemsphere Vol. 43, pp. 517-524, 2001.
Domingo, J. L.; Schuhmacher, M.; Müller, J. F.; Tivera, J.; Granero, S.; Llobet, J. M “Evaluating the Environmental Impact of an Old Municipal Waste Incinerator: PCDD/F Levels in Soil and Vegetation Samples” Journal of Hazardous Materials Vol. A76, pp. 1-12, 2000.
Domingo, J. L., Schuhmacher, M., Agramunt, M. C., Llobet, J. M., Rivera, J., Muller, L. “PCDD/F Levels in the Neighbourhood of a Municipal Solid Waste Incinerator after Introduction of Technical Improvements in the Facility”, Environment International, Vol. 28, pp. 19-27, (2002).
Dwernychuk, L. Wayne.; Hoang Dinh Cau.; Christopher T. Hatfield. “Dioxin Reservoirs in Southern Viet Nam－A legacy of Agent Orange”, Chemosphere, Vol. 47,pp. 117-137,2002.
Dyke, P. H.; Foan, C.; Wenborn, M.; Coleman, P. J. “A Review of Dioxin Releases to Land and Water in the UK” Environmental Science & Technology Vol. 207, pp. 119-131, 1997.
Eljarrat, E.; Caixach, J,; Rivera, J. “Levels of Polychlorinated Dibenzo-p- dioxins and Dibenzofurans in Soil Samples from Spain” Chemosphere Vol. 44, pp. 1383-1387, 2001.
Eltzer, B. D. “Comparison of Point and Nonpoint Sources of Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans to Sediments of the Housatonic River” Environmental Science & Technology Vol. 27, pp. 1632-1637, 1993.
Everaert, K.; Baeyens, J. “The Formation and Emission of Dioxins in Large Scale Thermal Processes” Chemosphere, Vol. 46, pp. 439-448, 2002.
Gaus, C.; Päpke O.; Dennison, N.; Haynes, D.; Shaw, G. R.; Connell, D. W.; Müller, J. F. “Evidence for the Presence of a Widespread PCDD Source in Coastal Sediments and Soils from Queensland, Australia” Chemsphere Vol. 43, pp. 549-558, 2001.
Gullett, B. K.; Lemleux, P. M.; Dunn, J. E. “Role of Combustion and Sorbent Parameters in Prevention of Polychlorinated Dibenzo-p-dioxin and Polychlorinated Dibenzofuran Formation during Waste Combustion” Environmental Science and Technology, Vol. 28, pp.107-118, 1994.
Hagenmaier, H.; Brunner, H. “Isomerspecific Analysis of Pentachlorophenol and Sodium Pentachlorophenate for 2,3,7,8- substituted PCDD and PCDF at sub-ppb Levels” Chemosphere Vol. 16, pp. 1759-1764, 1987.
Hagenmaier, H.; Kraft, M.; Brunner, H.; Haag, R. “Catalytic Effects of Fly Ash from Waste Incineration Facilities on the Decomposition of Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans” Environmental Science and Technology, Vol. 21, pp. 1080-1084, 1987.
Hagenmaler, H.; Undig, C.; She, J. “Correlation of Environmental Occurance of Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans with Possible Sources” Organohalogen Compounds, pp.271-274, 1993.
Japan Ministry of the Environment, The Environmental Monitoring Report on the Persistent Organic Pollutants (POPs) in Japan. 2002.
Jimenez, B.; Eljarrat, E. “Polychlorinated Dibenzo-p-dioxins and Dibenzofurans in Soils near a Clinical Waste Incinerator in Madrid, Spain. Chemometric Comparison with other Pollution Sources and Soils.” Chemosphere Vol. 32, pp. 1327-1348, 1996
Jimenez, B.; Hermandez, L. M.; Gonzalez, M. J. “Congerner, Specific Analysis of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans in Crabs and Sediments from the Vince and Orbello, Lagoons, Italy” Environmental Science & Technology Vol. 32, pp. 3853-3861, 1998.
Jolliffe, I. T. Principal Component Analysis, Springer-Verlag, 1986.
Joelle A.Prange.; Caroline Gaus.”Investigation into the PCDD Contamination of Topsoil, River Sediments and Kaolinite Clay in Queensland, Australia.”Chemosphere Vol 46, pp. 1335-1342, 2002.
