本研究使用非平衡磁控濺鍍法披覆碳氮(CN)於氮化熱處理前後的Ti6Al4V及3D列印Ti6Al4V以及披覆含鈦類鑽碳 (Ti-C:H) 於氮化熱處理前後的3D列印Ti6Al4V。實驗中有十二種不同的下試件，Ti6Al4V系列中有六種，分別為 Ti6Al4V (T)、氣體氮化後的Ti6Al4V (NT)、將氣體氮化Ti6Al4V降低粗糙度至原材N-Ti6Al4Vs(NTs)與披覆碳氮於三者(CN-T、CN-NT、CN-NTs)；3D列印Ti6Al4V系列六種分別為3D列印Ti6Al4V(3DT)、經氣體氮化處理後的3D列印Ti6Al4V降低粗糙度至原材N-3D-Ti6Al4Vs(N3DTs)以及將前兩者披覆碳氮(CN)及含鈦類鑽碳(DLC)：CN-3DT、CN-N3DTs、DLC-3DT、DLC-N3DTs。分析所有試片之微結構、機械性質，並以往復式磨耗試驗機在0.9 wt.% NaCl溶液中進行磨耗試驗，使用316L球、Si3N4球與3D列印Ti6Al4V球(3DT)三種上試件，研究其磨潤性質與磨耗機構；電化學實驗分析評估各種試片之抗腐蝕能力；培養Raw264.7小鼠單核巨噬細胞於所有試片上，探討生物相容性。
表面氮化與被覆上CN、DLC膜能夠提升抗磨耗性質、抗腐蝕性與生物相容性。在Ti6Al4V系列中由CN-NTs擁有最佳抗磨耗性與抗腐蝕性。在3D列印Ti6Al4V系列中DLC-N-3D-Ti6Al4Vs擁有最佳抗磨耗性，披覆DLC膜表現優異抗腐蝕性，鍍上CN或DLC膜之試片皆表現出良好的生物相容性。

The nitriding treatment and CN, DLC doped Ti (Ti-C:H) coatings are used for the casting and 3D manufacturing Ti6Al4V alloy. The high temperature nitriding (900°C) was applied to casting and 3D manufacturing Ti6Al4V alloy. CN and DLC coatings were deposited amorphous carbon nitride (CN) and Ti-C:H (DLC) coating used by Closed Field Unbalanced Magnetron Sputtering (CFUMBS) on unnitrided samples and nitrided specimens. The microstructure, adhesion and hardness of the CN, DLC coatings are measured by using X-ray diffraction, scratch tester and nanoindenter, respectively. The wear tests were performed by SRV tester in 0.9% NaCl solution to simulate human body environment at load of 10N for 24 min as sliding 316L, Si3N4 and 3D-Ti6Al4V balls. The corrosion resistance of all specimens was evaluated by potentiodynamic polarization test. The Purified mouse leukemic monocyte macrophage cells (Raw 264.7) are seeded on the samples for 1 day, 3 day and 5 day to investigate the biocompatibility. The result shows the duplex surface treatment effectively improved the wear, corrosion resistance and biocompatibility.

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