本實驗用VLS方法成長了硫化鋅奈米線/奈米帶結構，奈米鋸齒狀(nanosaw)結構，奈米梳子狀結構(nanocomb)。奈米線和奈米帶都有WZ結構和ZB結構；而鋸齒狀奈米線則是由ZB結構的牙齒和WZ結構的枝幹組成；梳子狀奈米線則是單晶的WZ結構。鋸齒狀結構的生長與ZnS的極性面有關，而梳子狀結構則是由於生長環境中反應氣體的蝕刻作用。實驗同樣用VLS的方法合成了摻雜銅的硫化鋅奈米線，摻雜銅的奈米線的形貌隨著銅含量的增加逐漸從直的變成zigzag的形貌，這種改變推測與銅含量增加產生晶格扭曲有關。實驗還利用生長好的硫化鋅奈米線為模板，用離子交換法生長了ZnS/Cu2-xS core/shell結構，並且量測了其和單根硫化鋅奈米線的光感應性質，發現核殼結構除了提高了UV光的響應，對800nm波長的光也有一定響應。另外硫化鋅奈米鋸齒結構也有顯著提高的UV響應。

ZnS nanostructures with variety morphology such as nanobelts, nanowires, nanosaws and nanocombs have been synthesized via VLS growth mechanism. Structure characterization revealed that nanobelts and nanowires both have Cubic and Hexagonal phases. Nanosaw consists of cubic teeth and hexagonal trunk while the nanocombs have single crystalline Wurtzite (WZ) structure. The positive polar surface of WZ structure causes the second growth on its lateral surface. The nanocomb is transformed from the nanobelts, which is etched along the preferential crystallographic planes in a reactive atmosphere. Cu-doped ZnS nanowires have also been synthesized. The copper-doped nanowires have two morphologies, the straight and the zigzag shape. The copper atoms may cause the lattice distortion in ZnS nanowire and to compensate the energy difference, the nanowire may change growth direction and form the zigzag shape. Finally, we use the ZnS nanowires as template to synthesize the ZnS/Cu2-xS core/shell structures. We also measured the photo response of single ZnS nanowire and ZnS/Cu2-xS nanowire and found that ZnS/Cu2-xS nanowire has high responsivity to UV and 800 nm wavelength light. Moreover, ZnS nanosaw also has enhanced UV light responsivity.

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