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研究生: 李沐宸
Li, Mu-Cheng
論文名稱: 石墨烯薄膜場效電晶體之製程及特性研究
Fabrication and Measurement Characterization of Graphene Field-Effect Transistor
指導教授: 高騏
Gau, Chi
學位類別: 碩士
Master
系所名稱: 工學院 - 奈米科技暨微系統工程研究所
Institute of Nanotechnology and Microsystems Engineering
論文出版年: 2012
畢業學年度: 100
語文別: 中文
論文頁數: 87
中文關鍵詞: 石墨烯電晶體
外文關鍵詞: grapheme, MOS FET
相關次數: 點閱:46下載:2
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  • 自從發現石墨烯(graphene)以來,石墨烯電晶體立刻成為目前電子領域中最為熱門的研究之一。石墨烯本身具有極高的電子遷移率,許多研究人員希望能夠取代矽半導體的材料,以石墨烯電晶體取代現有的電晶體,將會大幅提升電子元件的反應速度,且石墨烯具有卓越的機械特性。本研究是利用酒精氣相化學沉積法以鎳箔製備石墨烯,作為場效電晶體的通道部分,並討論石墨烯電晶體之特性。
    實驗中製作出不同的各種通道長度、寬度並討論其尺寸效應,爐管成長二氧化矽當作介電層,採用背閘極(bottom gate)的方式製作電晶體。利用拉曼光學系統觀察石墨烯成長的層數,使用電子型場發射掃描式電子顯微鏡(Scanning Electron Microscope, SEM)觀察石墨烯的表面形貌等,接著取得由代工生成之銅箔成長少層石墨烯,以相同條件製程電晶體後將其與鎳薄成長之石墨烯做比較觀察其電性之區別,最後研究如何利用矽奈米線製作出可以將電晶體定位的石墨烯奈米帶電晶體。

    Since the discovery of graphene , graphene transistors immediately become one of the most popular studies in the field of electronics. Graphene has a very high electron mobility and many researchers hope to replace the silicon semiconductor materials. If the graphene transistor can be replace to the existing transistors , it can be improve the speed of response of the electronic components and graphene has excellent mechanical properties can be used in flexible device. It will replace to organic transistor one day.

    This study use chemical vapor deposition method to prepare graphene by nickel foil and the carbon source gas is alcohol. We use the grapheme as a channel material of MOS FET and discuss the characteristics of the graphene transistor.

    In th experiment, we produce different channel length , width and discuss the size effect. We use furnace tube to growth silicon dioxide as the dielectric layer and make transistors using back gate method. Using Raman optical system to observe the growth of graphene layers and e-field emission scanning electron microscope observe the surface morphology of the graphene.

    Then growth few-layer graphene by copper foil by the foundry. We use the same process to made a transistor and compared with nickel foil growth graphene. At the last we study used silicon nanowire to made a graphene nano ribbon transistors which can be positioned

    中文摘要 目錄 1 圖目錄 4 表目錄 7 第一章 序論 8 1.1研究動機 8 1.2石墨烯的發展概述 9 1.2.1石墨烯的結構與性質 9 1.2.2石墨烯的成長機制 10 1.2.3石墨烯的合成方式 10 1.2.4打開石墨烯能隙的方法 12 第二章 實驗原理 15 2.1金氧半場效電晶體的基本原理 15 2.2石墨烯場效電晶體的基本原理 18 2.3介電層的選擇 19 2.4介電層電容 20 第三章 元件製程與量測 21 3.1石墨烯薄膜成長 21 3.2材料物性量測 21 3.2.1場發掃描式電子顯微鏡(Scanning Electron Microscope,SEM) 21 3.2.2拉曼光譜分析儀(Raman Spectrometer) 21 3.3石墨烯電晶體製備 22 3.3.1鎳箔成長石墨烯電晶體製備 23 3.3.2少層石墨烯電晶體利用矽奈米線微影製備 24 3.4電性量測參數 25 3.4.1汲極電流-汲極電壓量測 25 3.4.2汲極電流-閘極電壓量測 25 3.4.3介電層之電容量測 26 3.4.4遷移率量測 26 3.5實驗製程及量測改進 26 3.6實驗儀器介紹 30 第四章 石墨烯粉末電晶體製備與討論 37 4.1石墨烯粉末電晶體製備 37 4.2粉末石墨烯電晶體特性研究 38 4.2.1電流電壓曲線分析 38 4.2.2表面輪廓儀分析 39 4.3粉末石墨烯製作問題與討論 39 4.3.1石墨烯溶液討論 39 4.3.2粉末石墨烯電晶體介電層討論 40 4.3.3材料與基板討論 41 4.3.4後續研究建議 41 第五章 單片石墨烯備製電晶體的結果與討論 44 5.1石墨烯電晶體不同通道尺寸之電性研究 44 5.2少層石墨烯與鎳薄成長石墨烯電晶體比較 44 5.3 將石墨烯電晶體通道寬度降至奈米尺寸時的少層石墨烯 電晶體特性 45 第六章 結論 46 第七章 未來展望 49 參考文獻 52

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