| 研究生: |
王政凱 Wang, Zheng-Kai |
|---|---|
| 論文名稱: |
固態鋁電容可行性研究 Feasibility Study on Al Solid State Capacitor |
| 指導教授: |
李文熙
Lee, Wen-Hsi |
| 學位類別: |
碩士 Master |
| 系所名稱: |
電機資訊學院 - 電機工程學系 Department of Electrical Engineering |
| 論文出版年: | 2023 |
| 畢業學年度: | 111 |
| 語文別: | 中文 |
| 論文頁數: | 84 |
| 中文關鍵詞: | 固態鋁電容 、晶界電容 、鋁熱反應 、氧化銅鋁反應 |
| 外文關鍵詞: | Al-Solid state capacitor, grain boundary capacitance, thermite reaction, copper oxide aluminum reaction |
| 相關次數: | 點閱:40 下載:0 |
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MLCC(Multilayer Ceramic Capacitor)即多層陶瓷電容器是目前最常見的電容之一,應用在許多電子元件上面,如手機、電動車、電路板等,隨著環保意識抬頭,電動車逐漸取代燃油車,造就更多MLCC需求,然而MLCC主要的介電材料是鈦酸鋇,因為材料與製程限制,面臨到無法降低介電厚度、電容值隨溫度變化太大以及漏電流的因素,因此本實驗對介電材料提出創新的見解,利用晶界電容的概念,搭配鋁粉本身的核殼結構,以及鋁熱反應三種概念相互組合,讓介電材料既能夠維持晶界結構,又能讓介電厚度降低,還能夠讓能隙寬度較高的氧化鋁做為介電層,因此透過本實驗相研究鋁粉的核殼core shell結構以及絕緣特性,對鋁粉做一些可行性的評估。研究發現鋁層以及氧化銅層無法完成完全使鋁產生完全絕,還需要添加銅使其事先氧化,在與鋁進行鋁熱反應,才能夠生成絕緣性質高的核殼結構晶界電容。
MLCC (Multilayer Ceramic Capacitor) is one of the most common capacitors used in many electronic components, such as cell phones, electric cars, circuit boards, etc. With the rise of environmental awareness, electric cars are gradually replacing fuel cars, creating more demand for MLCC. However, the main material for MLCC is barium titanate, because of the material and process limitation, it is unable to reduce the thickness of the boundary charge, the capacitance value changes too much with temperature, and the leakage current, therefore, this experiment proposes a subversive solution for the boundary charge material, using the concept of grain boundary capacitance, the core shell structure of aluminum powder itself, and the combination of three concepts of aluminum thermal reaction, so that the boundary charge material can not only maintain the grain boundary structure, but also allow the thickness of the boundary charge to be reduced, and the higher gap width of alumina can be used as the boundary charge layer. Therefore, the core shell structure and the insulation characteristics of aluminum powder are investigated in this experiment. It is found that the aluminum layer and the copper oxide layer cannot completely insulate the aluminum, and it is necessary to add copper to make it oxidize beforehand and then react with aluminum in the thermite reaction to generate the grain boundary capacitance with high insulating property.
[1] K. Hong, T. H. Lee, J. M. Suh, S.-H. Yoon, and H. W. Jang, "Perspectives and challenges in multilayer ceramic capacitors for next generation electronics," Journal of Materials Chemistry C, vol. 7, no. 32, pp. 9782-9802, 2019.
[2] O. A. Towoju and F. A. Ishola, "A case for the internal combustion engine powered vehicle," Energy Reports, vol. 6, pp. 315-321, 2020/02/01/ 2020, doi: https://doi.org/10.1016/j.egyr.2019.11.082.
[3] K.-i. Sakayori et al., "Curie temperature of BaTiO3," Japanese journal of applied physics, vol. 34, no. 9S, p. 5443, 1995.
[4] A. M. Abyzov, "Aluminum Oxide and Alumina Ceramics (review). Part 1. Properties of Al2O3 and Commercial Production of Dispersed Al2O3," Refractories and Industrial Ceramics, vol. 60, no. 1, pp. 24-32, 2019/05/01 2019, doi: 10.1007/s11148-019-00304-2.
[5] K. Yim et al., "Novel high-κ dielectrics for next-generation electronic devices screened by automated ab initio calculations," NPG Asia Materials, vol. 7, no. 6, pp. e190-e190, 2015.
[6] S. Senthilraja, K. Vijayakumar, and R. Gangadevi, "A comparative study on thermal conductivity of Al2O3/water, CuO/water and Al2O3–CuO/water nanofluids," Digest Journal of Nanomaterials and Biostructures, vol. 10, no. 4, pp. 1449-1458, 2015.
[7] A. J. H. Mante and J. Volger, "The thermal conductivity of BaTiO3 in the neighbourhood of its ferroelectric transition temperatures," Physics Letters A, vol. 24, no. 3, pp. 139-140, 1967/01/30/ 1967, doi: https://doi.org/10.1016/0375-9601(67)90729-3.
[8] A. Nicollet, L. Salvagnac, V. Baijot, A. Estève, and C. Rossi, "Fast circuit breaker based on integration of Al/CuO nanothermites," Sensors and Actuators A: Physical, vol. 273, pp. 249-255, 2018/04/15/ 2018, doi: https://doi.org/10.1016/j.sna.2018.02.044.
[9] L. Glavier et al., "Nanothermite/RDX‐Based Miniature Device for Impact Ignition of High Explosives," Propellants, Explosives, Pyrotechnics, vol. 42, no. 3, pp. 308-317, 2017.
[10] C. Rossi, "Engineering of Al/CuO reactive multilayer thin films for tunable initiation and actuation," Propellants, Explosives, Pyrotechnics, vol. 44, no. 1, pp. 94-108, 2019.
