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研究生: 李清平
Lee, Ching-Ping
論文名稱: 鈷、鋁共摻雜氧化鋅系統其鋁對磁性影響之研究
The effect of Al on the magnetic property of (Co, Al) co-doped ZnO system
指導教授: 黃榮俊
Huang, J. C. A.
學位類別: 碩士
Master
系所名稱: 理學院 - 物理學系
Department of Physics
論文出版年: 2008
畢業學年度: 96
語文別: 中文
論文頁數: 89
中文關鍵詞: 氧化鋅稀磁性半導體束縛極化子
外文關鍵詞: Diluted magnetic semiconductor, BMP model, ZnO
相關次數: 點閱:87下載:7
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  • 討論以不同施子能階的束縛極化子對鈷摻雜在氧化鋅的薄膜中對樣品磁性上的影響,可以發現較淺層的施子能階可以讓樣品有較大的磁性。本實驗討論兩種不同的施子能階,分別是氧化缺所產生的施子能階及以鋁三正離子取代鋅二正離子時產生的施子能階,由結果可以發現鋁三正離子取代鋅二正離子時產生的施子能階能使樣品有較大的飽和磁化量,這是由於其施子能階較氧空缺更為淺層。且退火後不同施子數量變化的不同,也造成樣品磁性的變化也不一致。

    In this thesis, the effect of different donors on the magnetic properties of Co-doped ZnO was investigated, and it was found that when the donor level was shallower, the magnetic of samples was larger. We discussed two kind of donor level: oxygen vacancy and the substitution of Al3+ for Zn2+, and the result is the sample with Al3+ -substituted Zn2+ had larger saturation magnetization, this is due to the donor level is shallower than oxygen vacancy. Furthermore, after the annealing, different kind of donor had different change of magnetic properties.

    第一章 序論 1 1-1 前言 1 1-2 氧化鋅薄膜特性簡介 2 1-3 文獻回顧 4 1-4 研究動機 18 第二章 相關理論介紹 20 2-1 平均場理論(Mean Field Theory) [2.1] 20 2-2 磁性來源機制 23 2-2-1雙交換耦合機制(Double Exchange) [2.3] 23 2-2-2 交互巡迴式鐵磁性(Itinerant Ferromagnetism) [2.7][2.8][2.9] 24 2-2-3 侷限載子式鐵磁性(Localized Carrier) [2.11][2.12] 26 2-2-4 束縛極化子模型[2.13] 27 第三章 儀器介紹與實驗流程 30 3-1 樣品備製 30 3-1-1 離子束濺鍍系統(Ion beam sputter,IBS) 30 3-1-2 樣品製備流程 34 3-1-3 退火處理儀器 35 3-2 實驗量測儀器 38 3-2-1 X-ray繞射儀 38 3-2-2 超導量子干涉磁量儀[3.3] 39 3-2-3 X-ray吸收光譜[3.4][3.5] 41 3-2-4 霍爾效應量測[3.6] 50 第四章 實驗結果與討論 53 4-1 (Co, Al)/ZnO多層膜不同鋁含量時各種分析 54 4-1-1 結構分析 57 4-1-2 UV-VIS光譜分析 60 4-1-3 Co L-edge 分析 64 4-1-4 Co K-edge分析 70 4-2 Co/ZnO DMS有無摻雜Al 3.5 at.%時其電性及磁性比較 77 4-2-1 電性量測 77 4-2-2 磁性量測 79 第五章 結論 88

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