| 研究生: |
張雅淇 Chang, Ya-Chi |
|---|---|
| 論文名稱: |
應用雙噴頭3D列印與脫脂燒結技術於雙金屬零件製造 Application of Dual-Nozzle 3D Printing and Debinding Sintering Techniques for Bi-Metal Part Fabrication |
| 指導教授: |
鄭金祥
Cheng, Chin-Hsiang |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 航空太空工程學系 Department of Aeronautics & Astronautics |
| 論文出版年: | 2025 |
| 畢業學年度: | 113 |
| 語文別: | 中文 |
| 論文頁數: | 136 |
| 中文關鍵詞: | FDM 、脫脂燒結 、雙金屬 、複合線材 、銅 、不鏽鋼 |
| 外文關鍵詞: | FDM, debinding and sintering, bimetal, composite filament, copper, stainless steel |
| 相關次數: | 點閱:17 下載:3 |
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本研究結合雙噴頭 FDM 3D 列印與脫脂燒結技術,開發銅-不鏽鋼雙金屬零件的製造流程。使用銅粉末含量 87-90 wt%與316L不鏽鋼粉末含量90 wt%之複合線材,探討燒結溫度(1273 K、1473 K、1598 K)、燒結時間(1、2、3小時)、幾何構型(包裹型、疊層型、交叉型)、排氣通道設計及加壓條件對成品的影響。熱物性分析結果顯示銅-不鏽鋼複合材料的熱傳導係數介於純不鏽鋼與銅之間,相較於純不鏽鋼提升了2.5倍。確定1598 K為最適燒結溫度,但發現3小時燒結雖能實現最充分界面擴散但導致過度燒結,1小時燒結保持良好外型但界面結合較弱。加壓燒結技術能顯著改善燒結效率與品質,在1339 N⸱m-2壓力下,疊層型試片1小時燒結獲得優異的外觀品質與機械性能。最佳製程參數組合為:疊層型設計、1598 K燒結溫度、1小時加壓燒結,此條件下複合材料楊氏係數達16.048 GPa,最大應力達100.727 MPa。本研究成功以FDM製程製備銅-不鏽鋼雙金屬零件,並發現孔洞形成的主要成因為燒結過程銅蒸發。為雙金屬積層製造提供了另一種可能的方法。
This study developed a manufacturing process for copper-stainless steel bi-metallic components to combine high thermal conductivity with mechanical strength using dual-nozzle FDM 3D printing and debinding sintering techniques. Two types of composite filaments were used: one containing 87-90 wt% copper powder, and the other containing 90 wt% 316L stainless steel powder. These materials were investigated under varying sintering temperatures (1273-1598 K), sintering durations (1-3 hours), geometric configurations, and pressurized conditions. The optimal parameters-layered design, 1598 K sintering temperature, and 1-hour pressurized sintering (1339 N⋅m-2)-achieved Young's modulus of 16.048 GPa, maximum stress of 100.727 MPa, and thermal conductivity 2.5 times higher than pure stainless steel. Copper evaporation during sintering was identified as the primary cause of void formation. This research provides an alternative approach for bi-metallic additive manufacturing.
[1] S.Y. Karaoglu, S. Karaoglu, and I. Unal, "Aerospace industry and aluminum metal matrix composites," International Journal of Aviation Science and Technology, Vol. 2, No. 2, pp. 73-81, 2021.
[2] G. R. Joshi, V.J. Badheka, R.S. Darji, A.D. Oza, V.J. Pathak, D.D. Burduhos-Nergis, D.P. Burduhos-Nergis, G. Narwade, and G. Thirunavularasu, "The joining of copper to stainless steel by solid-state welding processes: a review," Materials, Vol. 15, No. 20, 7234, 2022.
[3] C. Gao, S. Wolff, and S. Wang, "Eco-friendly additive manufacturing of metals: energy efficiency and life cycle analysis," Journal of Manufacturing Systems, Vol. 60, pp. 459-472, 2021.
[4] B.D. Bock, K. Pretorius, and S. Scott, "3D printing for heat transfer: characterisation of additive manufactured copper," in Proc. MATEC Web Conf., Vol. 388, 8004, 2023.
