| 研究生: |
黃郁心 Huang, Yu-hsin |
|---|---|
| 論文名稱: |
成長於不同超晶格層上的氮化鎵/氮化銦鎵多重量子井之光學特性研究 Optical Properties of GaN/InGaN Multiple Quantum Wells Grown on Various Superlattice Underlayers |
| 指導教授: |
許進恭
Sheu, Jinn-kong |
| 學位類別: |
碩士 Master |
| 系所名稱: |
電機資訊學院 - 電機工程學系 Department of Electrical Engineering |
| 論文出版年: | 2007 |
| 畢業學年度: | 95 |
| 語文別: | 中文 |
| 論文頁數: | 70 |
| 中文關鍵詞: | 微光致螢光 、陰極射線螢光 、氮化鎵 、超晶格 |
| 外文關鍵詞: | micro-PL, CL, superlattice, GaN |
| 相關次數: | 點閱:85 下載:4 |
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本文以有機金屬氣相沈積法(metalorganic chemical vapor-phase deposition, MOCVD)在(0001)方向的藍寶石基板(sapphire)上成長氮化鎵/氮化銦鎵及氮化鎵/氮化鋁鎵超晶格結構,並分別成長氮化鎵/氮化銦鎵多重量子井於兩種超晶格結構上,我們利用原子力顯微鏡(AFM)、掃瞄式電子顯微鏡(SEM)來觀察表面,並使用陰極射線螢光光譜(CL)、微光致螢光光譜(micro-PL)來研究在不同超晶格結構上所成長之氮化鎵/氮化銦鎵量子井之發光特性。由原子力顯微鏡、掃瞄式電子顯微鏡量測結果可知,表面分佈許多六角型凹洞,一般所通稱之為V-defect,其V型缺陷的大小約為100nm。此外,微光致螢光光譜的結果可知,成長在氮化鎵/氮化鋁鎵超晶格結構上的多重量子井有較高之發光效率。
This thesis aims at fabricating and characterizing of GaN/InGaN multiple quantum wells(MQWs)grown on GaN/InGaN or GaN/AlGaN superlattice underlayer, which were grown by MOCVD on(0001)sapphire substrates. Surface morphologies of these samples were examined by atomic force microscope (AFM)and scanning electron microscope(SEM). The optical properties of GaN/InGaN MQWs grown on various superlattice underlayers were investigated by cathodoluminescence(CL)and micro-photoluminescence (micro-PL). The AFM and SEM images showed open hexagonal inverted pyramids on the(0001)plane of the epi-wafer surfaces, the so-called “V-defect”, and the feature size of the V-defect is about 100 nm. Furthermore, the micro-PL revealed that GaN/InGaN MQWs grown on GaN/AlGaN superlattice underlayer have higher luminescence efficiency.
【1】E.Fred Schubert, “Light-Emitting Diodes”, CAMBRIDGE,
Second edition (2006).
【2】S. Nakamura, M. Senoh, N. Iwasa, and S. Nagahama, “High-Brightness InGaN Blue, Green and Yellow Light-Emitting Diodes with Quantum Well Structures”, Jpn. J. Appl. Phys. Vol.34, L797 (1995).
【3】S. Nakamura, M. Senoh, S. Nagahama, and N. Iwasa, “InGaN-Based Multi-Quantum-Well-Structure Laser Diodes”, Jpn. J. Appl. Phys. Vol.35, L74, (1996).
【4】M. S. Shur, “GaN Based Transistors for High Power Applications”, Solid-State Electronics, Vol. 42, pp. 2131 (1998).
【5】M. A. Khan, J. N. Kuznia, D. T. Olson, W. J. Schaff, J. W. Burm, and M. S. Shur, “Microwave performance of a 0.25 μm gate AlGaN/GaN heterostructure field effect transistor”, Appl. Phys. Lett. Vol. 65, pp. 1121 (1994).
【6】F. Ren, C. R. Abernathy, J. M. Van Hove, P. P. Chow, R. Hickman, J. J. Klaasen, R. F. Kopf, H. Cho, K. B. Jung, J. R. La Roche, R. G. Wilson, J. Han, R. J. Shul, A. G. Baca, and S. J. Pearton, “300°C GaN/AlGaN Heterojunction Bipolar Transistor”, MRS Internet J. Nitride Semicond. Res. Vol. 3, 41 (1998).
【7】M. A. Khan, J. N. Kuznia, A. R. Bhattarai, and D. T. Oslon, “Metal semiconductor field effect transistor based on single crystal GaN”,Appl. Phys. Lett. Vol. 62, pp. 1786 (1993).
【8】G. S. Nakamura, “InGaN-based violet laser diodes”, Semicond. Sci. Technol. Vol. 14, pp. R27 (1999).
