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研究生: 蕭擁丁
Hsiao, Yung-Ding
論文名稱: 高分子改質瀝青型態對工程性質之影響
Effect of Morphology on Engineering Properties of Polymer-Modified Asphalt
指導教授: 陳建旭
Chen, Jian-Shiuh
學位類別: 碩士
Master
系所名稱: 工學院 - 土木工程學系
Department of Civil Engineering
論文出版年: 2017
畢業學年度: 105
語文別: 中文
論文頁數: 105
中文關鍵詞: SBS改質瀝青微觀形態學(Morphology)離析
外文關鍵詞: SBS Modified Asphalt, Morphology, Storage Stability
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  • 瀝青檢驗時程通常繁瑣耗時,為節省成本及維護品質,本研究期望透過改質瀝青型態(Morphology),找出與工程性質之關聯,達到提升改質瀝青工程品質之目的。本研究透過分析高分子材料(SBS)添加之瀝青的微觀型態,探討改質瀝青的工程性質,接著評估改質瀝青微觀特徵,並且加以分類。研究材料包含線型及星型的SBS,以1%~5%的添加量與基底瀝青混拌,以不同養治溫度製成試樣後,透過光學顯微鏡觀察微觀型態,利用影像分析軟體計算出SBS分布面積比例,進而分析型態與工程性質之關係。結果顯示高分子改質瀝青性質受到型態影響,同時,養治溫度對SBS改質瀝青型態影響明顯,SBS溶脹至原來體積之2~8倍;養治溫度180°C下呈現的微觀型態,與離析程度有相當高的關聯性。型態圖說明改質瀝青的微觀型態,建議於不同養治溫度下進行觀察,單一溫度下的微觀型態並不能代表改質瀝青的整體型態。

    In order to improve the quality of polymer-modified asphalt (PMA), this study was expected to find out the relationship between the morphology of PMA and engineering properties. In this study, the engineering properties of PMA were investigated by analyzing the morphology of PMA with SBS, and then the morphology of PMA was evaluated and classified. The material in this study contains two kinds of SBS (linear and radial). The samples were prepared by mixing 1% to 5% with the base asphalt. After the samples were prepared at different conditioning temperature, the morphology was observed by optical microscope. Then, Using the image analysis software to calculate the proportion of SBS distribution area, and analyzing the relationship between the morphology and engineering properties. The results showed that the properties of PMA were affected by the morphology. At the same time, the effect of conditioning temperature on SBS PMA was obvious, SBS was also swollen to the original volume of 2 ~ 8 times. Finally, the morphology under the conditioning temperature of 180°C showed a high relevance with storage stability.

    目錄 摘要 I 英文延伸摘要 II 誌謝 V 目錄 VII 表目錄 XI 圖目錄 XII 第一章 緒論 4.1 前言 1-1 4.2 研究動機 1-2 4.3 研究目的 1-3 4.4 研究範圍 1-3 第二章 文獻回顧 2.1 瀝青簡介 2-1 2.2 改質瀝青 2-2 2.3 改質劑 2-2 2.3.1 聚合物改質瀝青(PMA) 2-4 2.3.2 苯乙烯–丁二烯–苯乙烯(SBS) 2-6 2.3.3 SBS改質瀝青的相容性 2-6 2.4 改質瀝青相轉換(phase inversion) 2-8 2.5 穩定劑-硫 2-8 2.6 形態學(Morphology) 2-9 2.7 螢光顯微鏡(Fluorescence microscopy) 2-9 第三章 研究計畫 3.1 研究流程 3-1 3.2 試驗材料 3-3 3.2.1 基底瀝青 3-3 3.2.2 高分子改質劑 3-4 3.2.3 穩定劑 3-5 3.3 改質瀝青 3-5 3.3.1 改質劑與穩定劑添加比例 3-5 3.3.2 改質瀝青拌和程序 3-6 3.3.3 改質瀝青物性試驗 3-8 3.4 微觀型態分析 3-17 3.4.1 微觀試樣製作方法 3-17 3.4.2 微觀影像分析 3-18 第四章 結果與討論 4.1 試驗材料基本物性 4-1 4.1.1 AC-10瀝青黏結料 4-1 4.1.2 高分子改質劑SBS 4-2 4.2 SBS改質瀝青物性 4-3 4.2.1 SBS改質瀝青針入度 4-4 4.2.2 SBS改質瀝青軟化點 4-5 4.2.3 SBS改質瀝青黏度 4-6 4.2.4 質流性質 4-8 4.3 型態與工程性質 4-10 4.3.1 SBS分布面積比例 4-10 4.3.2 SBS面積與工程性質 4-12 4.3.3 溫度對改質瀝青型態之影響 4-16 4.3.4 改質瀝青於養治溫度下之型態 4-19 4.3.5 SBS型態與質流性質 4-30 4.4 改質瀝青微觀 4-32 4.4.1 微觀型態的可逆性 4-32 4.4.2 拌和時間對SBS改質瀝青微觀之影響 4-34 4.4.3 離析之型態 4-35 4.4.4 螢光光源下微觀分析 4-37 4.5 改質瀝青型態分類 4-39 4.5.1 瀝青連續相 4-41 4.5.2 聚合物連續相 4-42 4.5.3 兩相互鎖 4-43 4.5.4 聚合物消失相 4-44 第五章 結論與建議 5.1結論 5-1 5.2建議 5-2 參考文獻 參-1 附錄 附-2  

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