[5] W. Ahmed, A.H. Al-Marzouqi, M.H. Nazir, T.A. Rizvi, E. Zaneldin, M. Khan, and M. Aziz, "Investigating the properties and characterization of a hybrid 3D printed antimicrobial composite material using FFF process: innovative and swift," International Journal of Molecular Sciences, Vol. 24, No. 10, p. 8895, 2023.
[6] P.D. Torino, "Characterization of metal FDM process and final mechanical performances evaluation," M.S. thesis, Dept. Mech. Aerosp. Eng., Med. Univ. Vienna, Vienna, Austria, 2022.
[7] M.Q. Shaikh , S.D. Nath, A.A. Akilan, S. Khanjar, V.K. Balla , G.T. Grant, and S.V. Atre, "Investigation of patient-specific maxillofacial implant prototype development by metal fused filament fabrication (MF3) of Ti-6Al-4V," Dentistry Journal, Vol. 9(10), No. 109, 2021.
[8] 陳映兆, 利用3D列印硼矽玻璃粉末摻合聚乳酸之複合材料的製程研究, 國立成功大學航空太空工程研究所碩士論文, 台灣, 2022。
[9] M. Drummond, A. Eltaggaz, and I. Deiab, "3D printing of high melting iron alloys using metal-fused deposition modeling: a comprehensive review," International Journal of Advanced Manufacturing Technology, Vol. 129, No. 1-2, pp. 1-22, 2023.
[10] J. Velásquez, M. Fuentealba, and M. Santibáñez, "Characterization of radiation shielding capabilities of high concentration PLA-W composite for 3D printing of radiation therapy collimators," Polymers, Vol. 16, No. 6, p. 769, 2024.
[11] M. Bauzá, N. Munar, A. Figuerola, G.T. Palomino, and C.P. Cabello, "Multifunctional HKUST-1-3D-printed device for the simultaneous extraction of hydrocarbons and dyes from water," Journal of Water Process Engineering, Vol. 58, p. 104890, 2024.
[12] J.-F. Silvain, D.L. Gifford, S. Fourcade, L. Cuzacq, J.-L. Grosseau-Poussard, C. Debiemme-Chouvy, N.T. Doyen, and Y. Lu, "Study on debinding and sintering conditions in extrusion-based additive manufacturing of 316L and 316L + Cu," Metals, Vol. 13, No. 11, p. 1858, 2023.
[13] G. Chang, X. Zhang, F. Ma, C. Zhang, and L. Xu, "Printing, debinding and sintering of 15-5PH stainless steel components by fused deposition modeling additive manufacturing," Materials, Vol. 16, No. 19, p. 6372, 2023.
[14] C.-H. Cheng, C.-C. Loh, and Y.-J. Zhang, "Simulation of metallic parts by 3D printing using metallic powder–polylactide composite filament," Progress in Additive Manufacturing, Vol. 7, No. 3, pp. 495-508,2022.
[15] R. Rafael and P.K. Chan, "Copper composites and laser sintering: novel hybridization method for 3D printed electronics," Advanced Materials Technologies, Vol. 8, No. 11, 2201900, 2023.
[16] 羅紹瑋, 3D列印不鏽鋼粉末摻合聚乳酸之複合線材之製程研究, 國立成功大學航空太空工程研究所碩士論文, 台灣, 2022。
[17] C.-H. Cheng, Y.-J. Zhang and C.-C. Loh, “A comprehensive evaluation of metallic parts produced by 3D printing with metallic powder-polylactide composite filament,” to appear in Journal of Materials Engineering and Performance. (Accepted July 10, 2025).
[18] X. Wei, X. Li, and R. Bähr, "Optimizing metal part distortion in the material extrusion-thermal debinding-sintering process: an experimental and numerical study," Heliyon, Vol. 10, No. 7, e28899, 2024.
[19] J.E. Montes-Ramirez, A. Lopez, M.S. Hassan, J. Munoz, S. Arroyo, C. Marquez, S. Zaman, A. Nunez, M.S. Mahmud, A. Gandara, and Y. Lin, "Shrinkage and deformation compensation in metal fused filament fabrication (mf3) sintered copper components using 3D scanning and inverse deformation," Journal of Manufacturing Processes, Vol. 121, pp. 9-19, 2024.
[20] X. Zhang, T. Pan, A. Flood, Y. Chen, Y. Zhang, and F. Liou, "Investigation of copper/stainless steel multi-metallic materials fabricated by laser metal deposition," Materials Science & Engineering. A, Vol. 811, p. 141071, 2021.
