不同原油提煉之瀝青於鋪面績效之影響扮演著重要的角色，黏結料則須加以分析，使瀝青應具有合適的功能性，提供道路耐久性以及行車舒適度。本研究主要是針對不同原油來源煉製而成之減壓油渣(VR)進行取樣試驗，並添加重減壓油(HVGO)、吹製瀝青之樣本，分別進行物性與化性試驗。物性方面透過瀝青膠泥基本物性試驗以及動態剪切流變儀(DSR)取得各項質流參數；化性方面則利用傅立葉轉換紅外線光譜儀(FT-IR)、薄層液相層析法之火焰離子檢視器(TLC-FID)以及高效能凝膠滲透層析儀(HP-GPC)分別探討瀝青材料官能基、化學成分以及分子大小分佈，接續進行實驗室模擬短期老化試驗，再將老化瀝青膠黏結劑依照新鮮瀝青黏結劑物性與化性試驗作業。最後，綜合上述試驗結果，分析物理性質與化學特性之間的相關性。
瀝青黏結劑主要以飽和族(saturate)、芳香族(aromatic)、膠質(resin)以及瀝青精(asphaltene)所組成，組分組成比例影響VR物理特性，於初期老化時輕質組分中芳香族產生化學變化轉變成膠質，再由膠質轉變為瀝青精，且於老化過程中主要增加的官能基為酮(ketones)與亞碸(sulfoxide)，這些官能基係因化學成分的降解以及氧化作用而生成，酮與亞碸的增加意味著膠體結構中極性分子(瀝青精、膠質)增多，使分子間凝聚力增加而影響瀝青黏結料的質流性質，以致材料趨向脆性行為。最後本研究以物理特性為依據進行摻配，當摻配成品擁有相同的黏滯度或針入度時，軟瀝青摻配吹製瀝青者於瀝青精指數指數(IA)以及廣分布指數(PDI)值皆高於硬瀝青摻配重減壓油者，則膠體不穩定指數(IC)大致相同，但經短期老化之老化指數為硬瀝青摻配重減壓油者較高，是因為膠體之化學轉變較顯著，導致物理特性變異較大。

Asphalt from different crude oil plays an important role on pavement performance, in order to make asphalt have suitable functionality, provide road durability and driving comfort by analyzing asphalt.
In this study, sampling different crude oil refining vacuum residues (VR) for test, and adding heavy vacuum gas oil (HVGO), blown asphalt, were subjected to physically and chemically characteristic test respectively. Physical part of asphalt by basic physical test, and dynamic shear rheometer (DSR) to obtain the mass flow parameters; Chemical properties by Fourier transform infrared spectroscopy (FT-IR), Thin-layer Chromatography Flame lionization Detector (TLC-FID) and High performance gel permeation chromatography (HP-GPC), discussed asphalt functional groups, chemical composition and molecular size distribution respectively. Succeeding term aging tests in laboratory simulations, then follow fresh asphalt physical properties and chemical testing operations. Finally, combining the above test results, analysis the correlation between physical and chemical properties
Asphalt is mainly composed of saturate, aromatic, resin and asphaltene. the composition ratio of VR affected physical properties. In the early aging of aromatic transferred to resin by chemical change, and then resin changes into the asphaltene, and the functional group of ketones and sulfoxide have major increase in the aging process , ketone and sulfoxide increase means that the colloidal structure of polar molecules (asphaltene, resin) increased.
Finally, the study base on physical characteristics for mixing, when mixing sample with the same viscosity or penetration, the Asphaltene Index (IA), and Polydispersity Index (PDI) values of Soft asphalt blending air blown asphalt were higher than the hard asphalt blending heavy vacuum gas oil. In the other hand, Colloidal instability Index (IC) are almost the same. However, the Aging Index (AI) of short-term aging is higher than the hard asphalt blending heavy vacuum gas oil. Because the chemical characteristic of colloid changes significantly, physical properties varied greatly.

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