本論文是利用水熱反應合成五個新穎化合物，合成出的化合物會先經由單晶X-光繞射儀分析定出其結構，再藉由元素分析儀、粉末X-光繞射儀、磁性和熱重量/熱差分析儀輔助鑑定之。依其結構型態可分為二個不同的系統。第一個系統包含二個三維孔洞化合物[Nd2(H2O)4(C2O4)(C4H4O4)2]•4H2O (1)和[Na2(H2O)2Nd2(C2O4)3(C4H4O4)]•2H2O (2)。化合物1由丁二酸根將釹離子連結起來，形成二維的網狀結構。再由草酸根連接各層，形成具四方形通道的三維結構。化合物2由六個釹離子與六個草酸根形成類似蜂巢狀的層狀結構，並有丁二酸支撐在其中。層跟層之間則由草酸相連，構成三維結構。由其熱重量/熱差分析圖可知化合物1在脫去了所有的水之後形成穩定的中間產物[Nd2(C2O4)(C4H4O4)2]。將其與水反應數日之後，可回復結晶性。化合物1和2的磁性測量顯示，這二個化合物的mT值隨溫度下降而降低，且值皆為負值，由此推測，這二個化合物可能具有微弱的逆磁性。
在第二個系統中則包含了NH4[Nd(H2O)(C2O4)(SO4)] (3)、NH4[Eu(H2O)(C2O4)(SO4)] (4)和NH4[Gd(H2O)(C2O4)(SO4)] (5)這三個新穎三維化合物。之前，我們實驗室曾經以鈰金屬為中心，合成具有相似的化合物。其通式可寫為NH4[Ln(H2O)(C2O4)(SO4)] , (Ln=Ce、Nd、Eu、Gd)。由於硫酸根的鍵結方式不同，造成它們三維結構不同。NH4[Ce(H2O)(C2O4)(SO4)]中，硫酸根是以μ3：η2：η1：η1的方式連結鈰離子，形成一維的無機鍊。鍊與鍊之間藉著沿[001]與[01-1]方向的草酸根相連進而形成三維的結構。化合物3的硫酸酸根硫酸根是以μ3：η2：η1：η1的方式連結釹離子，形成二維的網狀結構，再由草酸根連結各層，形成三維的骨架。其中化合物4和5為等結構。在化合物4和5中，硫酸根是以μ3：η1：η1：η1的方式連結金屬離子，形成二維的層狀結構。再以草酸根連結各層，形成三維的骨架。化合物3和5的磁性測量顯示，這二個化合物的mT值隨溫度下降而降低，且值皆為負值，由此推測，這二個化合物可能具有微弱的逆磁性。

Five new lanthanide coordination polymers have been prepared under the mild solvothermal conditions. In [Nd2(H2O)4(C2O4)(C4H4O4)2]•4H2O (1), the succinates are assembled with the Nd3+ ions to form layers, which layers are then pillared by the oxalates yielding a porous framework, possessing open channels along the multiple-directions. The dehydrated phase of “Nd2(C2O4)(C4H4O4)2” sill sustains and which framework presents flexibility upon the reversible adsorption of water molecules. In [Na2(H2O)2Nd2(C2O4)3(C4H4O4)]•2H2O (2), the formation of honeycomb-like layer is facilitated by two in-plane oxalates where the presence of dimeric neodymium units are bridged through the succinates. The third out-of-plane oxalate pillars the layer into a new open framework.
The other three compounds adopt the general chemical stoichiometry of NH4[Ln(H2O)(C2O4)(SO4)] (Ln = Nd for 3, Eu for 4 and Gd for 5), which all crystallize in three-dimensional frameworks. The SO42- ligands apply the various connective fashions of μ3：η2：η1：η1 for 3, μ3：η1：η1：η1 for 4 and 5, and μ3：η2：η1：η1 for the Ce analogue prepared in the previous work and direct the various architectures formed in these frameworks.

