| 研究生: |
黃俊富 Huang, Chun-Fu |
|---|---|
| 論文名稱: |
拌和塑性體和彈性體之高分子改質瀝青 Polymer-Modified Asphalt Mixed with Thermoplastics and Thermoelastics |
| 指導教授: |
陳建旭
Chen, Jian-Shiuh |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 土木工程學系 Department of Civil Engineering |
| 論文出版年: | 2015 |
| 畢業學年度: | 103 |
| 語文別: | 中文 |
| 論文頁數: | 110 |
| 中文關鍵詞: | 高分子改質瀝青 、塑性體 、彈性體 、苯乙烯-丁二烯-苯乙烯 、聚乙烯 、聚丙烯 |
| 外文關鍵詞: | styrene-butadiene-styrene, polymer modified asphalt, polyethylene, polypropylene |
| 相關次數: | 點閱:135 下載:0 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
添加高分子的改質瀝青存有相容性、儲存穩定性以及拌合溫度過高等議題,本研究於基底瀝青分別添加塑性體包含聚乙烯(polyethylene, PE)與聚丙烯(polypropylene, PP),進行比較,選出改質效果較佳的塑性體。再與彈性體,也就是苯乙烯-丁二烯-苯乙烯(styrene–butadiene–styrene, SBS)進行摻配,摻配後之改質瀝青除了傳統的黏度、針入度、軟化點等物性試驗外,也加入韌性試驗並透過動態剪切流變儀(Dynamic Shear Rheometer, DSR)來評估改質瀝青的質流行為;另外,本研究也使用光學顯微鏡對改質瀝青進行微觀結構的分析,評估最佳的改質瀝青摻配模式。塑性體改質劑中,PE的改質效果較佳,擁有高軟化點、低黏度,且較無離析的問題,但彈性回復率均較差,需要添加彈性體才能符合規範;添加硫除了有助於降低SBS改質瀝青的離析,亦能提昇改質瀝青的高溫性能;於彈性體改質瀝青中加入塑性體可以降低改質瀝青的黏度,軟化點的增減隨著塑性體改質劑的不同而有所變化;建議最佳改質瀝青摻配比例為5%SBS+3%硫(相對於SBS重)+1%~3%PE,此時改質瀝青具有較佳的軟化點與工作性。
Polymer modified asphalt (PMA) have some problems such as compatibility, storage stability and mixing temperature is too high. In this study, base binders which were add thermoplastics including polyethylene(PE) and polypropylene(PP) were compared. Then select better thermoplastic mixing with thermoelastic(here use styrene-butadiene-styrene(SBS)). For physical properties, the blended PMA were tested include viscosity test, penetration test and softening point test etc. Besides traditional physical test, this study also add toughness test and Dynamic Shear Rheometer to evaluate rheological properties of different PMBs. In addition, optical microscope was used to analysis microstructures of PMA. Finally assessing the best PMA blending mode. PE is the best modifier in the thermoplastics which has the highest softening point, the lowest viscosity and will not separate during the hot storage. But the elastic recovery is poor, we need to add an thermoelastic to meet specifications; In addition to helping avoid the SBS modified asphalt segregation, also improved high-temperature performance of modified asphalt by adding sulfur; Thermoelastic modified asphalt can reduce viscosity by adding thermoplastics, but softening point will change with different thermoplastics;Finally, the recommended modifier content is 5%SBS+ 3% sulfur(relative to the weight of SBS)+1%~3%PE. In this case the PMA have higher softening point and better mobility.
張文政 (2004) 硫磺助溶劑對高分子改質瀝青之影響,國立成功大學
土木工程研究所碩士論文,台南。
楊林江、李井軒 (2001)「SBS改性瀝青的生產與應用」,人民交通
出版社,北京。
蔡攀鰲 (2003) 公路工程學,鵬逞書局,台南。
Airey, G.D. (2011). “Factor Affecting the Rheology of Polymer Modified Bitumen (PMB),” Polymer Modified Bitumen Properties and Characterisation, McNally, T., 1st edition, Oxford, pp.238-263.