Kakareka, S. V. “Sources of Persistent Organic Pollutants Emission on the Territory of Belarus” Atmospheric Environment, Vol. 36, pp. 1407-1419, 2002.
Karasek, F. W.; Dickson, L. C. Science, Vol. 237, pp.754, 1987.
Klara Hilscherova.; Kurunthachalam Kannan. “Polychlorinated Dibenzo-p-dioxin and Dibenzofuran Concentration Profiles in Sediments and Flood-plain Soils of the Tittabawassee river,Michigan” Environmental Science & Technology Vol. 37, pp. 468-474, 2003.
Leeuwen, F. X. R.; Feeley, M.; Schrenk, D.; Larsen, J. C.; Farland, W.; Younes, M. “Dioxins: WHO’s Tolerable Daily Intake (TDI) Revisited” Chemosphere, Vol. 40, pp. 1095-1101, 2000.
Lober, M.; P, Pinsky “Reationships Between Dioxin in Soil, Air, Ash, and Emissions from a Municipal Solid Waste Incinerator Emittiing large amount of Dioxin” Chemosphere, Vol 37,pp. 2173-2197,1998.
Luijk, R.; Akkerman, D. M.; Slot, P.; Olie, K.; Kapteijn, F. “Mechanism of Formation of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans in the Catalyzed Combustion of Carbon”, Environmental Science and Technology, Vol. 28, pp.312-321, 1994.
Martha Harnly.; William M. “Assessing Environmental Contamination from a Pentachlorophenol Fire:Screening Soils for Octachlorodibenzo-p-dioxin” Chemosphere Vol. 17, pp. 1831-1850, 1988.
Maystrenko, V.; Kruglov, E.; Amirova, Z.; Khamitov, R. “Polychlorinated Dioxin and Debenzofuran Levels in the Environment and Food from the Republic of Bashkortostan, Russia” Chemosphere Vol. 37, pp. 1699-1708, 1998.
McKay, G. “Dioxin Characterisation, Formation and Minimisation during Municipal Solid Waste (MSW) Incineration: Review”, Chemical Engineering Journal, Vol. 86, pp. 343-368, 2002.
Milligan, M. S.; Altwicker, E. “The Relationship between de Novo Synthesis of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans and Low-Temperature Carbon Gasification in Fly Ash” Environmental Science and Technology, Vol. 27, pp.1595-1601, 1993.

Olie, K.; Vermeulen, P. L.; Hutzinger, O. “Chlorodibenzo-p-dioxins and Chlorodibenzofurans Are Trace Components of Fly Ash and Flue Gas of Some Municipal Incinerators in the Netherlands” Chemosphere, Vol. 6, pp. 455-459, 1977.
Ogura, Isamu.; Masunaga, Shigeki. “Congener-Specific Characterization of PCDDs/PCDFs in Atmospheric Deposition: Comparison of Profiles among Deposition, Source, and Environmental Sink” Chemosphere, Vol. 45, pp. 173-183, 2001.
Quaß, U.; Fermann, M. W.; Bröker, G. “Steps Towards A European Dioxin Emission Inventory” Chemosphere, Vol. 40, pp. 1125-1129, 2000.
Rigo, H. G.; John, C. A.; Steven, L. W. “The Relationship between Chlorine in Waste Stream and Dioxin Emissions from Waste Combustor Stacks.” ASME Reasearch Report, CRTD Vol.36,1995.
Sam-Cwan, Kim.; Hwan, Jeon Sung. ”Removal Efficiencies of PCDDs/PCDFs by Air Pollution Control Devices in Municipal Solid Waste Incinerators“ Chemosphere Vol 43, pp. 773-776. 2001.
Sakurai, T.; Kim, J. G.; Suzuki, N.; Matsuo, T.; Li, D. Q.; Yao, Y.; Masunaga, S.; Nakanishi, J. “Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans in Sediment, Soil, Fish, Sellfish, and Crab Samples from Tokyo Bay Area, Japan” Chemosphere Vol. 40, pp. 627-640, 2000.
