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研究生: 黃冠憲
Huang, Guan-Sian
論文名稱: (Mg0.95Mn0.05)TiO3微波介電材料之改善與應用
Improved and Applications of (Mg0.95Mn0.05)TiO3 Microwave Dielectric Material
指導教授: 黃正亮
Huang, Cheng-Liang
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年: 2010
畢業學年度: 98
語文別: 中文
論文頁數: 122
中文關鍵詞: 微波介電材料低損耗
外文關鍵詞: microwave dielectric, low loss
相關次數: 點閱:83下載:1
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  • 在此篇論文中主要介紹兩大部分,第一部份將介紹低損耗的介電材料,且嘗試著調整共振頻率溫度飄移係數使其為零;第二部份將介紹其在被動元件之應用,並實作於不同基板上探討元件尺寸的改善。
    第一部份首先要介紹(Mg0.95Mn0.05)TiO3陶瓷系統之微波介電特性。由實驗中可得知(Mg0.95Mn0.05)TiO3在1330°C燒結4小時可得到最佳之介電特性εr ~ 17,Q׃~ 220,000 (at 10 GHz),τf ~ –58 ppm/°C。由於此系統之τf為負值,我們添加具正值共振頻率溫度飄移係數的鈣鈦礦材料CaTiO3 (+800 ppm/°C)、Ca0.8Sm0.4/3TiO3 (+400 ppm/°C)及Ca0.8Sr0.2TiO3 (+991 ppm/°C),探討共振頻率溫度飄移係數趨近零之最佳比例。
    第二部份我們設計及實作一操作在2.4 GHz的微帶線帶通濾波器,濾波器主要採用一電場耦合的SIR結構做為主體,使用零度饋入的方式在通帶兩側產生傳輸零點,並加入一開路殘段(Open-stub)來改善倍頻寄生響應。最後,我們將此電路實作在FR4、氧化鋁和0.94(Mg0.95Mn0.05)TiO3–0.06Ca0.8Sr0.2TiO3基板上,並量測其頻率響應。由量測的結果可得知,利用高介電係數及低損耗的材料做為電路基板時,確實能達到提升效能和縮小面積的需求。

    There are two main subjects in this thesis. First, we will discuss the low loss dielectric material, and try to adjust temperature coefficient of resonant frequency near zero. Second, there will be a discussion of passive components and improvement of circuit size in different substrates.
    First, the microwave dielectric properties of (Mg0.95Mn0.05)TiO3 ceramic system have been investigated. The experiment results show that (Mg0.95Mn0.05)TiO3 ceramics has the best properties at sintering temperature 1330°C for 4 hours, which could reach the best dielectric properties εr~ 17, Q×f ~ 220,000 (at 10 GHz) and τf ~ –57 ppm/°C. Concerning about the negative value of τf, we choose adding the CaTiO3 (+800 ppm/°C), Mg0.95Co0.05TiO3 (τf ~ –55 ppm/°C), and Ca0.8Sr0.2TiO3 (+991 ppm/°C) to adjust the value, then we could make temperature coefficient of resonant frequency near zero.
    Second, we design and fabricate a microstrip band-pass filter which resonator at 2.4 GHz. The filter was constructed by two stepped impedance resonators using electric coupling. In order to product transmission zeros on the opposite of the passband of band-pass filter, zero-degree feed tapping feed lines were be used. Finally, an open-stub was added to suppress the spurious response. The pattern was printed on FR4, Al2O3 and 0.94(Mg0.95Mn0.05)TiO3–0.06Ca0.8Sr0.2TiO3 substrates. By measured their frequency responses, using the substrates of high dielectric constant and low loss, which can improve the performance and reduce filter’s size.