Bahia, H.U., and Anderson, D.A. (1995). ”Strategic Highway Research Program Binder Rheological Parameters:Background and Comparison with Convertional Properities,” Transportation Reasearch Record, Vol.1488, pp.32-39.
Collins, J.H. and Bouldin, M.G. (1992). ”Stability of Straight and Polymer-Modified Asphalts,” Transportation Research Record : Journal of the Transportation Research Board, No.1342, pp.92–100.
Chen, J.S., Liao, M.C., and Shiah, M.S. (2002). “Asphalt Modified by Styrene–Butadiene–Styrene Triblock Copolymer: Morphology and Model,” Journal of Materials in Civil Engineering, Vol.14, pp.224–229.
Diefenderfer, S.D. and McGhee, K.M. (2015). Installation and Laboratory Evaluation of Alternatives to Conventional Polymer Modification for Asphalt, Virginia Department of Transportation, VCTIR 15-R15, Richmond, Virginia.
Dongre, R., Button, J.W., Kluttz, R.Q., Anderson, D.A. (1997). ”Evaluation of Superpave Binder Specification with Performance of Polymer-Modified Asphalt Pavement,” Progress of Superpave : Evaluation and Implementation, ASTM STP 1322, pp.80-100.
Isacsson, U. and Lu, X. (1995). “Testing and Appraisal of Polymer Modified Road Bitumens – State of the Art,” Materials and Structures, Vol.28, pp.139–159.
Li, Y., Li, L., Zhang, Y., Zhao, S., Xie, L. and Yao, S. (2010). ”Improving the Aging Resistance of Styrene–Butadiene–Styrene Tri-block Copolymer and Application in Polymer Modified Asphalt,” Journal of Applied Polymer Science, Vol.116, pp.754–761.
Mckay, K.W., Gros, W.A. and Diehl, C.F. (1995). “The influence of Styrene-Butadiene Diblock Copolymer and Styrene-Butadiene-Styrene Triblock Copolymer Properties and Product Performance,” Journal of Applied Polymer Science, Vol.56, pp.947-958.
Masson, J.F., Collins, P., Robertson, G., Woods, J.R., and Margeson, J. (2003). “Thermodynamics, Phase Diagrams, and Stability of Bitumen–Polymer Blends,” Energy & Fuels, Vol.17, pp.714–724.
Polacco, G., Stastna, J., Biondi, D. and Zanzotto, L. (2006). “Relation between Polymer Architecture and Nonlinear Viscoelastic Behavior of Modified Asphalts,” Current Opinion in Colloid & Interface Science, No.11, pp.230–245.
Sengoz, B., Topal, A., and Isikyakar, G. (2009). “Morphology and Image Analysis of Polymer Modified Bitumens,” Construction and Building Materials, Vol.23, pp.1986–1992.
Shanks, R. and Kong, I. (2012). Thermoplastic Elastomers, Applied Sciences, RMIT University, Melbourne.
Urquhart, R., and Khoo, K.Y. (2013). Investigations into the Effects of Polymer Segregations and Degradation in Polymer Modified Binders, AP-T227-13, Austroads, Sydney.
Urquhart, R., and Esnouf, J. (2014). Effects of Hot Storage on Polymer Modified Binder Properties and Field Performance, AP-T271-14, Austroads, Sydney.
Welborn, J.T., and Babashak, J.F. (1959). “New rubberized asphalt for roads,” Journal of Highway Division, Proceedings of American Society of Civil Engineering, Vol.84, pp.1-82.
Wen, G., Zang, Y., Zang, Y., Sun, K., and Fan, Y., (2002). “Rheological Characterization of Storage-Stable SBS-Modified Asphalts,” Polymer Testing, Vol.21, No.3, pp.295-302.
Zhang, Y., Zhao, S., Li, Y., Xie, L., and Sheng, K. (2008). “Radiation Effects on Styrene–Butadiene–Styrene Copolymer,” Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol.266, pp.3431–3436.
校內:2025-12-31公開