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研究生: 朱冠維
Chu, Kaung-Way
論文名稱: 透明導電膜氮化鈦於發光二極體上之分析與研究
The Analysis for TiN Films on LEDs as Transparent Conductive Films
指導教授: 王永和
Wang, Yeong-Her
洪茂峰
Houng, Mau-Phon
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 微電子工程研究所
Institute of Microelectronics
論文出版年: 2003
畢業學年度: 91
語文別: 英文
論文頁數: 74
中文關鍵詞: 透明導電膜氮化鈦發光二極體
外文關鍵詞: titanium nitride (TiN), transparent contacting, light emitt diodes (LEDs)
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  • AlGaInP發光二極體大多是成長在n-型GaAs基板上,電流自p層由上而下至主動層以產生光。要得到高發光效率,p層的電流分佈非常重要。為了促進電流分佈以提高發光二極體的發光效率,本論文試著沉積一層氮化鈦薄膜,並藉由不錯的熱穩定性與散熱作用,達到在高發光效率時有更佳之電流分布作用。
    本論文利用真空濺鍍系統在AlGaInP發光二極體上沈積氮化鈦薄膜來作為透明電極。並以XRD、AES、XPS為分析的主軸,試著從材料分析的角度探討含氧量與結晶性對於氮化鈦薄膜品質的影響。氮化鈦沈積在p-型磷化鎵上呈現整流特性。因此嘗試先沈積一層鈦當作緩衝層以提升氮化鈦的薄膜品質,並可同時兼顧氮化鈦的光特性及電特性。如預期的發光二極體的臨界電壓(在20mA時)有明顯下降,且電流分佈也有增加的趨勢。

    AlGaInP LEDs were commonly grown on n-GaAs substrates, the drive current from the p-type material flew to active layer and generated light. A very important factor for high efficiency for luminescence of the device was the current spreading effect of p-type layer. To improve the current spreading effect, in this thesis we tried to sputter a thin TiN films. Since with better thermodynamic stability of TiN, LEDs may have a better current spreading effect for high efficiency for luminescence than without TiN.
    The work reported in this paper showed that TiN films were deposited on AlGaInP LED surfaces to form transparent contacts by sputtering system. And with the help of XRD、AES、XPS, we tried to aim at the aspect of material analysis then discussed the content of oxygen and the trend for crystallization to the quality of TiN films and the effects on LEDs. The TiN films deposited on p-GaP exhibited rectifying properties. We deposited a thin Ti as buffer layer to improve the quality of TiN films, and to look after both light output and electrical properties meanwhile. As expectancy, Vf(at 20mA)of the LEDs decreased apparently, and promoted the tendency of the current with better spreading of the devices as well.

    Chapter1 Introduction……………………………………………………………………1 1.1 Motivations with the Properties of TiN……………………………………1 1.2 Brief statements for AlGaInP LEDs……………………………………………2 1.3 Organizations of the Thesis………………………………………………………5 Chapter2 Basic Characteristics of the Experiment……………………………6 2.1 Sputtering system techniques……………………………………………………6 2.1.1 Principle of sputtering………………………………………………………6 2.1.2 Glow discharge DC sputtering…………………………………………………7 2.1.3 High rate sputtering deposition……………………………………………8 2.1.4 Reactive sputter deposition…………………………………………………11 2.2 Ohmic contacts………………………………………………………………………11 2.2.1 Theory of ohmic contacts……………………………………………………12 2.2.2 Practical of ohmic contacts…………………………………………………14 2.3 PL Spectra of the AlGaInP LEDs………………………………………………15 Chapter3 Experiment for material and device fabrications………………18 3.1 Samples Preparation and process concepts…………………………………18 3.1.1 Pre-Processing Cleaning………………………………………………………18 3.1.2 Sputtering TiN films……………………………………………………………19 3.1.3 Fabrication the Devices with Transparent Contacts…………………19 3.2 Characterization of this Thin Films…………………………………………20 3.3 Electrical Measurement of LEDs…………………………………………………22 Chapter4 Discussions for Material Analysis and Device Characteristics……………………………………………………………………………24 4.1 Material analysis for TiN films………………………………………………24 4.1.1 SEM Cross Section View & AFM Surface Morphology……………………25 4.1.2 XRD for crystallization analysis…………………………………………25 4.1.3 AES Depth Profile…………………………………………………………………27 4.1.4 XPS Surface Analysis of Ti 2p3/2 spectra………………………………28 4.2 Growth conditions of TiN Films…………………………………………………29 4.2.1 Thickness with the Deposition Time…………………………………………29 4.2.2 Resistivity of Deposited TiN Films ………………………………………29 4.2.3 Transmittance of Deposited Thin Films……………………………………30 4.3 Summary of this section……………………………………………………………31 4.4 LED Performance………………………………………………………………………31 4.4.1 Electrical properties……………………………………………………………31 4.4.2 Optical Properties………………………………………………………………32 Chapter5 Conclusions & Future Works………………………………………………35 References……………………………………………………………………………………37

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