| 研究生: |
郭權毅 Kuo, Chuan-I |
|---|---|
| 論文名稱: |
HfAlO 輔助電荷捕捉層於 AlScN 與 HfAlO 鐵電 GaN HEMT 閾值調控之應用 HfAlO-Assisted Charge-Trapping Engineering in AlScN- and HfAlO- Based Ferroelectric GaN HEMTs |
| 指導教授: |
王永和
Wang, Yeong-Her |
| 學位類別: |
碩士 Master |
| 系所名稱: |
智慧半導體及永續製造學院 - 半導體製程學位學程 Program on Semiconductor Manufacturing Technology |
| 論文出版年: | 2025 |
| 畢業學年度: | 113 |
| 語文別: | 英文 |
| 論文頁數: | 99 |
| 中文關鍵詞: | 電荷捕獲 、鐵電性 、AlScN 、HfAlO 、Enhancement mode 、HEMT |
| 外文關鍵詞: | Charge trapping, Ferroelectricity, AlScN, HfAlO, Enhancement mode, HEMT |
| 相關次數: | 點閱:6 下載:0 |
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本論文於同一 GaN 平臺上成功製作增強型鐵電 HEMT 與增強型電荷捕陷 HEMT。承襲先前以高鋁含量電荷捕陷層 Hf0.78Al0.22O 之經驗,本論文將閘極堆疊優化為低鋁含量 Hf0.92Al0.08O。其閾值電壓位移 (ΔVₜₕ) 為 6.2 V,並確保持續穩定的偏壓後操作。
在鐵電元件部分,本研究採用 10 nm Al2O3/25 nm AlScN 雙層閘極介電層製備 AlScN MIS-HEMT。該元件之峰值跨導為 88 mS·mm⁻¹,最大飽和電流達 356.9 mA·mm-1;其將可調閾值電壓視窗擴展至 12.47 V 以上,正向極化狀態下 Vₜₕ 約為 0.8 V。相較於傳統耗盡型 HEMT,本元件之導通電流與跨導幾乎無損耗,顯示結構設計得當且性能優異。
綜合上述結果,本論文所提出之材料與閘極堆疊工程有效提升 GaN 基增強型元件的閘極控制能力、閾值電壓可調範圍及長期操作穩定性,為低功耗、高性能之 GaN 功率與射頻應用提供可行的技術途徑。
In this study, enhancement-mode ferroelectric HEMTs and enhancement-mode charge-trapping HEMTs were realized on the same GaN platform. Leveraging prior experience with high-aluminum charge-trapping dielectrics (Hf0.78Al0.22O), the gate stack was re-optimized with a lower-aluminum composition, Hf0.78Al0.22O. The revised dielectric suppresses gate leakage by two orders of magnitude, from 1.4 mA mm⁻¹ to 0.081 mA mm⁻¹, while expanding the tunable threshold-voltage window to > 6 V and ensuring stable normally-off operation.
Ferroelectric AlScN MIS-HEMTs were fabricated with 10-nm Al2O3/25-nm AlScN bilayer gates. Devices exhibit a peak transconductance of 88 mS mm⁻¹ and a maximum saturation current of 356.9 mA mm-1. A threshold-voltage shift (ΔVTH) of 12.47 V is obtained, with the forward-polarized state yielding VTH ≈ 0.8 V. Performance metrics remain comparable to conventional depletion-mode counterparts, indicating minimal compromise in on-state current or transconductance.
The combined results demonstrate a practical route to low-power, high-performance GaN transistors for power and RF applications, achieving enhanced gate control, extended VTH adjustability, and long-term stability under enhancement-mode bias.
[1] "Global Energy Review 2025," International Energy Agency(IEA), March 2025. [Online]. Available: https://www.iea.org/reports/global-energy-review-2025
[2] F. Roccaforte, G. Greco, P. Fiorenza, and F. Iucolano, "An overview of normally-off GaN-based high electron mobility transistors," Materials, vol. 12, no. 10, p. 1599, 2019.
[3] H. Guo, B. Duan, H. Wu, and Y. Yang, "Breakdown mechanisms of power semiconductor devices," IETE Technical Review, 2019.
