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研究生: 楊文瑞
Yang, Wen-Ruei
論文名稱: Nd(Zn1/2Ti1/2)O3介電陶瓷之微波特性及其應用
Microwave Dielectric Properties and Applications of Nd(Zn1/2Ti1/2)O3 Ceramics
指導教授: 黃正亮
Huang, Cheng-Liang
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年: 2007
畢業學年度: 95
語文別: 中文
論文頁數: 97
中文關鍵詞: 微波陶瓷
外文關鍵詞: microwave, ceramic
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  • 在本論文中將探討 Nd(Zn1/2Ti1/2)O3 陶瓷系統的微波介電特性及材料的微結構。由實驗結果顯示,Nd(Zn1/2Ti1/2)O3在1330℃燒結4小時,可得最佳之介電特性εr~31.55,Q׃~170000(at 8.55GHz),τƒ~-42 ppm/oC。由於τƒ為負值,我們選擇添加 CaTiO3(+850 ppm/oC) 及 SrTiO3(+1100 ppm/oC)調整其τƒ。再者,添加CuO使其燒結溫度降低到1270℃~1300℃。
    此外,本論文還分別以FR4、Al2O3及Nd(Zn1/2Ti1/2)O3作為基板來設計一緊密微帶線帶通濾波器,濾波器的規格為:中心頻率 2GHz、頻寬約5%,並使用電磁模擬軟體HFSS 來進行電腦模擬。

    The microwave dielectric properties and the microstructures of the series of Nd(Zn1/2Ti1/2)O3 ceramics system were investigated. The experiment results show that
    Nd(Zn1/2Ti1/2)O3 has the best properties with sintering temperature at 1330℃, the dielectric properties are εr ~ 31.55 , Q×f ~ 170000(at 8.55 GHz) , τƒ ~ -42 ppm/oC. Concerning about the negative value of τƒ, we choose adding the CaTiO3 (+850 ppm/oC) and SrTiO3 (+1100 ppm/oC) to adjust the value. The CuO additives lowered the sintering temperature of NZT ceramics to the range 1270℃~1300℃.
    Besides, a compact microstrip bandpass filter on FR4、Al2O3 and Nd(Zn1/2Ti1/2)O3 substrates have been design. The band-pass frequency is 2GHz, the bandwidth is 5% and simulated by electromagnetic simulation software, HFSS.

    第一章 緒論 …………………………………………………… 1 1-1 前言 ………………………………………………………… 1 1-2 研究目的 …………………………………………………… 1 第二章 介電材料原理 ………………………………………… 2 2-1微波介電材料的原理 ……………………………………… 2 2-2介電共振器(Dielectric Resonator, DR)原理 ………… 8 2-3鈣鈦礦之結構 ……………………………………………… 13 2-4 燒結原理 …………………………………………………… 13 2-4-1燒結的種類 ……………………………………………… 13 2-4-2液相燒結理論 …………………………………………… 15 2-4-3陶瓷體燒結的三過程 …………………………………… 16 第三章 微帶線及濾波器之原理 ……………………………… 18 3-1濾波器的簡介 ……………………………………………… 18 3-2 微帶線原理 ………………………………………………… 21 3-2-1 微帶傳輸線介紹 ………………………………………… 21 3-2-2 微帶線傳輸組態 ………………………………………… 21 3-2-3微帶線各項參數公式計算及考量 ……………………… 22 3-3 微帶線諧振器種類 ………………………………………… 28 3-4 四分之一波長的阻抗轉換器與開路殘段(open stub) … 31 3-5 以四分之一波長開路殘段產生傳輸零點 ………………… 32 3-6使用四分之一波長開路殘段所製作的濾波器 …………… 33 3-7緊密微帶線帶通濾波器 …………………………………… 34 第四章 實驗程序與量測方法 ………………………………… 36 4-1 微波介電材料的製備流程圖 …………………………… 36 4-2 微波介電材料的特性分析與量測 ……………………… 40 4-2-1 X-Ray分析(XRD) ……………………………………… 40 4-2-2 掃瞄式電子顯微鏡(SEM)分析 ………………………… 40 4-2-3 密度之量測 …………………………………………… 41 4-2-4 微波特性之量測 ……………………………………… 41 4-3  濾波器之製作與量測 ……………………………… 47 4-3-1 濾波器設計 …………………………………………… 47 4-3-2 濾波器實作 …………………………………………… 48 4-3-3 濾波器特性量測 ……………………………………… 48 第五章 實驗結果與討論 ……………………………………… 50 5-1 Nd(Zn1/2Ti1/2)O3之微波特性探討 …………………… 50 5-2 xNd(Zn1/2Ti1/2)O3-(1-x) CaTiO3之微波特性探討 … 60 5-3 xNd(Zn1/2Ti1/2)O3-(1-x) SrTiO3之微波特性探討 … 69 5-3 Nd(Zn1/2Ti1/2)O3添加CuO之微波特性探討 …………… 77 5-4 濾波器特性探討 ………………………………………… 84 5-4-1 FR4基板特性探討 ……………………………………… 84 5-4-2 Al2O3基板特性探討 …………………………………… 87 5-4-3 Nd(Zn1/2Ti1/2)O3基板特性探討 …………………… 89 第六章 結論與未來展望 ……………………………………… 93 參考文獻 ………………………………………………………… 94

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