    第一章 緒論...1 1-1 前言...1 1-2 研究目的...1 第二章 介電材料原理...3 2-1 介電材料之微波特性...3 2-1-1介電係數(Dielectric constant:K、εr)...3 2-1-2品質因數(Quality factor:Q)...6 2-1-3共振頻率溫度飄移係數(Temperature coefficient of resonant frequency:τf)...8 2-2介電共振器(Dielectric resonator:DR)原理...9 2-3鈦鐵礦結構(Ilmenite structure)...14 2-4鈣鈦礦結構(Perovskite structure)...15 2-5材料的燒結...17 2-5-1燒結的種類...17 2-5-2材料燒結之擴散方式...18 2-5-3材料燒結之過程...19 第三章 微帶線及濾波器原理...20 3-1 濾波器原理...20 3-1-1濾波器的簡介...20 3-1-2濾波器之種類及其頻率響應...21 3-2 微帶線原理...24 3-2-1 微帶傳輸線的簡介...24 3-2-2 微帶線的傳輸模態...24 3-2-3 微帶線各項參數公式計算及考量...25 3-2-4 微帶線的不連續效應...28 3-2-5 微帶線的損失...34 3-3 微帶線諧振器種類...35 3-3-1 λ/4短路微帶線共振器...36 3-3-2 λ/2開路微帶線共振器...37 3-4 共振器間的耦合形式...38 3-4-1 電場耦合:...38 3-4-2 磁場耦合:...42 3-4-3 混和耦合:...45 3-5 零度饋入(非對稱性饋入)...48 3-6 步階阻抗諧振器...50 第四章 實驗程序與量測方法...52 4-1 微波介電材料的製備...52 4-1-1 粉末的製備與球磨...53 4-1-2 粉末的煆燒...53 4-1-3 粉末的混相調配...53 4-1-4 加入黏劑、過篩...54 4-1-5 壓模成型、去黏劑及燒結...54 4-2 微波介電材料的量測與分析...54 4-2-1 密度測量...54 4-2-2 X-Ray分析...55 4-2-3 SEM、EDS分析...55 4-2-4 介電特性量測與分析...55 4-2-5 共振頻率溫度飄移係數之量測...62 4-3 濾波器的製作與量測...62 第五章 實驗結果與討論...65 5-1 (1–x)(Mg0.95Mn0.05)TiO3–xCaTiO3之微波介電特性...66 5-1-1 (1–x)(Mg0.95Mn0.05)TiO3–xCaTiO3之τf分析結果...66 5-1-2 (1–x)(Mg0.95Mn0.05)TiO3–xCaTiO3之XRD分析結果...67 5-1-3 (1–x)(Mg0.95Mn0.05)TiO3–xCaTiO3之EDS、SEM分析結果...68 5-1-4 (1–x)(Mg0.95Mn0.05)TiO3–xCaTiO3之密度分析結果...77 5-1-5 (1–x)(Mg0.95Mn0.05)TiO3–xCaTiO3之K、Q×f分析結果...78 5-2 (1–x)(Mg0.95Mn0.05)TiO3–xCa0.8Sm0.4/3TiO3之微波介電特性...80 5-2-1 (1–x)(Mg0.95Mn0.05)TiO3–xCa0.8Sm0.4/3TiO3之τf分析結果...80 5-2-2 (1–x)(Mg0.95Mn0.05)TiO3–xCa0.8Sm0.4/3TiO3之XRD分析結果...81 5-2-3 (1–x)(Mg0.95Mn0.05)TiO3–xCa0.8Sm0.4/3TiO3之EDS、SEM分析結果...82 5-2-4 (1–x)(Mg0.95Mn0.05)TiO3–xCa0.8Sm0.4/3TiO3之密度分析結果...92 5-2-5 (1–x)(Mg0.95Mn0.05)TiO3–xCa0.8Sm0.4/3TiO3之K、Q×f分析結果...93 5-3 (1–x)(Mg0.95Mn0.05)TiO3–xCa0.8Sr0.2TiO3之微波介電特性...94 5-3-1 (1–x)(Mg0.95Mn0.05)TiO3–xCa0.8Sr0.2TiO3之τf分析結果...95 5-3-2 (1–x)(Mg0.95Mn0.05)TiO3–xCa0.8Sr0.2TiO3之XRD分析結果...95 5-3-3 (1–x)(Mg0.95Mn0.05)TiO3–xCa0.8Sr0.2TiO3之EDS、SEM分析結果...97 5-3-4 (1–x)(Mg0.95Mn0.05)TiO3–xCa0.8Sr0.2TiO3之密度分析結果...107 5-3-5 (1–x)(Mg0.95Mn0.05)TiO3–xCa0.8Sr0.2TiO3之K、Q×f分析結果...108 5-4 濾波器的模擬與實作...109 5-4-1 使用FR4(玻璃纖維基板)之模擬與實作結果...110 5-4-2 使用Al2O3之模擬與實作結果...112 5-4-3使用自製基板(0.94MMT–0.06CSrT)之模擬與實作結果...114 第六章 結論...118 參考文獻...120

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