[11] H. Altenburg, J. Plewa, G. Plesch, and O. Shpotyuk, "Thick films of ceramic superconducting, electro-ceramic materials," Pure and Applied Chemistry, vol. 74, no. 11, pp. 2083-2096, 2002, doi: doi:10.1351/pac200274112083.
[12] 金進興. "印製型電路技術概論." 工業材料雜誌273期. (accessed.
[13] A. Dziedzic, A. Kolek, W. Ehrhardt, and H. Thust, "Advanced electrical and stability characterization of untrimmed and variously trimmed thick-film and LTCC resistors," Microelectronics Reliability, vol. 46, no. 2-4, pp. 352-359, 2006.
[14] M. Hrovat, A. Benčan, D. Belavič, J. Holc, and G. Dražič, "The influence of firing temperature on the electrical and microstructural characteristics of thick-film resistors for strain gauge applications," Sensors and Actuators A: Physical, vol. 103, no. 3, pp. 341-352, 2003/02/15/ 2003, doi: https://doi.org/10.1016/S0924-4247(02)00402-8.
[15] R. Demcko, "PASSIVE COMPONENTS Keys to Enabling Advanced Future System Designs," 2019. [Online]. Available: https://epci.eu/passive-components-keys-to-enabling-advanced-future-system-designs/.
[16] L. L. da Silva and M. Hinterstein, "Size Effect on Ferroelectricity in Nanoscaled BaTiO 3," Technological Applications of Nanomaterials, pp. 123-133, 2022.
[17] S. H. Kim, "Multilayer ceramic electronic component," ed: Google Patents, 2013.
[18] S. Ramakanth and K. James Raju, "Band gap narrowing in BaTiO3 nanoparticles facilitated by multiple mechanisms," Journal of Applied Physics, vol. 115, no. 17, p. 173507, 2014.
[19] H. Gong, X. Wang, S. Zhang, H. Wen, and L. Li, "Grain size effect on electrical and reliability characteristics of modified fine-grained BaTiO3 ceramics for MLCCs," Journal of the European Ceramic Society, vol. 34, no. 7, pp. 1733-1739, 2014.
[20] S. Jayanthi and T. Kutty, "Giant dielectrics from modified boundary layers in n-BaTiO 3 ceramics involving selective melting reactions of silver/glass composites at the grain boundaries," Journal of Materials Science: Materials in Electronics, vol. 16, pp. 269-279, 2005.
[21] P. Franken, M. Viegers, and A. Gehring, "Microstructure of SrTiO3 boundary‐layer capacitor material," Journal of the American Ceramic Society, vol. 64, no. 12, pp. 687-690, 1981.
[22] Y.-H. Lin, J. Cai, M. Li, C.-W. Nan, and J. He, "Grain boundary behavior in varistor-capacitor TiO2-rich CaCu3Ti4O12 ceramics," Journal of Applied Physics, vol. 103, no. 7, 2008, doi: 10.1063/1.2902402.
[23] R. Mauczok and R. Wernicke, "Ceramic boundary-layer capacitors," Philips Tech. Rev., vol. 41, no. 11, p. 338, 1983.
[24] L. Jeurgens, W. Sloof, F. Tichelaar, and E. Mittemeijer, "Thermodynamic stability of amorphous oxide films on metals: Application to aluminum oxide films on aluminum substrates," Physical Review B, vol. 62, no. 7, p. 4707, 2000.
[25] L. Jeurgens, W. Sloof, F. Tichelaar, and E. Mittemeijer, "Structure and morphology of aluminium-oxide films formed by thermal oxidation of aluminium," Thin solid films, vol. 418, no. 2, pp. 89-101, 2002.
[26] M. A. Trunov, M. Schoenitz, and E. Dreizin, "Effect of polymorphic phase transformations in alumina layer on ignition of aluminium particles," Combustion Theory and Modelling, vol. 10, no. 4, pp. 603-623, 2006.
[27] F. Saceleanu, S. Atashin, and J. Z. Wen, "Investigation of the effects of phase transformations in micro and nano aluminum powders on kinetics of oxidation using thermogravimetric analysis," Physical Chemistry Chemical Physics, vol. 19, no. 29, pp. 18996-19009, 2017.
[28] L. L. Wang, Z. Munir, and Y. M. Maximov, "Thermite reactions: their utilization in the synthesis and processing of materials," Journal of Materials Science, vol. 28, pp. 3693-3708, 1993.
[29] M. Hasegawa, "Chapter 3.3 - Ellingham Diagram," in Treatise on Process Metallurgy, S. Seetharaman Ed. Boston: Elsevier, 2014, pp. 507-516.
[30] G. Lahiner et al., "A redox reaction model for self-heating and aging prediction of Al/CuO multilayers," Combustion Theory and Modelling, vol. 23, no. 4, pp. 700-715, 2019.
[31] 林柏辰, "一種新穎空氣中燒結合金電阻的研究," 電機工程學系, 國立成功大學, 臺灣博碩士論文知識加值系統, 2022. [Online]. Available: https://hdl.handle.net/11296/ywwkcu
[32] Y.-S. Kwon, A. A. Gromov, and J. I. Strokova, "Passivation of the surface of aluminum nanopowders by protective coatings of the different chemical origin," Applied Surface Science, vol. 253, no. 12, pp. 5558-5564, 2007.
[33] J. L. Murray, "The aluminium-copper system," International metals reviews, vol. 30, no. 1, pp. 211-234, 1985.
[34] K. Z. Rajab et al., "Broadband Dielectric Characterization of Aluminum Oxide (Al2O3)," Journal of Microelectronics and Electronic Packaging, vol. 5, no. 1, pp. 2-7, 2008, doi: 10.4071/1551-4897-5.1.1.
校內:2028-08-15公開