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研究生: 黃柏閣
Huang, Bo-Ge
論文名稱: 鋰離子電池等效模型建立與快速充電策略之研究
A Study on Lithium-Ion Battery Modeling and Fast Charging Strategy
指導教授: 黃世杰
Huang, Shyh-Jier
學位類別: 博士
Doctor
系所名稱: 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年: 2013
畢業學年度: 101
語文別: 英文
論文頁數: 87
中文關鍵詞: 電池模型快速充電鋰離子電池關聯式向量機
外文關鍵詞: Battery model, fast charge, Li-ion battery, Relevance vector machine
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  • 隨著二氧化碳過度排放所造成之全球溫室效應,綠色能源技術與其相關應用已成為全球最受關注之議題,推廣電動載具普及使用更列為各國目前發展重點,並均極力投入電動載具研發,而於電動載具發展技術中,又以電源系統設計為關鍵研發技術設計之良好與否,直接影響載具之操控性能與續航力。綜觀目前電源系統設計,多以能量型鋰電池作為核心,作為電動載具能量來源。而此類能量型鋰電池於運轉時狀態,諸如電壓/電流響應,溫度與阻抗等,更為評估電源模組是否正常操作之重要指標。至於充電策略擬定,則亦同樣大幅影響較高容量之電池模組便利性,若能展現優良充電程序之數項優勢,諸如縮短充電時間、延長電池模組壽命及提升充電效率,必將頗有助於綠能科技之再升級。惟目前對於鋰電池特性之研究仍未臻成熟,且於鋰電池模組設計與充電策略研製時,多使用簡單等效電路進行分析或運轉狀態評估,恐難以切確掌握鋰電池運轉相關特性。
    有鑑於此,本論文提出一程序化之鋰電池模型建立流程,該流程結合混合式平均法、縮減型關聯式向量機與即時內阻測量法,進而建立鋰電池開路電壓與內阻等效參數;接著本論文亦將所研製之等效模型予以延伸,發展鋰電池快速充電策略。經由模型模擬與實際試測結果比較可知,本論文所提方法除可迅速決定鋰電池各項等效參數,模擬電池於各種不同操作情況下之電壓特徵;同時亦可抑制實際環境中取樣雜訊及提升電路評估精確度;且以該等效電路為核心所擬定之充電策略,將可順利完成快速充電之要求,大幅降低充電等待時間,應有助於未來落實於綠能科技之廣泛應用。

    Following the greenhouse effect by excessive carbon emissions, applications of green energy has become a critically important issue. As for the goal of popularizing the electronic vehicles, this topic is even one of important developments considered in most countries around the world. Among these green technologies, the research made on the battery related study is deemed the kernel one. The performance of battery module has a direct influence on the control quality and cruising endurance in transportation carriers, where the high-energy Li-ion battery plays a key role to be the primary source for electric drives. The states of high-energy battery under different operations including voltage/current response, battery temperature, and battery impedance become the most concerned in the performance evaluation of batteries. The charge strategy meanwhile is highly related with the battery performance exhibition as well. With a proper strategy made for the battery-charging task, the time of charging can be shorten while extending the cycle life and improving the charging efficiency. However, previous studies which were contributed to the characterizations of Li-ion battery and the investigation of different charge strategies were yet limited, lacking of grasping the overall characteristics of battery operations.
    In view of aforementioned problems, this dissertation proposed a systemic procedure of battery model formulation. This modeling includes hybrid averaging method, trimmed relevance vector machine, and impedance networks observation method, by which the parameters of equivalent circuits of a Li-ion battery can be well established. This battery model can be effectively extended as the useful reference to determine the fast charge strategy. From the simulation outcomes and experimental results, they have confirmed that this proposed method not only rapidly determines the parameters of Li-ion battery equivalent circuit, but also simulates the battery voltage responses under different loads. This method is also capable of restricting the sampling noise, enhancing the accuracy of the equivalent circuit evaluation. The charge method based on the proposed equivalent circuit was also found to more effectively reach the requirements of fast charging and achieves the goal of charging time reduction. The benefits gained from this study will be beneficial to promote a wide utilization of green technologies.

    摘要 I Abstract II 誌謝 IV LIST OF TABLES VII LIST OF FIGURES VIII CHAPTER 1 Introduction 1 1.1 Motivation and Background 1 1.2 Literature Survey 4 1.3 Contribution of this Dissertation 7 1.4 Outline of the dissertation 8 CHAPTER 2 Analysis of a Li-ion Battery 10 2.1 The structure of a Li-ion battery 10 2.2 Battery voltage of a Li-ion battery 11 2.3 Battery impedance of a Li-ion battery 12 2.4 Equivalent circuit of a Li-ion battery 13 CHAPTER 3 A Cooperation Design for Super-Capacitor and Lithium-Ion Battery 14 3.1 Introduction 14 3.2 Paradigm and methodology 14 3.3 Experimental results 18 3.3.1 Comparison of internal resistances 18 3.3.2 Evaluations of parameters of battery in simulation and experiment 19 3.3.3 Validity of cooperation in battery and ultra-capacitor 20 3.4 Summary 23 CHAPTER 4 An Approach to Measurements of Electrical Characteristics of Lithium-ion Battery with OCV Function 24 4.1 Introduction 24 4.2 Battery equivalent circuit 25 4.3 Modeling the equivalent circuit of Li-ion battery 26 4.3.1 Hybrid averaging method 26 4.3.2 Formulation of the OCV characterization 29 4.3.3 Impedance network observation approach 30 4.3.4 The proposed process of modeling Li-ion battery 33 4.4 Experimental Results 34 4.4.1 De-noise capability of methods 35 4.4.2 Performance of OCV pattern retrieval using proposed hybrid averaging method 37 4.4.3 The OCV function formulation by the proposed method 38 4.4.4 Method Comparisons 41 4.4.5 Total evaluations of proposed parameter extractions 42 4.5 Summary 46 CHAPTER 5 Design of Charging Controllers for a Lithium-Ion Battery with Evaluation of Open-Circuit Voltage Function 47 5.1 Introduction 47 5.2 Characterization of a Li-ion battery 47 5.2.1 Equivalent circuit 47 5.2.2 Open-circuit voltage function formulations 49 5.3 Proposed charge strategy 50 5.4 Hardware implementation 51 5.5 Experimental results 52 5.5.1 Charging inspection. 52 5.6 Summary 54 CHAPTER 6 Fast Charge Strategy Based on the Characterization and Evaluation of LiFePO4 Batteries 55 6.1 Introduction 55 6.2 Electrical characterization of a LFP battery 55 6.2.1 Equivalent circuit of a LFP battery 55 6.2.2 Residual energy model of the LiFePO4 56 6.2.3 Hysteresis effect of LFP battery 58 6.3 Proposed strategy of the rapid charge 61 6.4 Experimental resuts 63 6.4.1 Evaluation of residual energy 64 6.4.2 Validation of battery charging performance 67 6.4.3 Assessment of battery cycle life 72 6.4.4 Validation of the proposed strategy with the external resistance added 74 6.5 Summary 76 CHAPTER 7 Conclusion 77 7.1 Conclusion 77 7.2 Future work 77 Reference 79 Biography 87

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