摘要
在本論文內將討論ZnO-B2O3-SiO2之介電陶瓷材料，藉由添加不同比例CaTiO3，探討對微波特性的影響。
材料方面分為二部分：第一部份為單一ZnO-B2O3-SiO2 微波性質；第二部份為添加CaTiO3對ZnO-B2O3-SiO2微波性質之影響。實驗結果顯示，添加15wt%的CaTiO3可在燒結溫度900℃/0.5hr，此時可得介電特性：εr~7.3；Q×f~4000 GHz； ~3.4 ppm/℃。
此外，本論文分別以FR4、氧化鋁、ZnO-B2O3-SiO2三種不同基板，製作設計一個緊密的微帶線步階阻抗帶通濾波器，中心頻率定為2.44GHz，頻寬5%。

Abstract
The microwave properties of ZnO-B2O3-SiO2 dielectric ceramic materials are discussed in this paper. By adding different percentage CaTiO3, we study the effects of microwave properties.
The material researches are divided into two parts in this thesis. Firstly, we discuss the microwave properties of ZnO-B2O3-SiO2. Then, we discuss the microwave properties of ZnO-B2O3-SiO2 by adding CaTiO3. The experimental results show that ZnO-B2O3-SiO2 with 15wt% CaTiO3 addition can be sintered to 900 oC/0.5hr, and we obtain the properties: εr~7.3；Q×f~4000 GHz； ~3.4 ppm/℃
In addition, we design and fabricate compact SIR band-pass filters with 2.44GHz central frequency and 5% bandwidth utilizing FR4, Al2O3 and ZnO-B2O3-SiO2 substrates.

參考文獻
[1]D. C. Woo, E.H. Kisi, S.J. Kennedy, C.J. Howard and Ma Yuxiang, presented at the Pacific Rim Ceramic Societies meeting, Cairns, Australia, July 14-17, 1996.
[2]Hu Tao, Uusimäki Antti, Jantunen Heli, Leppävuori Seppo, Soponmanee Kajitrat, “Optimization of MgTiO3–CaTiO3 based LTCC tapes containing B2O3 for use in microwave applications,” Ceramics International, 31, 85, 2005.
[3]Koichi Shimakawa, Shoji Nitta and Yoneichi Inagaki, “Temperature dependence of the switching phenomena in Te-Se-Ge glass,” J. Appl. Phys., 10, 391, 1971.
[4]R. C. Kell, A. C. Greenham, G. C. E. Olds, “High-permittivity temperature-stable ceramic dielectrics with low microwave loss,” J.Am.Ceram.Soc. 56, 352, 1973.
[5]H. M. O'Bryan JR., J. Thomson JR., J. K. Plourde, “A new BaO-TiO2 compound with temperature-stable high permittivity and low microwave loss ,” J.Am.Ceram.Soc., 57, 450, 1974.
[6]Gisbert Wolfram and Herbert E. Göbel, “Existence range, structural and dielectric properties of ZrxTiySnzO4 ceramics (x+y+z=2) ,” Met.Res.Bull., 16, 1455, 1981.
[7]Toshiro Hayakawa, Seiki Yano and Toshiki Hijikata, “Multimode-oscillating behavior in index-guiding v-channeled substrate inner stripe lasers depending on structural factor,” Jpn. J. Appl. Phys., 21, L642, 1982.
[8]W. D. kingery and J. Francl, “Fundamental study of clay: XIII, drying behavior and plastic propertie,” J.Am.Ceram.Soc., 37, 596, 1954.
[9]Takahiro Takada, Sea Fue Wang, Shoko Yoshikawa, Sei-Joo Jang, Robert E. Newnham, “Effects of glass additions on (Zr,Sn)TiO4 for microwave applications,” J.Am.Ceram.Soc., 77, 2485, 1994.
[10]W. D. Kingery, Ceramic fabrication process, John Wiley, p.131, New York, 1958.
[11]S. Timoskenko and J. N. Goodier, Theory of elasticity, Mcgrand Hill, 372, New York, 1951.
[12]I. Bahl and P. Bhartia, Microwave solid state circuit design, chap6, John Wiley&Sons, 1988.
[13]P. A. Rizzi., Microwave engineering passive circuits, Prentice Hall, 1988.
