I-1. 以循環伏安法探討酚紅(sulfonephthalein)之電化學性質並於玻璃碳電極表面形成聚酚紅薄膜。研究發現酚紅結構中之醌甲基位置具電化學活性並且為酚紅氧化還原與聚合反應之主要來源。從酚紅的循環伏安圖以及酚紅與聚酚紅之紅外線光譜得知，以陽極方向掃描而得之自由基陽離子先行耦合，經鏈增長過程再進一步形成聚合物。經聚酚紅修飾之玻璃碳電極以計時安培分析法、線性掃描伏安法、微分脈衝伏安法探討對分析物質的異相催化反應常數、擴散係數、質傳係數與其他電化學參數。實驗結果顯示聚酚紅玻璃碳電極對對-乙醯胺基酚與多巴胺的氧化催化速率常數分別為1.29×103與8.45×102 M−1 s−1。對此二者之定性測量所得之線性範圍分別為0.4-1.8 mM (0.026 μA μM−1) 與20-160 μM ( 0.16 μA μM−1)。
I-2. 數十年來，化學感測材料一直有穩定的發展，對於特定感測之對象這些材料具有相當程度以上的需求。然而，多功能材料或獨特性材料的研發是主要的屏障。本研究提出以新奈米結構聚合物作為電化學感測材料之合成與其催化效能探討。以5-氨基四唑(5-amino-1H-tetrazole)作為聚合單體，利用電聚合法施以氧化電位產生自由基以引發聚合反應而將這個單體聚合於電極上，產生之聚合物薄膜利用循環伏安法探討其電化學行為，其化學結構與反應機構以FTIR探討。以循環伏安法探討其可能之聚合機構，以計時安培分析法探討聚合物之氧化催化效率與其他電化學參數。最後聚合物修飾電極針對某些化合物做感測之應用，研究對象如dopamine, ascorbic acid, uric acid, acetaminophen等。期望此電極具有低感測極限、寬線性範圍、高選擇性、高穩定性等優點並具備發展潛力以應用於各個適當之領域。
II. 以循環伏安法探討CuCl2、AlCl3與SeO2各個化合物於酸性水溶液環境下在玻璃碳電極上的電化學行為。並藉由伏安法對具有氧化還原活性物質之研究，以嘗試推測CuAlSe2在電極表面共沉積的機制。CuAlSe2的共沉積是由各個前驅物經由還原與(或)化學反應形成Al2Se3與Cu2Se，最後在電極表面結合形成最終產物。電沉積過程中加入三乙醇胺做為錯合劑以利共沉積的進行，在摻錫氧化銦玻璃電極上形成達到化學計量比的CuAlSe2薄膜。薄膜以X光繞射儀、場發射掃描式電子顯微鏡、紫外可見光光譜儀、歐傑電子能譜儀與X光能量分散光譜分析儀做材料定性定量與光學性質測量。

I-1. The electrochemical properties of phenol red were investigated and the fabrication of poly(phenol red) film on glassy carbon electrode was achieved by the technique of cyclic voltammetry. The sector of quinone methide in the structure of phenol red was found electroactive in aqueous solution and is the center of redox reactions for polymerization. Cyclic voltammograms of phenol red and FTIR spectra of both phenol red and poly(phenol red) suggest that the radical cations which were generated from the scans in anodic direction first coupled to a dimer and propagated further into polymers. The modified electrode was exploited in electrochemical studies such as chronoamperometry, linear sweep voltammetry, and differential pulse voltammetry for the evaluation of the rate constant of heterogeneous catalytic reaction along with the diffusion coefficients and transfer coefficients of acetaminophen and dopamine, and simultaneous determination of the analytes of interest. Heterogeneous rate constant of 1.29×103 and 8.45×102 M−1 s−1 was each evaluated for the oxidative reaction of acetaminophen and dopamine by the modified electrode, respectively. The linear range for acetaminophen was evaluated to be in the range of 0.4-1.8 mM with the sensitivity of 0.026 μA μM−1 and that for dopamine is 20-160 μM with the sensitivity of 0.16 μA μM−1.
I-2. A conducting polymer-modified electrode was proposed in this work, which was fabricated by electropolymerization of 5-amino-1H-tetrazole (ATet) on a glassy carbon electrode. Electrochemical studies such as differential pulse voltammetry and chronoamperometry were performed for the evaluation of the rate constant of the catalytic reaction, the diffusion coefficient of the analyte dopamine, and the linear range for analyte determination. The film modified electrode has superior resolving power in quantitative determination from the mixture of analytes and it was found to be an efficient functionalized electrode for its sensitivity and selectivity toward the analyte of interest.
II. The electrochemical behavior of the compositional ingredients CuCl2, AlCl3 and SeO2 individually or collectively in acidic aqueous solution was investigated on a glassy carbon electrode using the technique of cyclic voltammetry. Co-electrodeposition mechanism of CuAlSe2 was attempted to be unraveled through cyclic voltammetric study of the electroactive species. The formation of CuAlSe2 was found to be achieved by the generation of the compounds Al2Se3 and Cu2Se via reductions and/or chemical reactions of the precursors. Triethanolamine as the complexing agent was introduced in the electrodeposition of CuAlSe2 on indium doped tin oxide glass substrates in order to assist the deposition and the stoichiometric composition of CuAlSe2 thin films was fabricated. The deposited thin films were characterized by X-ray diffraction, scanning electron microscopy, UV-Vis spectrometry, Auger electron spectroscopy and energy dispersive X-ray spectrometry analysis.

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