【9】M. A. Khan, J. N. Kuznia, D. T. Olson, M. Blasingame, and A. R. Bhattarai, “Schottky barrier photodetector based on Mg-doped p-type GaN films”, Appl. Phys. Lett. Vol. 63, pp. 2455 (1993).
【10】X. Wang and A. Yoshikawa, “Molecular beam epitaxy growth of GaN, AlN and InN”, Prog.Cryst.Growth Charact.Mater. Vol. 48-49, pp.42 (2004).
【11】Yasushi Nanishi, Yoshiki Saito and Tomohiro Yamaguchi,“RF-Molecular Beam Epitaxy Growth and Properties of InN and Related Alloys”, Jpn. J. Appl. Phys. Part 1 Vol. 42, pp.2549(2003).
【12】J. Wu and W. Walukiewicz, “Band gaps of InN and group III nitride alloys”, Superlattices Microstruct. Vol. 34, 63 (2003).
【13】X. H. Wu, C. R. Elsass, A. Abare, M. Mack, S. Keller, P. M. Petroff, S. P. DenBaars, J. S. Speck, and S. J. Rosner, “Structural origin of V-defects and correlation with localized excitonic centers in InGaN/GaN multiple quantum wells” , Appl. Phys. Lett. Vol. 72, 6, pp.692 (1998).
【14】P. A. Crowell, D. K. Young, S. Keller, E. L. Hu, and D. D. Awschalom, “Near-field scanning optical spectroscopy of an InGaN quantum well”, Appl. Phys. Lett. Vol. 72, 8, pp. 927 (1998).
【15】M. S. Jeong, Y.W. Kim, J. O. White, E.K. Suh, M. G. Cheong, C. S. Kim, C.H. Hong, and H. J. Lee, “Spatial variation of Photoluminescence and related defects in InGaN/GaN quantum wells”, Appl. Phys. Lett. Vol.79, 21, pp. 3440 (2001).
【16】C. J. Sun, M. Zubair Anwar, Q. Chen, J. W. Yang, M. Asif Khan, M. S. Shur, A. D. Bykhovski, Z. Liliental-Weber, C. Kisielowski, M. Smith, J. Y. Lin, and H. X. Xiang, “Quantum shift of band-edge stimulated emission in InGaN–GaN multiple quantum well light-emitting diodes”, Appl. Phys. Lett. Vol.70, 22, pp. 2978 (1997)
【17】J. P. Liu, Y. T. Wang, H. Yang, D. S. Jiang, U. Jahn and K. H. Ploog,“Investigations on V-defects in quaternary AlInGaN epilayers”, Appl. Phys. Lett. Vol. 84, 26, pp. 5449 (2004).
【18】A. Hangleiter, F. Hitzel, C. Netzel, D. Fuhrmann, U. Rossow, G. Ade and P. Hinze, “Suppression of Nonradiative Recombination by V-Shaped Pits in GaInN/GaN QuantumWells Produces a Large Increase in the Light Emission Efficiency”, Phys. Rev. Lett. 95, 127402 (2005).
【19】史光國,“現代半導體發光及雷射二極體材料技術”, 全華科技圖書股份有限公司, p2 (2001)
【20】S. Yoshida, S. Misawa, and S. Gonda, “Improvements on the electrical and luminescent properties of reactive molecular beam epitaxially grown GaN films by using AlN-coated sapphire substrates”, Appl. Phys. Lett. Vol. 42,5, pp.427(1983).
【21】H. Amano, N. Sawaki, I. Akasaki, and Y. Toyoda , “Metalorganic vapor phase epitaxial growth of a high quality GaN film using an AlN buffer layer”, Appl. Phys. Lett. Vol.48,5, pp.353(1986).
【22】C. Y. Hwang, “Growth and Characterization of Gallium Nitride on (0001) sapphire by Plasma Enhanced Atomic Layer Epitaxy and by Low Pressure Metaloganic Chemical Vapor Deposition”,Ph.D. dissertation, Rutgers University, Piscataway, NJ (1995).
【23】S. Chichibu, T. Azuhata, T. Sota, and S. Nakamura, “Luminescences from localized states in InGaN epilayers”, Appl. Phys. Lett. Vol. 70, 21, pp. 2822 (1997).
【24】S.F. Chichibu, A.C. Abare, M. S. Minsky, S. Keller, S. B. Fleischer, J.E.Bowers, E. Hu, U. K. Mishra, L. A. Coldren, S. P. DenBaars, and T. Sato, “Effective band gap inhomogeneity and piezoelectric field in InGaN/GaN multiquantum well structures” Appl. Phys. Lett. Vol. 73, 14, pp. 2006 (1998).
【25】D. Behr, J.Wagner, A.Ramakrishnan, H. Obloh, and K.-H.Bachem,“Evidence for compositional inhomogeneity in low In content (InGa)N obtained by resonant Raman scattering",Appl. Phys.Lett. Vol.73,2, pp.241(1998).