[21] P.R. Gradl, S.E. Greene, and T. Wammen, "Bimetallic channel wall nozzle development and hot-fire testing using additively manufactured laser wire direct closeout technology," in Proc. 55th AIAA/SAE/ASEE Joint Propul. Conf., Indianapolis, IN, USA, 2019.
[22] B. Onuike and A. Bandyopadhyay, "Additive manufacturing of inconel 718 – Ti6Al4V bimetallic structures," Additive Manufacturing, Vol. 22, pp. 844-851, 2018.
[23] B. Onuike, B. Heer, and A. Bandyopadhyay, "Additive manufacturing of inconel 718—copper alloy bimetallic structure using laser engineered net shaping (LENS™)," Additive Manufacturing, Vol. 21, pp. 133-140, 2018.
[24] K. Lee, V.V. K. Doddapaneni, S. Mirzababaei, S. Pasebani, C.H. Chang, and B.K. Paul, "Multi-metal additive manufacturing of selectively doped 316 L stainless steel-copper composite using hybrid laser powder bed fusion," Additive Manufacturing, Vol. 86, 104202, 2024.
[25] P. Ferro, A. Fabrizi, H. Elsayed, and G. Savio, "Multi-material additive manufacturing: creating IN718-AISI 316L bimetallic parts by 3D printing, debinding, and sintering," Sustainability (Basel, Switzerland), Vol. 15, No. 15, p. 11911, 2023.
[26] Homepage of The Virtual Foundry. https://thevirtualfoundry.com/ [Accessed: July 1, 2025].
[27] "Ultrafuse 316L user guidelines for 3D printing metal parts," BASF, Ludwigshafen, Germany, 2021. https://forward-am.com/wp-content/uploads/2021/04/UserGuidelines_2021_03_29.pdf [Accessed: July 15, 2025].
[28] Homepage of Ultimaker. https://support.makerbot.com/s/ [Accessed: July 15, 2025].
[29] Homepage of Bueler. https://www.buehler.com/ [Accessed: July 1, 2025].
[30] Homepage of NETZSCH. https://www.netzsch.com/en [Accessed: July 15, 2025].
[31] W.J. Parker, R.J. Jenkins, C.P. Butler, and G.L. Abbott, "Flash method of determining thermal diffusivity, heat capacity, and thermal conductivity," Journal of Applied Physics, Vol. 32, No. 9, pp. 1679-1684, 1961.
[32] Homepage of Hot Disk Instruments. https://www.hotdiskinstruments.com/ [Accessed: July 15, 2025].
[33] F. Cucinotta, G.D. Bella, M. Raffaele, and F. Salmeri, "A Design Strategy for Removing the Debinding and Sintering Gas in Additive Manufactured Samples of a Bronze/Polylactic Acid Filament," Advanced engineering materials, Vol. 26, No. 6, p. 2301722, 2024.
[34] A. AlHazaa, N. Haneklaus, and Z. Almutairi, "Impulse Pressure-Assisted Diffusion Bonding (IPADB): Review and Outlook," Metals, vol. 11, No. 2, p. 323, 2021.
[35] X. Yuan, K. Tang, Y. Deng, J. Luo, and G. Sheng, "Impulse pressuring diffusion bonding of a copper alloy to a stainless steel with/without a pure nickel interlayer," Materials and Design, Vol. 52, pp. 359–366, 2013.
[36] S. Chen, J. Huang, J. Xia, H. Zhang, and X. Zhao, "Microstructural characteristics of a stainless steel/copper dissimilar joint made by laser welding," Metallurgical and Materials Transactions. A, Vol. 44, No. 8, pp. 3690-3696, 2013.
[37] S. Sebastian and V. Suyamburajan, "Microstructural analysis of diffusion bonding on copper stainless steel," Mater. Today Proc., Vol. 37, pp. 1706-1712, 2021.
[38] R. Schroeder, R. Binder, G. Hammes, and A.N. Klein, "Plasma debinding and sintering of metal injection moulded 17-4PH stainless steel Plasma debinding and sintering of metal injection moulded 17-4PH stainless steel," Materials Research, Vol. 14, No. 4, pp. 564-568, 2011.