Schuhmacher, M., Bocio, A., Agramunt, M. C., Domingo, J. L., Kok H.A.M. “PCDD/F and Metal Concentrations in Soil and Herbage Samples Collected in the Vicinity of a Cement Plant”, Chemosphere, Vol. 48, pp. 209-217, (2002).
Schuhmacher, M., Rodriguez-Larena, M. C., Agramunt, M. C., Diaz-Ferrero, J., Domingo, J. L. “Environmental Impact of a New Hazardous Waste Incinerator in Catalonia, Spain: PCDD/PCDF Levels in Herbage Samples”, Chemosphere, Vol. 48, pp.187-193, (2002).
Schuhmacher, M.; Domingo, J. L.; Llobet, J. M.; Müller, L.; Jager, J. “Assessment of Baseline Levels of PCDD/Fs in Soils in the Neighbourhood of a New Hazardous Waste Incinerator in Catalonia, Spain” Chemosphere Vol. 35, pp. 1947-1958, 1997b.
Schuhmacher, M.; Granero, S.; Xifró, A.; Domingo, J. L.; Rivera, J.; Eljarrat, E. “Levels of PCDD/Fs in Soil Samples in the Vicinity of a Municipal Solid Waste Incinerator” Chemosphere Vol. 37, pp. 2127-2137, 1998.
Schuhmacher, M.; Xifró, A.; Llobet, J. M.; de Kok, H. A. M.; Domingo, J. L. “PCDD/Fs in Soil Samples Collected in the Vincinity of a Municipal Solid Waste Incinerator: Human Health Risks” Archives of Environmental Contamination and Toxicology Vol. 33, pp. 239-246, 1997.
Schuhnacher, M., Domingo, J. L., Liobet, J. M., Muller, L., Jager, J. “Levels of PCDDs and PCDFs in Grasses and Weeds Collected near a Municipal Solid Waste Incinerator” The Science of the Total Environment, Vol. 201, pp. 53-62, 1997.
Schwarz, G.; Steiglitz, L.; Roth, W. “Formation Conditions of Several Polychlorinated Compound Classes on Fly Ash of a Municipal Waste Incinerator” Organohalogen Compounds, Vol. 3, pp. 169-172, 1990.
Shigeki Masunaga.; Takumi Takasuga.; Junko Nakanishi. “Dioxin and Dioxin-like PCB Impurities in Some Japanese Agrochemical Formulations.” Chemosphere, Vol. 44,pp.873-885
Stieglitz, L.; Vogg, H., Report KFK 4379, Laboratorium fur Isotopentechnik, Institut fur Heize Chemi, Kernforschungszentrum Karlsruhe, 1988.
Thurston, G. D.; Spengler, J. D. “A Quantitative Assessment of Source Contributions to Inhalable Particulate Matter Pollution in Metropolitan Boston” Atomospheric Environment, Vol. 19, pp. 9-25, 1985.
US EPA Alternative Control Techniques Document - NOx Emissions from Iron and Steel Mills. EPA-453/R-94-065, 1994c.
US EPA Combustion Emissions Technical Resource Document (CETRED), Report No. EPA 530-R-94-014, Washington, DC, 1994b.
US EPA Database of Sources of Environmental Releases of Dioxin like Compounds in the United States, EPA/600/C-01/012, 2001.
US EPA Exposure and Human Health Reassessment of 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) and Related Compounds, EPA/600/P-00/001Bb, 2000.
US EPA Health Assessment Document for 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) and Related Compounds”, EPA/600/Bp-92/001c Estimating Exposure to Dioxin-Like Compounds, EPA/600/6-88/005Cb, Office of Research and Development, Washington, DC, 1994a.
US EPA Locating and Estimating Air Emission from Source of Polycycle Organic Matter（POM）, EPA-45014-84-007, 1987.
US EPA Profile of the Iron and Steel Industry. EPA/310-R-95-005, 1995.
US EPA The Inventory of Sources of Dioxin in the United States, EPA/600/P-98/002Aa, April 1998.
US EPA, Technical Implementation Document for EPA’s Boiler and Industrial Furnace Regulations. Office of Solid Waste and Emergency Response. EPA-530-R-92-001, 1992b.
US EPA, Technical Support Document for HWC MACT Standards, Volume II, Miscellaneous Technical Issues, 1996.
