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研究生: 侯俊良
Hou, Jiun-Liang
論文名稱: MCT陶瓷介電特性之研究及其在微波元件之應用
Dielectric Properties and Microwave Applications of MCT Ceramics
指導教授: 黃正亮
Huang, Cheng-Liang
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年: 2005
畢業學年度: 93
語文別: 中文
論文頁數: 89
中文關鍵詞: 微波元件陶瓷介電
外文關鍵詞: microwave, ceramics, MCT
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  • 摘要
      在本論文內將討論0.95MgTiO3 – 0.05CaTiO3介電陶瓷材料,藉由分別添加不同燒結促進劑ZnO、B2O3、SiO2,探討對其微波特性的影響。
      材料方面分為三部分:第一部份為單一添加物對0.95MgTiO3 – 0.05CaTiO3微波性質之影響;第二部份為微量添加ZnO對0.95MgTiO3 – 0.05CaTiO3微波性質之影響;第三部份為混合此三種玻璃添加物對0.95MgTiO3 – 0.05CaTiO3微波性質之影響。實驗結果顯示,添加1wt%的ZnO可有效降低燒結溫度到1350℃,此時可得最佳介電特性εr~20.3,Q×f~66300,因此改善了0.95MgTiO3 – 0.05CaTiO3介電陶瓷的微波特性。
      此外,本論文以FR4、氧化鋁、0.95MgTiO3 – 0.05CaTiO3+1wt%ZnO三種不同基板,製作設計一個緊密的微帶線步階阻抗帶通濾波器,中心頻率定為2.4GHz,頻寬10%。

    Abstract
      The microwave properties of 0.95MgTiO3 – 0.05CaTiO3 dielectric ceramic materials are discussed in this paper. By adding different sintering aids ZnO、B2O3 and SiO2 respectively, we study the existence effects of liquid phase for the microwave properties of 0.95MgTiO3 – 0.05CaTiO3.
      There are three part about the dielectric material. First, we discuss the properties of 95MCT with single sitering aids. Second, we discuss 0.95MgTiO3 – 0.05CaTiO3 adding a trace of ZnO. Third, we mix 0.95MgTiO3 – 0.05CaTiO3 with those three different sintering aids.. The experiment results show that 0.95MgTiO3 – 0.05CaTiO3 with 1wt% ZnO addition can efficiently reduce sintering temperature to 1350 oC, and it appears the best property: εr~20.3, Q×f~66300. Hence, the microwave properties of 0.95MgTiO3 – 0.05CaTiO3 dielectric ceramic materials is improved.
      In addition, we design and fabricate compact SIR band-pass filters with 2.4GHz central frequency and 10% bandwidth on FR4, Al2O3 and 0.95MgTiO3 – 0.05CaTiO3 substrates.

    目錄 第一章 緒論 …………………………………………………………………………  1 1-1. 前言 ……………………………………………………………………  1 1-2. 研究背景與動機…………………………………………………………  1 第二章 文獻探討與原理………………………………………………………………  2 2-1. 介電原理………………………………………………………………  2 2-2. 高頻介電陶瓷材料……………………………………………………  2 2-3. 玻璃成分與微波性質……………………………………………………  4 2-4. 微波介電材料低溫燒結相關文獻……………………………………  6 2-5. 液相燒結裡論 …………………………………………………………  6 2-6. TMA熱膨脹係數 …………………………………………………………  10 第三章 微波濾波器電路理論 …………………………………………………………  12 3-1.集總元件濾波器之簡介………………………………………………  12 3-1-1. Butterworth濾波器………………………………………………  12 3-1-2.Chebyshev濾波器………………………………………………  13 3-1-3. Elliptic濾波器……………………………………………………  14 3-2. 微帶線原理………………………………………………………………  15 3-2-1. 微帶線傳輸組態………………………………………………  16 3-2-2. 微帶線各項參數公式 …………………………………………  16 3-3. 微帶線的不連續效應……………………………………………………  18 3-3-1 不對稱的步階不連續接面…………………………………………  19 3-3-2. 開路端效應……………………………………………………  20 3-3-3. T-Junction處效應………………………………………………  21 3-4. 步階阻抗共振器…………………………………………………………  21 3-5. 二級共振器之 模型等效電路…………………………………………  24 3-6. 微帶線SIR濾波器電路佈局…………………………………………  26 第四章 實驗製程與量測……………………………………………………………  28 4-1.微波介電材料之製作程序………………………………………………  28 4-2.特性分析與量測 …………………………………………………………  30 4-2-1. X-Ray分析(XRD) ………………………………………………  30 4-2-2. 掃瞄式電子顯微鏡(SEM)分析 ………………………………  30 4-2-3. 密度之量測……………………………………………………  30 4-2-4. 微波特性之量測………………………………………………  31 4-3.濾波器之製作與量測……………………………………………………  33 4-3-1. 濾波器規格……………………………………………………  33 4-3-2. 濾波器實作……………………………………………………  34 4-3-3. 特性量測 …………………………………………………………  34 第五章 實驗結果與討論………………………………………………………………  35 5-1. (0.95MgTiO3 - 0.05CaTiO3)添加燒結促進劑特性探討 …………  35 5-1-1. 未添加燒結促進劑之特性……………………………………  35 5-1-2. 添加燒結促進劑ZnO之影響……………………………………  35 5-1-3. 添加燒結促進劑B2O3之影響……………………………………  42 5-1-4. 添加燒結促進劑SiO2之影響……………………………………  50 5-1-5. 添加微量燒結促進劑ZnO之影響 ………………………………  57 5-1-6. (1-x)95MCT - x(ZnO、SiO2、B2O3)系統……………………  67 5-2. 濾波器特性探討…………………………………………………………  78 5-2-1. FR4基板特性探討………………………………………………  79 5-2-2. Al2O3基板特性探討 ………………………………………………  80 5-2-3. (0.95MgTiO3 - 0.05CaTiO3)基板特性探討 ……………………  83 第六章 結論與未來展望………………………………………………………………  86 參考文獻 ………………………………………………………………………………  88

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