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研究生: 董國信
Tung, Kuo-Shin
論文名稱: 奈米氧化鎂、二氧化鈦之合成及應用於微波介電陶瓷之研究
Synthesis and Microwave Dielectric Applications of Magnesium Titanates Sintered by MgO and TiO2 Nanostructures
指導教授: 施權峰
Shih, Chuan-Feng
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年: 2010
畢業學年度: 98
語文別: 中文
論文頁數: 113
中文關鍵詞: 鈦酸鎂奈米線奈米球濾波器
外文關鍵詞: Magnesium Titanates, Nanowire, Nanosphere, Filter
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  • 本論文以多元醇熱解法合成氧化鎂奈米結構以及水熱法合成二氧化鈦奈米線,利用這兩種奈米氧化物為先驅物合成鈦酸鎂陶瓷。
    在化學法合成氧化鎂奈米球及水熱法合成二氧化鈦奈米線的研究中,藉由控制反應時間、溶液酸鹼值、反應溫度、濃度等參數,合成高比表面積之氧化鎂奈米結構和二氧化鈦奈米線,同時具有高純度、均勻性佳、再現性佳等特點,無需昂貴設備即可在低溫下大量生產奈米級粉末。
    利用高比表面積的氧化鎂奈米球及二氧化鈦奈米線以無煆燒法合成鈦酸鎂,Q × f 為186,000 GHz(10 GHz),特性與文獻相似;另外,以傳統固態燒結法合成鈦酸鎂,在較低溫度下(1300 oC)便可燒結成功,並得到鈦酸鎂陶瓷的微波介電特性:εr = 15、Q × f 為386,000 GHz、τf = -55 ppm/oC。
    最後,以FR4、Al2O3以及自製陶瓷鈦酸鎂做為基板,設計一個3階Butterworth 髮夾式帶通濾波器,中心頻率為2.4 GHz,頻寬10 %,並使用電磁全波模擬軟體IE3D,討論模擬與實作量測的差異。

    In this paper, the MgO nanospheres and TiO2 nanowires were synthesized separately using polyol-mediated thermolysis process and hydrothermal method. Magnesium titanates that were synthesized by calcination-free solid-state method and traditional solid-state method that used TiO2 and MgO nanopowders as the starting materials.
    Nano-scaled powders were obtained by controlling the reaction time, the solution pH, the reaction temperature, and the concentrations. Magnesium oxide nanospheres and titanium dioxide nanowires possessed high surface area, high purity, good uniformity, and excellent reproducibilitywithout expensive equipment can be mass produced nano-powder at low temperature.
    MgO and TiO2 nano-powders with high surface area were used to synthesize the ilmenite MgTiO3. The Q × f of ~186,000 GHz was obtained by a calcination-free solid-state sintering; the value was similar with those reported in the literature. Moreover, an extremely high Q × f value of 368,000 GHz (at 10 GHz)associated with a τf of ~56 ppm/oC and a εr of ~15 was achieved by a traditional solid-state sintering at a low sintering temperature (1300 oC).
    Finally, we design a three order Butterworth band-pass filter with hairpin shape on various substrates (such as FR4, Al2O3, and MgTiO3). The centeral frequency was 2.4 GHz, FBW was 10 %. The full wave E.M. simulatior IE3D was used to discuss the difference between the simulation and measurement resultes.

    目錄 摘要 i Abstract ii 誌謝 iv 目錄 v 表目錄 ix 圖目錄 x 第一章 序論 1 1-1 前言 1 1-2 研究動機 2 1-3 研究目的 3 第二章 文獻回顧 4 2-1 奈米氧化物合成 4 2-1-1 奈米級氧化鎂特性與製備 6 2-1-2 二氧化鈦奈米線特性與製備 9 2-2 陶瓷燒結理論 10 2-2-1 介電材料的微波特性 10 2-2-2 鈦鐵礦之結構 16 2-2-3 燒結理論 17 2-2-4 煆燒對燒結之影響 17 2-2-5 燒結過程分析,,, 18 2-3 微波介電陶瓷量測理論 19 2-3-1 介電共振器 19 2-3-2 介電共振器理論 20 2-3-3 微波特性的量測 21 2-4 微帶線的原理 26 2-4-1 微帶線傳輸組態 26 2-4-2 微帶線參數公式 27 2-4-3 微帶線諧振器種類 30 2-4-4 集膚效應 31 2-4-5 微帶線的損失 31 2-4-6 微帶線的不連續效應 32 2-5 耦合共振濾波器 34 2-5-1 電場耦合 34 2-5-2 磁場耦合 36 2-5-3 混合耦合 37 2-6 微帶線濾波器設計 39 2-6-1 饋入線之輸入及輸出點設計 39 2-6-2 巴特沃茲濾波器設計 40 第三章 實驗方法 55 3-1 實驗材料及儀器 55 3-2 化學法合成氧化物奈米粉末 56 3-2-1 多元醇熱解法製備氫氧化鎂奈米顆粒 56 3-2-2 水熱法製備二氧化鈦奈米線 56 3-3 無煆燒法合成鈦酸鎂介電陶瓷 57 3-3-1 無煆燒法合成鈦酸鎂製程 58 3-3-2 無煆燒法合成鈦酸鎂分析 59 3-4 固態法燒結合成鈦酸鎂介電陶瓷 59 3-4-1 固態燒結法合成鈦酸鎂製程 59 3-4-2 固態燒結法合成鈦酸鎂分析 60 3-5 低損耗被動微帶線濾波器製作 61 3-5-1 濾波器規格 61 3-5-2 濾波器實作 62 3-5-3 特性量測 62 3-6 量測分析 63 3-6-1 X-ray 繞射分析儀 63 3-6-2 掃描式電子顯微鏡 63 3-6-3 熱差/熱重分析 64 3-6-4 氧化物比表面積量測 64 3-6-5 密度量測 65 3-6-6 微波介電陶瓷量測量測 65 第四章 結果與討論 70 4-1 化學法合成奈米氧化物 70 4-1-1 奈米級氧化鎂結構分析 70 4-1-2 二氧化鈦奈米線結構分析 72 4-1-3 市售奈米級二氧化鈦粉末分析 73 4-2 無煆燒法合成鈦酸鎂特性量測與分析 74 4-2-1 無煆燒法合成鈦酸鎂及DT-TGA、SEM、XRD分析 74 4-2-2 無煆燒法合成鈦酸鎂介電特性量測與分析 75 4-3 固態法燒結合成鈦酸鎂特性量測與分析 76 4-3-1 固態燒結法合成鈦酸鎂及DIL、SEM、XRD、TEM分析 77 4-3-2 固態燒結法合成鈦酸鎂介電特性量測與分析 78 4-4 濾波器頻率響應探討 80 4-4-1 髮夾式耦合濾波器應用於FR4基板 80 4-4-2 髮夾式耦合濾波器應用於氧化鋁基板 81 4-4-3 髮夾式耦合濾波器應用於鈦酸鎂基板 82 第五章 結論 105 第六章 未來展望 107 第七章 參考文獻 108

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