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研究生: 郭展綱
Guo, Jhan-Gang
論文名稱: 燒結促進劑對0.9CaWO4-0.1Mg2SiO4介電陶瓷之影響與應用
The Effect and Application of 0.9CaWO4-0.1Mg2SiO4 Dielectric Ceramics Added Sintering Aids
指導教授: 黃正亮
Huang, Cheng-Liang
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年: 2004
畢業學年度: 92
語文別: 中文
論文頁數: 76
中文關鍵詞: 介電陶磁介電常數
外文關鍵詞: dielectric ceramics, dielectric constant
相關次數: 點閱:46下載:7
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  •   本論文內討論0.9CaWO4-0.1Mg2SiO4介電陶瓷材料,分別添加燒結促進劑V2O5、B2O3、及CuO不同含量時,產生的液相對其微波特性之影響。實驗結果顯示,適當添加燒結促進劑可降低0.9CaWO4-0.1Mg2SiO4之燒結溫度。當添加0.25wt%之V2O5時有最佳的微波介電特性,其εr 值為約10,Q*f值約為70000,共振頻率溫度係數(τf)約為-53(ppm/oC),並可將燒結溫度由1200℃降低至1080℃。
      另外,本論文以FR4、Al2O3、0.9CaWO4-0.1Mg2SiO4為基板,製作設計一使用增強型調整殘段耦合環型共振器之帶通濾波器,其中心頻率為2.45GHz,頻寬約為5%。利用軟體模擬並與實作的結果作特性上之比較。

      The effects of microwave dielectric properties of 0.9CaWO4-0.1Mg2SiO4 adding different amounts of sintering aids V2O5, B2O3, and CuO which could produce liquid phase have been discussed in this paper. The results show that adding sintering aids can lower the sintering temperature of 0.9CaWO4-0.1Mg2SiO4 ceramics. The best properties of the microwave dielectric are εr = 10, Q*f = 70000, and τf = -53, as 0.25wt% V2O5 additions. And lower the sintering temperature from 1200℃ to 1080℃.
      In addition, a bandpass filter using ring resonators with enhanced-coupling tuning stubs on FR4, Al2O3, and 0.9CaWO4-0.1Mg2SiO4 substrates have been design. The center frequency is 2.45GHz, the bandwidth is 5%. And we compared the result of the simulation with the result of the measurement of the performance.

    第一章 緒論   ………………………………………………………………  1 1-1. 前言 ……………………………………………………………  1 1-2. 研究背景與動機  ………………………………………………  1 1-3. 論文架構 ………………………………………………………  2 第二章 介電材料原理   ………………………………………………………  3 2-1. 微波電性與介電原理   …………………………………………  3 2-2. 介電共振原理 …………………………………………………  10 2-2-1. 馬克思威爾方程式之推導 ……………………………  14 2-3. 燒結原理   ………………………………………………………  16 2-3-1. 液相燒結理論   …………………………………………  16 第三章 微波濾波器電路理論   ……………………………………………  18 3-1. 微波濾波器之簡介   ……………………………………………  18 3-2. 微帶線原理 ……………………………………………………  19 3-2-1. 微帶線傳輸組態 ………………………………………  19 3-2-2. 微帶線各項參數公式計算及考量   ……………………  20 3-3. 使用增強型調整殘段耦合環型共振器之帶通濾波器 ………  26 3-3-1. 採用正交饋入線之環型耦合共振器 ……………… 27 3-3-2. 使用增強型耦合調整殘段之環型共振器 …………… 28 第四章 實驗製程與量測   …………………………………………………  30 4-1. 微波介電材料之製備   …………………………………………  30 4-2. 特性分析與量測  ………………………………………………  32 4-2-1. X-Ray分析(XRD)   ……………………………………  32 4-2-2. 掃瞄式電子顯微鏡(SEM)分析  ……………………  32 4-2-3. 密度之量測 ……………………………………………  32 4-2-4. 微波特性之量測 ………………………………………  33 4-3. 濾波器之製作與量測  …………………………………  40 4-3-1. 濾波器規格 ……………………………………………  40 4-3-2. 濾波器實作 ……………………………………………  40 4-3-3. 特性量測  ………………………………………………  41 第五章 實驗結果與討論   ……………………………………………………  42 5-1.(0.9CaWO4-0.1Mg2SiO4)添加燒結促進劑特性探討 ………  42 5-1-1. 未添加燒結促進劑之特性 ……………………………  42 5-1-2. 添加燒結促進劑V2O5之影響   …………………………  42 5-1-3. 添加燒結促進劑B2O¬3之影響 …………………………  50 5-1-4. 添加燒結促進劑CuO之影響   …………………………  57 5-2. 濾波器特性探討  ………………………………………………  63 5-2-1. FR4基板特性探討 ………………………………………  64 5-2-2. Al2O3基板特性探討  ……………………………………  66 5-2-3. 0.9CaWO4 – 0.1Mg2SiO4基板特性探討  ………………  68 第六章 結論與未來展望   ……………………………………………………  71 參考文獻 ………………………………………………………………………  73

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