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研究生： 蘇家慧
Su, Chia-Hui
論文名稱： 低損耗與低溫燒結微波介電材料之開發
Development of Low-Loss and Low Temperature Sintered Microwave Dielectric Materials
指導教授： 黃正亮
Huang, Cheng-Liang
學位類別： 博士
Doctor
系所名稱： 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年： 2016
畢業學年度： 104
語文別： 英文
論文頁數： 147
中文關鍵詞： 微波介電材料 、低損耗 、低溫
外文關鍵詞： Microwave dielectric properties, Low-loss, Low-temperature
相關次數： 點閱：112  下載：1 
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    • 近年來，由於微波通訊系統的演進及發展，微型化、高效能和低成本已經成為微波元件的主要需求。微波介電共振器需具有高介電常數、高品質因素及趨近於零的溫度頻率飄移係數等特性，適合用於介質共振天線、濾波器、震盪器和雙工器。因此，高品質因素介電材料常應用於通訊系統中。由於具有低損耗的特性表現，也常設計於高效能微波元件上。然而，高介電常數陶瓷材料亦可達到微型化的目的，所以材料的選擇也是相當重要的課題。最後，穩定的溫度飄移係數讓我們在使用上不易受溫度影響。另外，低溫製程同時可降低成本以利大量生產。針對以上所述，本論文將以兩個部分加以探討及研究

    In recent years, the wireless communication industry has experienced enormous growth, the microwave dielectric resonators (DR) having a high dielectric constant, high quality factor and near-zero temperature coefficient of resonant frequency and other features, suitable for a dielectric resonator, filters, oscillators, and duplexers. Due to the miniaturized, high performance and low cost has become the main demand of the microwave components, the high quality factor dielectric material often used in communications systems. As mentioned above, the main study of this dissertation is divided two parts which preparation of low loss and low temperature sintered of the microwave dielectric properties.

    摘要 I Acknowledgement VI Contents VIII Table Captions X Figure Captions XII Chapter 1 Introduction 1 Chapter 2 Theory 6 2-1 Introduction of Structure 6 2-1-1 Spinel Structure 8 2-1-2 Zircon-type 8 2-1-3 Quasi-one-dimensional (Q1D) 8 2-2 Theory of Sintering 10 2-2-1 Solid-State Sintering 10 2-2-1-1 Driving Forces 10 2-2-1-2 Stages of Sintering 11 2-2-1-3 Mechanisms of Sintering 11 2-3 GSAS 14 2-4 Theory of Microwave Dielectric Properties 16 2-4-1 Dielectric Constant, εr 16 2-4-2 Quality Factor, Q × f 23 2-4-3 Temperature Coefficient of Resonant Frequency, τf 25 2-5 Dielectric Resonator 26 2-6 Measurement of Microwave Dielectric Properties 29 Chapter 3 Development of Low Loss Microwave Dielectric Materials 34 3-1 Li-Based-Li2ATi3O8 34 3-1-1 Introduction 34 3-1-2 Experiment Procedures 36 3-2 Results and Discussion 39 3-2-3 Li2(Mg1–xCox)Ti3O8 ceramics (A2+ = Zn, Co and x = 0.02–0.1) 39 3-2-4 Li2(Zn1–xAx)Ti3O8 (A = Mg, Co and x = 0.02–0.1) 58 Chapter 4 Investigation of the Microwave Dielectric Properties of Li2ZnTi5O12 Ceramics 70 4-1 Introduction 70 4-2 Experimental Procedures 71 4-3 Results and Discussion 73 Chapter 5 Characterization and Microwave Dielectric Properties of Mg2YVO6 Ceramic 91 5-1 Introduction 91 5-2 Experimental Procedures 92 5-3 Results and Discussion 94 Chapter 6 Structural Characteristics and Microwave Dielectric Properties of Low-Firing Ba(Co1-xMgx)2(VO4)2 (x = 0–1) Ceramics 107 6-1 Introduction 107 6-2 Experimental Procedures 109 6-3 Results and Discussion 111 Chapter 7 Conclusions 127 Reference 130

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