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研究生: 楊祐丞
Yang, You-Cheng
論文名稱: 鍶-矽氮氧化物綠色螢光粉之合成及應用於白光LED元件
The synthesis of strotium silicon-based oxynitride green phosphors and their applications on white light emitting diodes
指導教授: 朱聖緣
Chu, Sheng-Yuan
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: 93
中文關鍵詞: 氮氧化物綠色螢光粉
外文關鍵詞: Oxynitride phosphor, WLED
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  • 氮氧化物綠色螢光粉體Sr1-xSi2O2N2:Eu2+的主要發光波長為530nm之綠光,具有一寬廣之激發光譜300~500nm,此粉體具有好的熱穩定性(T50遠大於150℃),可應用於藍光和紫外光發光二極體(LED)上。
    因此本研究主要利用不同方法合成氮氧化物綠色螢光粉
    Sr1-xSi2O2N2:Eu2+,摻雜不同濃度之銪離子(Eu2+)為發光中心,研究其發光機制與濃度淬滅效應,並以X-ray粉末繞射行相鑑定、掃描式電子顯微鏡進行粉體之形貌與大小分析,並就合成方式對發光效率之影響做一探討,此外也藉由共摻雜鈰離子(Ce3+)為增感劑來提升螢光粉體之發光效率並探討能量轉移之機制。氮氧化物螢光粉Sr1-xSi2O2N2:Eu2+在397nm波長下的外部量子效率可由13%提升至32% , 450nm波長下的外部量子效率可由9%提升至20%,發光效率提升之原因為螢光粉體結晶性的提升,與晶粒形貌之改善,此外利用共摻雜Ce3+與Eu2+證實了確實能增加發光強度,其能量轉移之機制為多極化交互作用之偶極-偶極的能量轉移。
    將本研究合成之綠色螢光粉體搭配商用紅色螢光粉與主波長450nm-LED結合製作成白光LED,並在驅動電流為300mA下,測試其元件特性,可獲發光效率為26ml/w,色溫4072K,CIE=(0.37,0.36) ,演色性為82之白光-LED。

    In this study, SrSi2O2N2:Eu2+ oxynitride phosphors were successfully synthesized by different methods and the improvement of the quantum efficiency of phosphors were discussed. The photoluminience (PL) and excitation (PLE), quantum efficiency, thermal stability, x-ray diffraction, and morphology were investigated. In addition, the Ce3+ ions were co-doped in the SrSi2O2N2:Eu2+ phosphors to enhance the luminescence intensity of phosphors; the energy transfer mechanism between Ce3+ and Eu2+ was also investigated.
    The experimental results show that SrSi2O2N2:Eu2+ have broad excitation band at 300 nm~500 nm. The emission peak of SrSi2O2N2: Eu2+ green phosphors at 530 nm was observed under an excitation of 450 nm. The SrSi2O2N2: Eu2+ green phosphors have excellent thermal stability because T50 is higher than 150 oC. The external quantum efficiency was enhanced from 13% to 32% under 397 nm excitation; the external quantum efficiency was enhanced from 9% to 20% under 450 nm excitation. The external quantum efficiency enhancement was ascribed to the improvement in morphology and crystallinity of phosphors.
    Finally, phosphor-converted White-LED (WLED) have been fabricated by using green phosphor SrSi2O2N2: Eu2+ and commercial red phosphor (NR619) combined with a 450 nm LED chip. The WLED exhibits a luminous efficiency of 40 lm/W, a color rendering index (CRI) of 86 and a colour temperature (CCT) of 4624 K, and CIE=(0.35,0.35) driven by 350 mA at room temperature.

    目錄 摘要 I Abstract II 致謝 III 目錄 IV 表目錄 VI 圖目錄 VII 第一章 緒論 1 1-1 前言 1 1-2 研究動機與目的 2 第二章 理論基礎 5 2-1螢光粉之介紹 5 2-1-1 螢光體發光原理與過程 7 2-1-2 螢光體性質[29] 16 2-1-3 發光中心之種類與原理 18 2-1-4 濃度淬滅理論 20 2-2 螢光材料之組成與設計[33] 21 2-2-1 主體晶格之選擇 21 2-2-2 活化劑之選擇 23 2-2-3 抑制劑之選擇 23 2-3稀土元素 24 2-3-1稀土元素之電子結構 24 2-3-2 稀土元素之光 25 2-4 固態反應法[24][36] 26 2-5 化學共沉法[37] 28 2-6 MSi2O2N2文獻與專利回顧[24] 32 2-6-1 MSi2O2N2 專利回顧: 32 2-6-2 氮氧化物螢光粉MSi2O2N2近年來文獻回顧 34 第三章 實驗步驟 41 3-1 實驗藥品 41 3-2 實驗步驟 41 3-2-1 矽酸鍶 42 3-2-2 氮氧化物 43 3-3 量測系統及特性分析 45 3-3-1 量測儀器設備 45 3-3-2 特性分析 47 第四章 結果與討論 54 4-1 以不同方法合成SrSi2O2N2:Eu特性分析 54 4-1-1 SrSi2O2N2:Eu光譜特性分析 54 4-1-2 SrSi2O2N2:Eu2+熱穩性分析 61 4-1-3 SrSi2O2N2:Eu2+ XRD分析 65 4-1-4 SrSi2O2N2:Eu2+ SEM分析 67 4-2 以不同方式合成之SrSi2O2N2:Eu2+特性比較分析 68 4-2-1 不同方式合成之SrSi2O2N2:Eu2+特性分析 68 4-3 矽酸鍶為前驅物所合成之SrSi2O2N2:Ce3+, Eu2+特性分析 71 4-3-1 SrSi2O2N2:Ce3+之特性分析 71 4-3-2 SrSi2O2N2:Ce3+, Eu2+之光譜特性分析 72 4-3-3 SrSi2O2N2:Ce3+, Eu2+ 能量轉移效率 75 4-3-4 SrSi2O2N2: Ce3+, Eu2+能量轉移機制之探討 76 4-3-5 SrSi2O2N2: Ce3+, Eu2+ XRD特性分析 80 4-4 SrSi2O2N2:Eu2+ 綠色螢光粉體之白光LED應用 81 第五章 結論與未來展望 84 5-1 結論 84 5-2 未來展望 85 Reference 86

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