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研究生：	蘇忠瑞 Su, Chung-Jui
論文名稱：	於氯化鋁-三甲基氯化銨離子液體中電沉積金屬奈米鋁線 Electrodeposition of aluminum nanowires from aluminum chloride trimethylamine hydrochloride ionic liquids
指導教授：	孫亦文 Sun, I-Wen
學位類別：	博士 Doctor
系所名稱：	理學院 - 化學系 Department of Chemistry
論文出版年：	2015
畢業學年度：	103
語文別：	英文
論文頁數：	90
中文關鍵詞：	奈米鋁線、電化學、離子液體
外文關鍵詞：	aluminum nanowire, electrochemistry, ionic liquid
相關次數：	點閱：54 下載：0
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本研究使用酸性的氯化鋁/三甲基氯化銨離子液體應用於電化學研究和探討上。目前為止此離子液體並未被使用於電化學研究上，而其具備的高黏度特質也使得在電沉積鋁實驗中不需使用任何模板和添加劑便可製備奈米鋁線和具節狀奈米鋁線。研究中使用三種不同氯化鋁/三甲基氯化銨比例之離子液體 (62：38、60：40和58：42)並搭配定電位法、定電流法和定電位脈衝法分別製備及探討奈米鋁線的形成，並從中推測其成長機制和控制條件，在奈米鋁線部分發現可利用電位選擇來調控奈米鋁線之粗細；在定電流法電鍍中得到不同震盪頻率和震幅之時間對電位圖，此結果也影響到具節狀奈米鋁線之形貌；最後在定電位脈衝法下成功的以控制脈衝時間和電位來調控節狀奈米鋁線的寬度和週期。所製備之奈米鋁線均以掃描式電子顯微鏡、穿透式電子顯微鏡、X光繞射儀進行表面形貌和晶體結構上的鑑定。

The electrochemical fabriccation of Al nanowires by electrodeposition without the use of template and additives is studied in the Lewis acidic aluminum chloride-trimethylamine hydrochloride (AlCl3-TMHC) ionic liquids containing various AlCl3-TMHC mol ratios of 62:38, 60:40 and 58:42. The deposition was performed using constant potential, pulse potential and constant current electrolysis methods, respectively.
For constant potential electrolysis, the diameter of Al nanowires can be varied by deposition potential. For constant current electrolysis, potential oscillation occurs during the electrolysis, the frequency and amplitude of the potential oscillation varies with the applied current. Such potential oscillation is associated with the formation of segment Al nanowires. Segment Al nanowires can also be prepared by pulse potential electrolysis, the width and period of the Al segment can be controlled by pulse-time and pulse-potential. All the electrodeposited Al samples are characterized by scanning electron microscopy, transmission electron microscopy and X-ray diffraction

Abstract	                                        III
Abstract (in Chinese)	                                 IV
Acknowlegment	                                          V
Chapter I. Introduction	                                  1
 1.1 Introduction of ionic liquids	                  1
 1.2 The history and development of ionic liquids	  7
 1.3 Introduction and application of chloroaluminate based   ionic liquids	                                          11
Chapter II. Experimental	                          16
 2.1 Reagents and materials	                          16
 2.2 Instruments	                                  17
 2.3 Experimental methods	                          20
Chapter III. Results and Discussions	                  22
 3.1 Electrodeposition of aluminum nanowires by chronoamperometry and electrochemical study in AlCl3/TMHC ILs	                                                  22
   3.1.1 Cyclic voltammetry study in AlCl3/TMHC ionic liquids	                                                  22
   3.1.2 Electrodeposition of aluminum in 60:40 mol ratio of AlCl3/ TMHC IL on tungsten substrate	                  29
   3.1.3 Electrodeposition of aluminum in 62:38 mol ratio of AlCl3/TMHC on tungsten substrate	                  36
   3.1.4 Electrodeposition of aluminum in 58:42 mol ratio of AlCl3/TMHC on tungsten substrate	                  39
   3.1.5 Electrodeposition of aluminum on different substrates	                                          44
   3.1.6 Identified of aluminum nanowires by XRD/TEM and summary	                                                  50
 3.2  Electrodeposition of periodically aluminum nanowires by constant current electrolysis	                  52
 3.3  Electrodeposition of periodically aluminum nanowires by pulse potential deposition	                          59
   3.3.1 Pulse potential deposition with symmetric pulse period at room temperature	                          59
   3.3.2 Pulse potential deposition with symmetric time at high temperature	                                  64
   3.3.3 Pulse potential deposition with asymmetric pulse periods at room temperature	                          74
Chapter IV. Conclusions	                                  84
Reference	                                          85

                                    

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校內：2020-09-01公開
校外：2025-01-01公開

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