本研究對於不同原油所提煉瀝青，添加添加劑與改質劑後進行比較，在相同條件下，改質瀝青樣本分別進行分析，物理性質方面，進行傳統的黏度、針入度、軟化點等物性試驗；並透過動態剪切流變儀(Dynamic Shear Rheometer, DSR)來評估不同改質瀝青材料間質流性質差異。化學性質方面，以高壓凝膠滲透層析儀(High Pressure Gel Permeation Chromatography, HP-GPC)、薄層液相層析法之火焰離子檢視器(Thin-layer Chromatography – Flame Ionization Detector, TLC-FID)和傅立葉轉換紅外線光譜儀(Fourier Transform Infrared Spectroscopy, FTIR) 分析高分子材料SBS之改質瀝青特性。最後，結合物理與化學性質的分析結果，對改善改質瀝青之相容性提出建議，建立的改質瀝青之摻配模式。改質瀝青的基底瀝青選擇，以基底瀝青的瀝青精含量較低或芳香族含量較高的相容性為佳； 改質劑選擇上，星型SBS雖具有較好的改質效果，工作性仍有改善空間，以線型SBS較為適合；SBS建議含量為5%~5.3%，含量低，易產生黏度不足的議題；含量高，工作性則會逐漸下降；穩定劑硫粉，對改質瀝青的彈性性質具正面效益，比例為3%對改善離析方面較佳；改質瀝青隨高溫儲存天數增加，軟化點可能隨之遞減。化性結果顯示，廣分布指數(PDI)隨硫比例增加而漸減，說明改質瀝青內部可能有均質化的現象；FTIR與HP-GPC的試驗結果，可應用於推估SBS含量。

The research compare different asphalt refined by crude oil and added with additives and modifiers. In the same condition, analyze polymer modified asphalt respectively. For physical properties, the tests include viscosity test, penetration test, softening point test etc. And use Dynamic Shear Rheometer to evaluate rheological properties of different polymer modified asphalt. For chemical properties, analyze characteristics of SBS modified asphalt with High Pressure Gel Permeation Chromatography, Thin-layer Chromatography – Flame Ionization Detector, and Fourier Transform Infrared Spectroscopy. Finally, combine with results of physical properties and chemical properties, and make recommendation for improving compatibility of polymer modified asphalt, and build blending model of polymer modified asphalt. Use base asphalt of lower asphaltene or higher aromatic is better in consideration of compatibility. In the choice of modifier, the radial SBS has better modified effect, but the workability has to improve. So, the linear SBS may be better choice. Lower SBS content easily generated less viscosity. Higher SBS content made the workability decrease. So, the recommended SBS content is 5%~5.3%. Adding stabilizer sulfur can enhance the elasticity of polymer modified asphalt. 3% sulfur content can improve segregation evidently. The softening point of polymer modified asphalt would decrease with staging day increasing at high temperature. The results of chemical properties showed that PDI would reduce with sulfur content increasing. The forgoing also described the interior of polymer modified asphalt existed homogenization possibly. The test results of FTIR and HP-GPC could apply to evaluate SBS content.

杜逸虹 (1983)，「聚合體學(高分子化學) 」 ，三民書局。
李煒光 (2013) ｢我國SBS改性瀝青使用現狀及一種測試新技術｣，第四屆瀝青材料國際學術會議，廣州，第95-103頁。
張文政 (2004)，硫磺助溶劑對高分子改質瀝青之影響，國立成功大學土木工程研究所碩士論文，台南。
張玉貞 (2013) ｢中國瀝青材料生產技術現狀 ｣，第四屆瀝青材料國際學術會議，廣州，第31-42頁。
楊林江、李井軒 (2001)「SBS改性瀝青的生產與應用」，人民交通出版社，北京。
劉伃芝(2012)，瀝青膠漿質流行為與轉爐石添加於石膠泥瀝青混凝土之工程性質評估，國立成功大學土木工程研究所碩士論文，台南。
《瀝青生產與應用技術手冊》編委會 (2010) 「瀝青生產與應用技術手冊」，中國石化出版社
Airey, G.D. (2003). “Rheological Properties of Styrene Butadiene Styrene Polymer Modified Road Bitumens,” Fuel, Vol.82, Issue 14, pp.1709–1719.
Blanco, R., Rodriguez, R., Garcia-Garduno, M., and Castano, V.M.(1996). “Rheological Properties of Styrene-Butadiene Copolymer –Reinforced Asphalt,” Journal of Applied Science, Vol.61, pp.1493-1501.
Brule, B., Ramond, G. and Such, C. (1986).“Relationships Between Composition, Structure, and Properties of Road Asphalts: State of Research at the French Public Works Central Laboratory,” Journal of the Transportation Research Board , Transportation Research Record 1096, pp.22-33.
Brule, B., Brion,Y., and Tanguy, A. (1988).” Paving Asphalt Polymer Blends: Relationship Between Composition, Structure and Properties,” Journal of the Association of Asphalt Paving Technologists, Vol.57, pp.41–64.
Bull, A.L., and Vonk, W.C. (1994).”Thermoplastic Elastomer and Bitumen Blends for Roof and Road,” paper TPE 6.3.1, Shell Chemicals, London, UK.