Vogg, H.; Hunsinger, H.; Merz, A.; Stieglitz, L. “Influencing the Production of Dioxin/Furan in Solid Waste Incineration Plants by Measures Affecting the Combustion as well as the Flue Gas Cleaning Systems” Chemosphere, Vol. 25, pp. 149-152, 1992.
Vogg, H.; Stieglitz, L. “Thermal Behavior of PCDD/PCDF in Fly Ash Municipal Incinerators” Chemosphere, Vol. 15, pp.1373-1378, 1986.
Wang, L. C.; Lee, W. J.; Lee, W. S.; Chang-Chien, G. P. “Inventory of PCDD/F Emission in Taiwan: Important Air Emission Sources”, 3rd Asian Aerosol Conference, Submitted, 2003a.
Wang, L. C.; Lee, W. J.; Lee, W. S.; Chang-Chien, G. P.; Tsai, P. J. “Major Emission Inventory of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans in Taiwan”, Environmental Health Perspectives, Prepared for Submission, 2003b.
Wang, L. C.; Lee, W. J.; Lee, W. S.; Chang-Chien, G. P.; Tsai, P. J. “Characterizing the Emission of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans from Crematories and their Impacts to the Surrounding Environment”, Environmental Science and Technology, Vol. 37, pp.62～67, 2003d.
Wang, L. C.; Lee, W. J.; Lee, W. S.; Chang-Chien, G. P.; Tsai, P. J. “Effect of Chlorine Content in Feeding Wastes of Incineration on the Emission of Polychlorinated Dibenzo-p-dioxins/ Dibenzofurans”, The Science of the Total Environment, Vol. 302, pp.185～198, 2003e.
Wang, L. C.; Lee, W. J.; Tsai, P. J.; Lee, W. S.; Chang-Chien, G. P. “Emissions of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans from Stack Flue Gases of Sinter Plants”, Chemosphere, Vol. 50, pp.1123～1129, 2003c.
WHO Regional Office for Europe, Copenhagen, “PCBs, PCDDs and PCDFs: Prevention and Control of Accidental and Environmental Exposures” Environmental Health Series, Vol. 32, 1987.
Wiesenhahn, D. F.; Li, C. P.; Penner, S. S. “A Simplified Model for Dioxin and Furan Formation in Municipal-waste Incinerators” Energy, Vol. 13, pp. 225-237, 1988.
Yu ML, Shin CW, Hsu CC, Chan WC, Guo YL. The Immunological Evaluation of the Yucheng Children Chemosphere 1998;37:1855-65.
王琳麒, “污染源及大氣中戴奧辛/呋喃之特徵”，國立成功大學環境工程學系博士論文，2003。
吳信賢，類神經網路在受體模式之應用，碩士論文，國立台灣大學環境工程研究所，1996。
徐盛喣，農業化學，1972。
張簡國平、李文智、王琳麒、蔡政穎、余建源、吳俊達、洪忠賢, “台灣PCDD/Fs之排放清單:重要之大氣排放源”, 戴奧辛研討會，2002.
陳建民、李孫榮，戴奧辛、環境與人類，工業污染防制，Vol.57，1996.
黃俊英，多變量分析，中國經濟企業研究所，1991。
楊錫賢，大氣環境中多環芳香烴化合物與金屬元素之特徵，國立成功大學環境工程學系博士論文，1997。
臺北市環境保護局，臺北市垃圾焚化廠-北投廠和木柵廠區內外環境中的戴奧辛、重金屬污染風險評估與管理，2002。
臺東縣環境保護局，台東市地區垃圾焚化廠周界空氣中及植物、土壤戴奧辛含量濃度調查及分析計畫，2002。
樊邦棠，環境工程化學，科技圖書股份有限公司，pp. 311~318 ，1994。
環保署，建立台灣地區戴奧辛排放清冊及排放資料庫計畫，EPA-90-FA12-03-A158，2002a。
環保署，電弧爐煉鋼廠乙座與四座大型垃圾焚化廠周界空氣，植物及土壤中戴奧辛含量調查計畫，2002b。
環保署，樹林垃圾焚化爐周界空氣中及植物、土壤戴奧辛含量濃度資料之建立，2001