對於以電漿子奈米晶體和高分子組成的奈米複合材料，電漿子奈米晶體周圍的電漿子奈米晶體誘導電磁場可以用於改變其周圍的介電環境，從而調控奈米複合材料的光學（電漿子共振）和電學（導電率）特性。這些性質主要可經由改變包覆在電漿子奈米晶體上的配體和基質之高分子的導電率來控制，其原因為在電漿子誘導電磁場下，奈米複合材料之”局部”(奈米晶體附近)和”整體”介電環境之改變。奈米複合材料的”局部”和”整體”介電環境的變化是由電漿子奈米晶體周圍配體和/或高分子基質的分子鏈重新排列引起的。此介電環境可由下列三個參數進行調整：(1)高分子基質中的奈米晶體的含量；(2)形成奈米晶體複合材之奈米晶體上的配體與高分子基質之導電率；(3)電漿子誘導電磁場的強度。奈米複合材料的光學特性取決於奈米複合材料的”局部”和”整體”介電環境，這使其在電漿子誘導的電磁場下電漿子共振波長(藍移約10 nm)發生顯著變化。然而奈米複合材料的電學性質僅取決於電漿子誘導電磁場下奈米複合材料的”整體”介電環境。在導電高分子基質中生成的奈米複合材料在電漿子誘導電磁場下，其導電率增加三個數量級(從4x10-14到10-10 S/cm)。
　　藉由電漿子誘導電磁場改變奈米複合材性質之現象，可因為二聚體奈米結(dimer nanojunctions)所產生之耦合效應(coupling effect)而進一步增強，此源自於在電漿子誘導電磁場下之二聚體奈米結周遭之配體與高分子基質重新排列，導致電漿子奈米晶體之間的間距改變所造成。二聚體奈米結中奈米晶體之間的間距的變化，可導致拉曼訊號顯著改變，但此間距之變化不足以使二聚體奈米結的電漿子響應產生顯著之變化。電漿子誘導電磁場下二聚體奈米結中拉曼訊號的增強因子強烈依賴於以下參數：(1)二聚體奈米結的構象(垂直二聚體或水平二聚體)；(2)用於製造二聚體奈米結之奈米晶體之配體或/和基質的導電率；(3)電漿子誘導電磁場的強度。在高導電性之配體(HS-PVK)包覆的AgNCs和高導電性基質(PVK)組成的二聚體奈米結，在外部刺激下其拉曼訊號增強因子可達~500%。
　　在外部刺激下具有高度靈敏的光學和電學響應的高分子-電漿子奈米晶體複合材料和對拉曼訊號有高度敏感響應的高分子-二聚體奈米結複合材料非常適合應用於”電磁場”或”光子”傳感器。

For nanocomposites composed of plasmonic nanocrystals and polymer, the plasmonic nanocrystal induced electromagnetic field around the plasmonic nanocrystals can be used to change the surrounding dielectric environment to tune the optical (plasmonic resonance) and electrical (electrical conductivity) properties of nanocomposites. These properties are mainly controlled by the conductivity of the ligand (coated on plasmonic nanocrystals) and polymer matrix, which led to change the “local” (near the nanocrystal) and “overall” dielectric environment of nanocomposites under plasmon-induced electromagnetic field. The changes in the “local” and “overall” dielectric environments of nanocomposites were caused by the rearrangement of molecular chains of ligand and/or polymer matrix around plasmonic nanocrystals. This dielectric environment can be adjusted by the following three parameters : (1) the content of nanocrystals in the polymer matrix ; (2) the conductivity of the ligand and/or polymer matrix for fabrication of nanocomposite ; (3) the strength of the plasmon-induced electromagnetic field. The optical properties of the nanocomposites depended on the” local” and “overall” dielectric environment of the nanocomposite, which showed a significant change in the plasmon resonance wavelength (blue-shift about 10 nm) under plasmon-induced electromagnetic field. However, the electrical properties of nanocomposites depended only on the “overall” dielectric environment of the nanocomposite under plasmon-induced electromagnetic field. The nanocomposites were constructed in the conducting polymer matrix that resulted in three orders of magnitude increase in the electrical conductivity (from 4 x 10-14 to 10-10 S/cm) of nanocomposites under plasmon-induced electromagnetic field.
　　Changing the properties of nanocomposites under plasmon-induced electromagnetic field can be enhanced by the plasmonic coupling effect, which was caused by plasmonic dimer nanojunction. The rearrangement of the ligands of the nanocrystals and the polymer matrix around dimer nanojunctions under plasmon-induced electromagnetic field resulted in the change of the spacing between the plasmonic nanocrystals. The changes in the spacing between nanocrystals in dimer nanojunctions can lead to a significant increase in Raman signals. However, the changes in spacing cannot cause a significant change in the plasmonic response of nanocomposite. The enhancement factor of the Raman signal of nanocomposite under the plasmon-induced electromagnetic field strongly depended on the following parameters : (1) the conformations of the dimer nanojunction (vertical dimer and horizontal dimer) ; (2) the electrical conductivity of ligands and/or polymer matrix for fabrication of dimer nanojunction ; (3) the strength of plasmon-induced electromagnetic field. For dimer nanojunction composed of high conductivity ligand (HS-PVK) coated AgNCs and high conductivity matrix (PVK), the Raman signal enhancement factor of dimer nanojunctions under external stimulus can reach about 500%.
　　Polymer-plasmonic nanocrystal composites with highly sensitive optical and electrical responses to external stimuli and polymer-dimer nanojunction composites with highly sensitive responses to Raman signals are very suitable for “electromagnetic field” or “photonic” sensor applications.

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