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研究生：	張志揚 Chang, Chih-Yang
論文名稱：	鹼硼四氫化合物與聚-3-己基噻吩化學反應之研究 Study on The Chemical Reaction between Alkali Boron Tetra-hydrides and Poly(3-hexylthiophene)
指導教授：	溫添進 Wen, Ten-Chin
學位類別：	碩士 Master
系所名稱：	工學院 - 化學工程學系 Department of Chemical Engineering
論文出版年：	2011
畢業學年度：	99
語文別：	中文
論文頁數：	82
中文關鍵詞：	聚-3-己基噻吩、化學反應
外文關鍵詞：	Poly(3-hexylthiophene), Chemical reaction
相關次數：	點閱：51 下載：0
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本論文的研究主要是探討鹼硼四氫化合物與聚-3己基噻吩之化學反應。
此篇論文中，我們發現鹼硼四氫化合物應用於高分子異質接面太陽能電池中能提升效率，因而組裝聚-3己基噻吩的單載子元件，並將鹼硼四氫化合物作為電子注入層，由實驗結果發現其能使電流有大量增加的現象，是來自於聚-3己基噻吩與鹼硼四氫化合物界面反應所致，反應能降低聚-3己基噻吩表面的功函數，藉由紅外線光譜儀的分析去確認反應的發生並推斷反應發生的可能途徑，並且發現反應會使得聚-3己基噻吩斷鍵，造成分子量下降。

In this dissertation, we investigate into the chemical reaction between alkali boron tetra-hydrides and poly(3-hexylthiophene).
In this part, we found that alkali boron tetra-hydrides applied in polymer bulk hetero-junction solar cells can improve efficiency. Thus we fabricated the single carrier device using poly(3-hexylthiophene) as active layer and alkali boron tetra-hydrides as electron injection layer. The experimental results showed a significant increase in electron only device due to the interfacial reaction between poly(3-hexylthiophene) and alkali boron tetra-hydrides. The reaction can reduce the surface work function of poly(3-hexylthiophene). By infrared spectroscopy analysis, we would identify the reaction occurred and conjecture the possible reaction mechanism and found that reaction would make poly(3-hexylthiophene) broken bonds, resulting in decreased molecular weight.

第一章 序論 ..................................... 1
1-1 前言 .................................................... 1
1-2 共輒高分子 .............................................. 3
1-2-1 共輒高分子的起源 ...................................... 3
1-2-2 共輒高分子的分類 ...................................... 3
1-2-3 導電機制 .............................................. 5
1-2-4 共輒高分子的應用 ...................................... 7
1-2-5 聚3-烷基噻吩之簡介[28] ................................ 11
1-3 高分子太陽能池電池 ..................................... 12
1-3-1 太陽光能與再生性能源的必要性 ......................... 12
1-3-2 有機太陽能電池分類 ................................... 13
1-4 紅外線光議儀的結構與工作原理 ........................... 16
1-4-1 紅外線光議儀的簡介 ................................... 16
1-4-2 分子的偶極矩變化 ..................................... 16
1-4-3 分子的振動與轉動 ..................................... 16
1-4-4 傅立葉紅外光光譜儀(Fourier Transform Infrared Spectrometry, FTIR) ........................................ 18
1-4-5 紅外光光譜儀的系統結構 ............................... 20
1-4-5-1 結構簡介 ........................................ 20
1-4-5-2 麥克森干涉儀 ..................................... 20
1-4-5-3 樣品載臺.......................................... 21
Attenuated total reflection infrared spectroscopy, ATR-IR 21
1-4-5-4 偵測器：焦電感測器 ............................... 21
1-4-5-5 偵測器：光導感測器 ............................... 21
1-5 研究動機 ............................................... 23
第二章 鹼硼四氫化合物與聚-3-己基噻吩化學反應之研究
................................................ 37
2-1 前言 ................................................... 37
2-2 實驗部分 ............................................... 38
2-2-1 實驗藥品 ............................................. 38
2-2-2 太陽能電池元件之組裝與量測 ........................... 39
2-2-2-1 太陽能電池元件組裝 ............................... 39
2-2-2-2 太陽能電池元件量測 ............................... 41
2-2-3 單載子元件之樣品製備與量測 ........................... 42
2-2-4 紫外光電子光譜之量測 ................................. 43
2-2-5 衰減全反射紅外線吸收光譜議之樣品製備與量測 ........... 43
2-2-5-1 衰減全反射紅外線光譜儀樣品製備 ................... 43
2-2-5-2 衰減全反射紅外線光譜儀量測 ....................... 44
2-2-6 鹼硼四氫化合物修飾聚-3-己基噻吩之膠體滲透色譜分析 .... 44
2-3 結果與討論 ............................................. 45
2-3-1 太陽能電池元件分析 ................................... 45
2-3-2 鹼硼四氫化合物修飾聚-3-己基噻吩之electron-only元件分析 46
2-3-3 紫外光電子圖譜結果分析 ............................... 47
2-3-4 鹼硼四氫化合物與聚-3-己基噻吩化學反應分析 ............ 48
2-3-4-1 鹼硼四氫化合物與聚-3-己基噻吩之界面反應 .......... 48
2-3-4-2 鹼硼四氫化合物與聚-3-己基噻吩之混合反應 .......... 50
2-3-5 鹼硼四氫化合物修飾聚-3-己基噻吩之分子量分析 .......... 53
2-4 結論 ................................................... 55
第三章 總結與建議 ............................... 76
3-1 總結 ..................................................... 76
3-2 未來工作建議 ............................................. 77
參考文獻.............................................78
自述 ............................................ 82
                                    

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