[4] M. Higashiwaki, K. Sasaki, A. Kuramata, T. Masui, and S. Yamakoshi, "Development of gallium oxide power devices," physica status solidi (a), vol. 211, no. 1, pp. 21-26, 2014, doi: https://doi.org/10.1002/pssa.201330197.
[5] A. Schiro and S. Oliver, "Wide bandgap power to electrify our world for a sustainable future," IEEE Power Electronics Magazine, vol. 11, no. 1, pp. 32-38, 2024.
[6] N. Keshmiri, D. Wang, B. Agrawal, R. Hou, and A. Emadi, "Current status and future trends of GaN HEMTs in electrified transportation," IEEE access, vol. 8, pp. 70553-70571, 2020.
[7] Y. Zhang, "Comparison between competing requirements of GaN and SiC family of power switching devices," in IOP Conference Series: Materials Science and Engineering, 2020, vol. 738, no. 1: IOP Publishing, p. 012004.
[8] G. Tang et al., "High-speed, high-reliability GaN power device with integrated gate driver," in 2018 IEEE 30th International Symposium on Power Semiconductor Devices and ICs (ISPSD), 2018: IEEE, pp. 76-79.
[9] F. Ye et al., "Ferroelectric switching behavior in GaN HEMTs with CMOS-compatible Hf0. 5Zr0. 5O2/Al2O3 dielectric layer," Applied Surface Science, p. 163556, 2025.
[10] G. He, Z. Sun, G. Li, and L. Zhang, "Review and perspective of Hf-based high-k gate dielectrics on silicon," Critical Reviews in Solid State and Materials Sciences, vol. 37, no. 3, pp. 131-157, 2012.
[11] J. Koo et al., "Characteristics of hafnium-aluminum-oxide thin films deposited by using atomic layer deposition with various aluminum compositions," Journal of the Korean Physical Society, vol. 47, no. 3, p. 501, 2005.
[12] P. K. Park and S.-W. Kang, "Enhancement of dielectric constant in HfO2 thin films by the addition of Al2O3," Applied physics letters, vol. 89, no. 19, 2006.
[13] M. H. Samuel Owen, M. Amin Bhuiyan, Q. Zhou, Z. Zhang, J. Sheng Pan, and Y.-C. Yeo, "Band alignment of HfO2/Al0. 25Ga0. 75N determined by x-ray photoelectron spectroscopy: Effect of SiH4 surface treatment," Applied Physics Letters, vol. 104, no. 9, 2014.
[14] M. M. Rahman, J.-G. Kim, D.-H. Kim, and T.-W. Kim, "Characterization of Al incorporation into HfO2 dielectric by atomic layer deposition," Micromachines, vol. 10, no. 6, p. 361, 2019.
[15] X. Liu et al., "Band alignment of HfAlO/GaN (0 0 0 1) determined by X-ray photoelectron spectroscopy: Effect of in situ SiH4 passivation," Journal of Alloys and Compounds, vol. 636, pp. 191-195, 2015.
[16] T. Cook Jr, C. Fulton, W. Mecouch, R. Davis, G. Lucovsky, and R. Nemanich, "Band offset measurements of the GaN (0001)/HfO 2 interface," Journal of applied physics, vol. 94, no. 11, pp. 7155-7158, 2003.
[17] J. Liu et al., "E-mode AlGaN/GaN HEMT with ScAlN/ScN charge trap-coupled ferroelectric gate stacks," Applied Physics Letters, vol. 126, no. 1, 2025.
[18] C.-H. Cheng et al., "Temperature-Dependent Polarization Switching and Endurance Cycling Properties of HfAlO Ferroelectric Thin Film," ECS Journal of Solid State Science and Technology, vol. 11, no. 8, p. 083013, aug 2022, doi: 10.1149/2162-8777/ac8954.
[19] 吳詠欣, "以氮化鋁鈧/氧化鋁閘極堆疊研製可調變式增強型高電子遷移率鐵電電晶體," 國立成功大學微電子工程研究所, 碩士論文, 2023.