[14]Sheng-Yuan Lee, “Design and fabrication of the planar SIR microwave,” Master thesis, NCKU, 1998.
[15]L. A. Trinogga, Guo Kaizhou and I. C. Hunter, Practical microstrip circuit design., UK: Ellis Horwood, 1991.
[16]E. J. Denlinger, “Losses of microstrip lines,” IEEE. Trans. Microwave Theory Tech., MIT-28, 513–522, 1980.
[17]R. A. Pucel, D. J. Masse and C. E Hartwig, “Losses in microstrip,” IEEE. Trans. Microwave Theory Tech., MIT-16, 342-350, 1968.
[18]Yong-Cheng Qiu, “Design of 2.4 GHz planar filters for ISM band,“ 2001.
[19]Pao-You Yen, Cheng-Liang Huang, Chung-Chuang Wei, “Design and Fabrication of the Planar SIR Microwave BandPass Filter,“ 1997.
[20]M. Makimoto and S. Yamashita, “Bandpass Filters Using Parallel Coupled Stripline Stepped Impedance Resonators,” IEEE. Trans. Microwave Theory and Tech., MTT-28, 12, 1413-1417, 1980.
[21]T. Ishizaki, T. Uwano and H. Miyake, “An Extended Configuration of a Stepped Impedance Comb-line Filter,” IEICE Trans. Electron., E79-C, 5, 671-677, 1996.
[22]D. M. Pozar, Microwave Engineering, Addison-Wesley Publishing Company Inc., U.S.A., 1990.
[23]J. Helszajn, Microwave Planar Passive Circuits and Filters, John Wiley & Sons, New York, 1994.
[24]B. W. Hakki and P. D. Coleman, “A dielectric resonator method of measure-ng inductive capacities in the millimeter range,” IEEE. Trans. Microwave Theory Tech., MTT-8, 402-410, 1960.
[25]Y. Kobayashi and N. Katoh, “Microwave measurement of dielectric properties of lo-w-loss materials by dielectric rod resonator method,” IEEE. Trans. Micr- owave Theory Tech., MTT-33, 586-592, 1985.
[26]P. Wheless, and D. Kajfez, “The use of higher resonant modes in measuring the dialectric constant of Dielectric Resonators,” IEEE. MTT-S Symposium Dig., 473-476, 1985.
[27]Y. Kobayashi, and S. Tanaka, "Resonant modes of a dielectric resonator short-circuited at both ends by parallel conducting plates," IEEE. Trans. MicrowaveTheory Tech., MTT-28, 1077-1085, 1980.
[28]J. W. Cahn and R. B. Heady, “Analysis of Capillary Forces in Liquid-Phase Sintering of Jagged Particles,” J. Am. Ceram., 406, 1970.
[29]W. J. Huppmann and G. Petzow, Sintering process, Edited by G.C. Kuczynski, Plenum Press, New York, 1980.
[30]W. J. Huppmann and G. Petzow, Ber. Bunnsenges Phys. Chem.82, 308, 1978.
[31]R. M. German, Liquid Phase Sintering, Plenum Press, New York, 1985.
[32]B. C. Wadell, Transmission line design handbook, chap5., 1991.
[33]Hsin-Chin Chang, Kuang-Chung Tao, “A Multilayer bandpass Filter Integrated Into Rf Module Board,“ IEEE. MTT-S Digest, 1996.
[34]M. Makimoto and S. Yamashita, “A Compact Bandpass Filter Using Stepped Impedance Resonators,“ Proc. IEEE, 67, 1, 16-19, 1979.
[35]A. Winkelmann, O. Schott, "Ueber die elastizitaet und ueber die druckfestigkeit verschiedener neuer glaeser in ihrer abhaengigkeit von der chemischen zusammensetzung," Ann. Physik Chemie, 51, 697, 1894.
[36]A. Winkelmann, O. Schott, "Ueber thermische widerstands coefficienten verschiedener glaeser in ihrer abhaengigkeit von der chemischen zusammensetzung," 51, 730, 1894.
[37]A. Winkelmann, O. Schott, "Ueber die specifischen waermen verschieden zusammengesetzter glaeser," 49, 401, 1893.