[1]Susumu Kitagawa, Ryo Kitaura, Shin-ichiro Noro, Angew.Chem. Int. Ed. 2004, 43, 2334
[2]Koichi Mikami, Masahiro Terada, Hiroshi Matsuzawa, Angew. Chem. Int. Ed. 2002, 41, 3554
[3]Jared M. Taylor, Amir H. Mahmoudkhani, George K. H. Shimizu, Angew. Chem. Int. Ed. 2007, 46, 795
[4]Banglin Chen, M. Eddaoudi, T. M. Reineke, J. W. Kampf, M. O'Keeffe, O. M. Yaghi, J. Am. Chem. Soc. 2000, 122, 11559
[5]Mohamed Eddaoudi, Jaheon Kim, Nathaniel Rosi,David Vodak, Joseph Wachter, M. O'Keeffe, O. M. Yaghi, Science 2002, 295, 469
[6]De-Liang Long, Alexander J. Blake, Neil R. Champness, Claire Wilson, Martin Schröder, Angew. Chem. Int. Ed. 2001, 40, 2443
[7]De-Liang Long, Alexander J. Blake, Neil R. Champness, Martin Schröder, Chem. Commun.2000, 1369
[8]Sujit K., Ghosh, Parimal K. Bharadwaj, Inorg. Chem. 2004, 43, 2293
[9]Suzy Surblé, Christian Serre., Franck Millange, G. Férey, Solid State Sci. 2006, 8, 413
[10]Fabien Serpaggi, G. Férey, J. Mol. Strct. 2003, 656, 201
[11]Tapas Kumar Maji, Golam Mostafa, Ho-Chol Changa, Susumu Kitaga-
wa, Chem. Commun. 2005, 2436
[12]Long Pan, Xiaoying Huang, Jing Li, Yonggang Wu, Nengwu Zheng, Angew. Chem. Int. Ed. 2000, 39, 527
[13]Rong Cao, Daofeng Sun, Yucang Liang, Maochun Hong, Kazuyuki Tatsumi, Qian Shi, Inorg. Chem. 2002, 41, 2087
[14]Xiaodan Guo, Guangshan Zhu, Zhongyue Li, Fuxing Sun, Zhenghong Yang, Shilun Qiu, Chem. Commun. 2006, 3172
[15]Theresa M. Reineke, Mohamed Eddaoudi, Michael Fehr, Douglas Kelley, O. M. Yaghi, J. Am. Chem. Soc. 1999, 121, 1651
[16]M. Bednarski, S. Danishefsky, J. Am. Chem. Soc. 1983, 105, 3716
[17]Jean-Pierre Costes, Juan Modesto Clemente-Juan,Francoise Dahan, Franck Nicodème, and Marc Verelst, Angew. Chem. 2002, 114, 333
[18]Subal Chandra Manna, Ennio Zangrando, Alessandro Bencini, Cristiano Benelli,Nirmalendu Ray Chaudhuri, Inorg. Chem. 2006, 45, 9114
[19]J.C. Trombe, J. Jaud, J. Chem. Crystallogr. 2003, 33, 19
[20]J.C. Trombe, Jean Galy, Renée Enjalbert, Acta Cryst. 2002, C58, m517
[21]S. Romero, A. Mosset, J. C. Trombe, J. Solid State Chem. 1996, 127, 256
[22]R. Vaidhyanathan, Srinivasan Natarajan, C. N. R. Rao, Chem. Mater. 2001, 13, 185
[23]R. Vaidhyanathan, Srinivasan Natarajan, C. N. R. Rao, Inorg. Chem. 2002, 41, 4496
[24]Yan-Qiong Sun, Jie Zhanga and Guo-Yu Yang, Chem. Commun. 2006, 1947
[25]Ding-Xian Jia, Yong Zhang, Jie Dai, Qin-Yu Zhu, Wen Lu, Wen-Juan Guo, Inorg, Chem. Commun. 2005, 8, 588
[26]Yan-Ping Yuan, Jun-Ling Song, Jiang-Gao Mao, Inorg, Chem.Commun. 2004, 7, 24
[27](a) G. M. Sheldrick, SHELXL-97, Program for the Solution of Crystal Structure, University of Göttingen, Germany, 1997
(b) G. M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997
[28]Meenakshi Dan, G. Cottereau, C.N.R. Rao, Solid State Sci. 2005, 7, 437
[29]簡伯任，三價鈰配位聚合物的合成、結構、熱分析及磁性，民國九十六年一月
[30]Zheng He, En-Qing Gao, Zhe-Ming Wang, Chun-Hua Yan, Mohamedally Kurmoo, Inorg. Chem. 2005, 44, 862
[31]Laura Cañadillas-Delgado, Jorge Pasández-Molina, Oscar Fabelo, Maria Hernádez-Molina, Francesc Lloret, Miguel Julve, Catalina Ruiz-Pérez, Inorg. Chem.2006, 45, 10585