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研究生: 黃郁心
Huang, Yu-hsin
論文名稱: 成長於不同超晶格層上的氮化鎵/氮化銦鎵多重量子井之光學特性研究
Optical Properties of GaN/InGaN Multiple Quantum Wells Grown on Various Superlattice Underlayers
指導教授: 許進恭
Sheu, Jinn-kong
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年: 2007
畢業學年度: 95
語文別: 中文
論文頁數: 70
中文關鍵詞: 微光致螢光陰極射線螢光氮化鎵超晶格
外文關鍵詞: micro-PL, CL, superlattice, GaN
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  • 本文以有機金屬氣相沈積法(metalorganic chemical vapor-phase deposition, MOCVD)在(0001)方向的藍寶石基板(sapphire)上成長氮化鎵/氮化銦鎵及氮化鎵/氮化鋁鎵超晶格結構,並分別成長氮化鎵/氮化銦鎵多重量子井於兩種超晶格結構上,我們利用原子力顯微鏡(AFM)、掃瞄式電子顯微鏡(SEM)來觀察表面,並使用陰極射線螢光光譜(CL)、微光致螢光光譜(micro-PL)來研究在不同超晶格結構上所成長之氮化鎵/氮化銦鎵量子井之發光特性。由原子力顯微鏡、掃瞄式電子顯微鏡量測結果可知,表面分佈許多六角型凹洞,一般所通稱之為V-defect,其V型缺陷的大小約為100nm。此外,微光致螢光光譜的結果可知,成長在氮化鎵/氮化鋁鎵超晶格結構上的多重量子井有較高之發光效率。

    This thesis aims at fabricating and characterizing of GaN/InGaN multiple quantum wells(MQWs)grown on GaN/InGaN or GaN/AlGaN superlattice underlayer, which were grown by MOCVD on(0001)sapphire substrates. Surface morphologies of these samples were examined by atomic force microscope (AFM)and scanning electron microscope(SEM). The optical properties of GaN/InGaN MQWs grown on various superlattice underlayers were investigated by cathodoluminescence(CL)and micro-photoluminescence (micro-PL). The AFM and SEM images showed open hexagonal inverted pyramids on the(0001)plane of the epi-wafer surfaces, the so-called “V-defect”, and the feature size of the V-defect is about 100 nm. Furthermore, the micro-PL revealed that GaN/InGaN MQWs grown on GaN/AlGaN superlattice underlayer have higher luminescence efficiency.

    中文摘要 I 英文摘要 II 致 謝 III 目 錄 IV 表 目 錄 VII 圖 目 錄 VIII 第一章 序論 1 1.1 前言 1 1.2 研究背景 3 1.3 研究動機 3 第二章 理論背景 6 2.1 氮化鎵材料發展 6 2.2 氮化鎵的晶體結構 6 2.3 氮化鎵材料特性 8 2.3.1 應力的產生 8 2.3.2 Stokes shift 9 2.3.3 壓電效應(Piezoelectric effect) 10 2.3.4 由發光光譜之波峰值計算氮化銦鎵之銦含量 11 第三章 實驗方法 13 3.1 樣品的製備 13 3.2 樣品表面分析 17 3.2.1 原子力顯微鏡(Atomic force microscopy, AFM) 17 3.2.3 掃描式電子顯微鏡(Scanning Electron Microscopy, SEM) 21 3.3 光學性質分析 23 3.3.1 光致螢光(photoluminescence, PL) 23 3.3.2 微光致螢光(µ-PL)系統裝置 25 3.3.3 陰極射線螢光(Cathodoluminescence, CL)原理 29 第四章 結果與分析討論 32 4.1 氮化鎵/氮化銦鎵多重量子井成長於氮化鎵/氮化銦鎵超晶格結構 32 4.1.1 掃描式電子顯微鏡(SEM)量測圖 32 4.1.2 原子力顯微鏡(AFM)量測圖 33 4.1.3 微光致螢光(µ-PL)光譜圖 38 4.2 氮化鎵/氮化銦鎵多重量子井成長於氮化鎵/氮化鋁鎵超晶格結構 39 4.2.1 掃描式電子顯微鏡(SEM)量測圖 39 4.2.2 原子力顯微鏡(AFM)量測圖 40 4.2.3 微光致螢光(µ-PL)光譜圖 44 4.3 氮化鎵/氮化銦鎵多重量子井結構成長於不同超晶格結構之比較 45 4.3.1 掃描式電子顯微鏡(SEM)量測圖 45 4.3.2 原子力顯微鏡(AFM)量測圖 45 4.3.3 微光致螢光(µ-PL)光譜圖 48 4.3.4 陰極射線螢光(CL)光譜與影像圖 50 第五章 結論與未來展望 62 5.1 結論 62 5.2 未來展望 63 參考文獻 64

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