[20] Y. Jiang et al., "Charge trapping layer enabled high-performance E-mode GaN HEMTs and monolithic integration GaN inverters," Applied Physics Letters, vol. 124, no. 24, 2024.
[21] T. Hanada, "Basic properties of ZnO, GaN, and related materials," in Oxide and nitride semiconductors: processing, properties, and applications: Springer, 2009, pp. 1-19.
[22] S. Pearton, F. Ren, A. Zhang, and K. Lee, "Fabrication and performance of GaN electronic devices," Materials Science and Engineering: R: Reports, vol. 30, no. 3-6, pp. 55-212, 2000.
[23] F. Roccaforte and M. Leszczynski, "Introduction to gallium nitride properties and applications," Nitride Semiconductor Technology: Power Electronics and Optoelectronic Devices, pp. 1-39, 2020.
[24] Y. Zhang, Q. Zhu, B. Tian, and C. Duan, "New-generation ferroelectric AlScN materials," Nano-Micro Letters, vol. 16, no. 1, p. 227, 2024.
[25] S. Fichtner, N. Wolff, F. Lofink, L. Kienle, and B. Wagner, "AlScN: A III-V semiconductor based ferroelectric," Journal of Applied Physics, vol. 125, no. 11, 2019.
[26] G. Lee, H. J. Joo, S. Oh, and G. Yoo, "Suppressed negative DIBL of ferroelectric HEMT with gate-align patterned AlScN stack," Ieee Electr Device L, 2025.
[27] Y. Park, J.-H. Lee, J.-K. Lee, and S. Kim, "Multifunctional HfAlO thin film: Ferroelectric tunnel junction and resistive random access memory," The Journal of Chemical Physics, vol. 160, no. 7, 2024.
[28] K. Xiong, J. Robertson, M. Gibson, and S. Clark, "Defect energy levels in HfO2 high-dielectric-constant gate oxide," Applied physics letters, vol. 87, no. 18, 2005.
[29] M. Houssa et al., "Trap-assisted tunneling in high permittivity gate dielectric stacks," Journal of Applied Physics, vol. 87, no. 12, pp. 8615-8620, 2000.
[30] H.-Y. Gou et al., "Influence of HfAlO composition on memory effects of metal-oxide-semiconductor capacitors with Al2O3/HfAlO/Al2O3 layers and Pd electrode," Thin Solid Films, vol. 529, pp. 380-384, 2013.
[31] J.-S. Wu et al., "Hf-based and Zr-based charge trapping layer engineering for E-mode GaN MIS-HEMT using ferroelectric charge trap gate stack," IEEE Journal of the Electron Devices Society, vol. 10, pp. 525-531, 2022.
[32] J.-S. Wu et al., "E-mode GaN MIS-HEMT using ferroelectric charge trap gate stack with low dynamic on-resistance and high V th stability by field plate engineering," Ieee Electr Device L, vol. 42, no. 9, pp. 1268-1271, 2021.
[33] C.-H. Wu et al., "High-performance normally-OFF GaN MIS-HEMTs using hybrid ferroelectric charge trap gate stack (FEG-HEMT) for power device applications," Ieee Electr Device L, vol. 39, no. 7, pp. 991-994, 2018.
[34] Z. Li et al., "Stabilizing the ferroelectric phase in HfAlO ferroelectric tunnel junction with different bottom electrodes," Ieee Electr Device L, vol. 44, no. 6, pp. 947-950, 2023.
[35] S. S. Behara and A. Van der Ven, "Ferroelectric HfO 2 and the importance of strain," Physical Review Materials, vol. 6, no. 5, p. 054403, 2022.
[36] M. N. U. Bhuyian and D. Misra, "Multilayered ALD HfAlO x and HfO 2 for high-quality gate stacks," IEEE Transactions on Device and Materials Reliability, vol. 15, no. 2, pp. 229-235, 2015.
[37] F. Du et al., "Improved gate leakage current and breakdown voltage of InAlN/GaN MIS-HEMTs by HfAlOx-based charge-trapping layer dielectric and in situ O3 treatment," Applied Physics Letters, vol. 126, no. 1, 2025.
校內:2028-08-19公開