【26】Y. Narukawa, Y. Kawakami, Sg. Fujita, and S. Nakamura,“Dimensionality of excitons in laser-diode structures composed of InxGa1-xN multiple quantum wells ”,Phys. Rev.B Vol.59, pp.10283 (1999).
【27】R. Zheng and T. Taguchi, “Stokes shift in InGaN epitaxial layers”, Appl. Phy. Lett. Vol.77,19, pp.3024 (2000).
【28】C. Cooper, D. I. Westwood, and P. Blood, “ Laser diodes in piezoelectric quantum-well structures”, Appl. Phys. Lett. Vol.69,16, pp.2415(1996).
【29】X. Zhang, S.-J. Chua, S. Xu, K. -B. Chong, and K. Onabe, “Optical property of a novel (111)-oriented quantum structure”, Appl.Phys. Lett. Vol.71, 13, pp.1840 (1997).
【30】G. Martin, A. Botchkarev, A. Rockett, and H. Morkoc, “Valence-band discontinuities of wurtzite GaN, AlN, and InN heterojunctions measured by x-ray photoemission spectroscopy”, Appl. Phys.Lett. Vol. 68,18, pp.2541 (1996).
【31】T. Takeuchi, S. Sota, M. Katsuragawa, M. Komori, H. Takeuchi, H. Amano, and I. Akasaki, “Quantum-Confined Stark Effect due to Piezoelectric Fields in GaInN Strained Quantum Wells”,Jpn. J. Appl. Phys. Vol. 36, L382, (1997).
【32】C. M. Lueng, H. L. W. Chan, C. Surya, and C. L. Choy, “Piezoelectric coefficient of aluminum nitride and gallium nitride”, J. Appl. Phys. Vol. 88,9, 5360 (2000).
【33】薛道鴻,“熱處理對氮化銦鎵量子井雷射結構之影響與壓電效應之分析”,國立中央大學物理研究所,碩士論文(2001).
【34】C. A. Parker, J. C. Roberts, S. M. Bedair, M. J. Reed, S. X. Liu, N. A. El-Masry, L. H. Robins, “ Optical band gap dependence on composition and thickness of InxGa1–xN (0<x<0.25) grown on GaN”,Appl. Phys. Lett. Vol.75,17, pp.2566 (1999).
【35】K. K. Smith, “Photoluminescence of Semiconductor Materials”, Thin Solid Films 84, 171-182, Oct. (1981).
【36】J. P. Wolfe and A. Mysyrowicz, “Excitonic Matter”, Sci. Am. 250, 98-107, March (1984).
【37】J. I. Pankove, “Optical Processes in Semiconductors”, Dover Publications, New York (1975).
【38】黃宏盛,林麗娟,“FE-SEM/CL/EBSD分析技術簡介”, 工業材料,201,99頁(2003)
【39】H. K. Cho, J. Y. Lee, and G. M. Yang, “Characterization of pit formation in III-nitrides grown by metalorganic chemical vapor deposition”,Appl. Phy. Lett., Vol. 80,8, pp.1370 (2002)
【40】Y. Chen, T. Takeuchi, H. Amano, I. Akasaki, N. Yamada,Y. Kaneko, and S. Y. Wang , “Pit formation in GaInN quantum wells”,Appl. Phy. Lett., Vol.72,6, pp.710 (1998)
【41】H. K. Cho, J. Y. Lee, G. M. Yang, and C. S. Kim, “Formation mechanism of V defects in the InGaN/GaN multiple quantum wells grown on GaN layers with low threading dislocation density”,Appl. Phy. Lett., Vol.79,2, pp.215(2001)
【42】H. K. Cho, J. Y. Lee, G. M. Yang, and C. S. Kim, N. Sharma and C. Humphreys, “Microstructural characterization of InGaN/GaN multiple quantum wells with high indium composition”, J. Cryst. Growth, Vol. 231,4, pp.466(2001)
【43】B. Pecz, Zs. Makkai, M. A. di Forte-Poisson,F. Huet, andR. E. Dunin-Borkowski, “V-shaped defects connected to inversion domains in AlGaN layers”,Appl. Phy. Lett., Vol.78,11, pp.1529 (2001)
【44】Y. Ono, Y. Iyechika, T. Takada, K. Inui, T. Matsue, “Reduction of etch pit density on GaN by InGaN-strained SQW”,J. Cryst. Growth 189/190, 133, (1998).
【45】D. A. B. Miller, D. S. Chemla, T. C. Damen, A. C. Gossard , W. Wiegmann, T. H. Wood and C. A. Burrus, “Electric field dependence of optical absorption near the band gap of quantum-well structures”, Phys. Rev. B Vol.32, pp 1043 (1985).
【46】F. Hitzel, G. Klewer, S. Lahmann, U. Rossow, and A. Hangleiter, Phys. Status Solidi C 1, 2520 (2004).