Cai, J. (1994).”Determination of Rubber Content in Rubber-Asphalt by Infrared Spectrum,” Journal of Zhejiang University, Vol.28, pp.385-388.
Choquet, F.S., and Ista, E.J., (1992)”The Determination of SBS, EVA, and APP Polymers in Modified Bitumens,” ASTM STP 1108, pp.35-49.
Dongre, R., Button, J.W., Kluttz, R.Q., Anderson, D.A.(1997). “Evaluation of Superpave Binder Specification with Performance of Polymer-Modified Asphalt Pavement,” Progress of Superpave：Evaluation and Implementation, ASTM STP 1322, pp.80-100.
Federal Highway Administration (2012).The Use and Performance of Asphalt Binder Modified with Polyphosphoric Acid (PPA) , FHWA-HIF-12-030，New Jersey.
Ismail, A., Al-Mansob, R.A., Yusoff, N.I.B.M., Karim M.R.(2012) “Effect Of Toluene As Disperser On The Bitumen Modified With Epoxidized Natural Rubber With Aging Simulation,” Australian Journal of Basic and Applied Science, Vol.6, No.12, pp.97-101
Khattak, M.J., and Baladi, G.Y.(1998). “Engineering Properties of Polymer Modified Asphalt Mixture,” Journal of the Transportation Research Board, Transportation Research Record1638, pp.12-21.
Lesueur, D. (2009). “The Colloidal Structure of Bitumen: Consequences on the Rheology and on the Mechanisms of Bitumen,” Advances in Colloid and Interface Science, Vol.145, pp.42-82
Masson, J.F, Pelletier, L.,and Collins, P.(2001). “Rapid FTIR Method for Quantification of Styrene-butadiene Type Copolymers in Bitumen,” J. Appl. Polym. Sci., 79: 1034-41
Masson, J.F., Collins, P., Woods, J.R., Bundalo-Perc, S. ,and Al-Qadi, I. ( 2006). Degradation of Bituminous Sealants due to Extended Heating Before Installation: a Case Study, report NRCC-48663, Institute for Research in Construction, Ottawa, Canada.
Mouillet, V., Lamontagne, J., Durrieu, F., Planche, J.P., and Lapalu, L. (2008). “Infrared Microscopy Investigation of Oxidation and Phase Evolution in Bitumen Modified with Polymers,” Fuel, Vol. 87, pp.1270-80.
Nasrazadani, S., Mielke, D., Springfield T., and Ramasamy, N. (2010).Practical Applications of FTIR to Characterize Paving Materials, Texas Department of Transportation, Technical Report 0-5608-1, Texas.
Oliver, J., Khoo, K.Y., and Waldron, K. (2012). ” The Effect of SBS Morphology on Field Performance and Test Results,” Road Materials and Pavement Design, 13:1, pp.104-127.
Polacco, G., Stastna, J., Biondi, D., and Zanzotto, L. (2006). “Relation Between Polymer Architecture and Nonlinear Viscoelastic Behavior of Modified Asphalts,” Current Opinion in Colloid and Interface Science, No.11, pp.230-245.
Sengoz, S., and G. Isikyakar (2008). ”Evaluation of the Properties and Microstructure of SBS and EVA Polymer Modified Bitumen,” Construction and Building Materials, Vol.22, Issue9, pp.1897-1905.
Shell Bitumen (2003) The Shell Bitumen Handbook, Shell Bitumen, UK.
Skoog, D.A., Holler, F.J., and Crouch, S.R. (2007) .Principle of Instrumental Analysis, Thomson Brooks/Cole, 6th edition, CA, Ch.16A
Sun, D., Zhang, L., and Zhang, X. (2011). “Quantification of SBS Content in SBS Polymer Modified Asphalt by FTIR, ” Advanced Materials Research, Vol.287/290, pp.953-960.
Urquhart, R., and Khoo, K.Y. (2013). Investigations into the Effects of Polymer Segregations and Degradation in Polymer Modified Binders, AP-T22713, Austroads, Sydney
Valcke, E., Rorif, F., and Smets, S. (2009). “Ageing of EUROBITUM Bituminised Radioactive Waste: An ATR-FTIR Spectroscopy Study,” Journal of Nuclear Materials, Vol.393, pp.175-185.
Vonk, W.C., and Bull, A.L. (1989). Phase Phenomena and Concentration Effects in Blends of Bitumen and SBS Elastomers., International Roofing Congress, 7th, Munich, Germany, pp. 210–222.
Vonk, W., Korenstra, J., Bodt, D. and Heimerikx, G. (1996). SBS Copolymers for Road Binders with Improved Processing Characteristics and Heat Stability, Eurasphalt and Eurobitume congress, 1st, 1996, Strasbourg, France.
Wang, T., Yi, T., and Yuzhen Z. (2010). ”The Compatibility of SBS-Modified Asphalt,” Petroleum Science and Technology, Vol.28, No.7, pp.764-772.
Wen, G., Zhang, Y., Zhang, Y., Sun, K., and Fan, Y. (2002). “Rheological Characterization of Storage-Stable SBS-Modified Asphalts,” Polymer Testing, Vol.21, No.3, pp.295-302.