傳統的有機染料敏化太陽能電池利用液態當作電解質，然而液態電解質在應用上有些問題，例如：電解質的洩漏及蒸散、電池穩定低無法長時間使用，因此利用高分子膠化劑膠化液態電解質形成膠態電解質，以解決上述問題。本研究將利用PVDF-HFP此高分子膠化液態電解質，並選擇適當的濃度(10 wt%)。然而此膠態電解質所組成的染料敏化太陽能電池其光電轉換效率低於液態電解質所組染料敏化太陽能電池，因此在膠態電解質裡添加奈米粒子(nano-filler)TiO2而其濃度為12 wt%，藉此提升電流密度(Jsc)，以提高光電轉換效率，其效率可以高於液態電解質所組成的染料敏化太陽能電池的效率。然而電池在長時間使用的穩定性上膠態電解質比液態電解質來的穩定，但在高溫之下以acetonitrile (ACN)當作溶劑的膠態電解質其熱穩定性不佳，故利用3-Methoxypropionitrile (MPN)和acetonitrile (ACN)以共溶劑方法(co-solvent)提升在高溫下熱穩定性，當ACN/MPN =7/3重量比例下，其電池在高溫下具有較好熱穩定性，其電池效率與ACN相比並沒有明顯下降。
在此研究裡染料方面將利用D149/SQ2雙成分染料系統以增加吸光範圍，或是染料單分子層填補缺陷機制的作用下可抑制激發電子與電解質的再結合，進而提升光電轉換效率。而在D149/SQ2=10/1時具有較高電流密度(Jsc)及光電轉換效率，可歸因於電池元件可以增加吸光範圍以及有效抑制激發電子與電解質的再結合。

Although classical dye-sensitized solar cells (DSSCs) with liquid-state electrolyte reach relatively high overall efficiency,there are some pratical probiems with liquid-state electrolyte. For example: solvent evaporation and leakage of the liquid electrolyte and poor stability for long-term used. Therefore, the co-polymer—PVDF-HFP was used to gel liquid electrolyte to become gel-stste electrolyte in order to solve the pratical problems. In this study, PVDF-HFP was used to be gelator and found out the optimum concertration (10 wt%). However, the efficiency of gel-state DSSCs are lower than liquid-state DSSCs, the nano-fillers(12 wt%) were added to the gel-state electrolyte to enhance the current density (Jsc) of the cells that could increase the effiency of gel-state DSSCs higher than liquid-state DSSCs. However, the thermal stability of gel-state DSSCs with ACN as the solvent is poor. ACN and MPN were mixed with the different weight ratio to improve the thermal stability by the co-solvent approach. When the weight ratio of ACN/MPN is 7/3,the thermal stability of the gel-state DSSCs are better than ACN and ACN/MPN= 9/1. The efficiency of gel-state DSSCs with co-solvent, ACN/MPN = 7/3,are almost the same with gel-state DSSCs with ACN as the solvent.
In this study, D149/SQ2 dye cocktails were applied in gel-state DSSCs to enhance the light harvest or the defects-filling mechanism of the dye to inhibit the recombination between electron and hole that could enhance the efficiency of gel-state DSSCs. When the ratio of D149 and SQ2 is 10 to1, the current density and efficiency of the gel-state DSSCs have higher value that could attribute to increase the light harvest and inhibit the recombination between excited electron and electrolyte.

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