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| 研究生： |
楊曉函 Yang, Siao-Han |
|---|---|
| 論文名稱： |
主族金屬硫族化合物之合成、結構與物理性質探討 Syntheses,Structures and Physical Properties of Main-Group Metal Chalcogenides |
| 指導教授： |
許桂芳
Hsu, Kuei-Fang |
| 學位類別： |
碩士 Master |
| 系所名稱： |
理學院 - 化學系 Department of Chemistry |
| 論文出版年： | 2012 |
| 畢業學年度： | 100 |
| 語文別： | 中文 |
| 論文頁數： | 83 |
| 中文關鍵詞： | 助熔劑長晶法 、非線性光學 |
| 外文關鍵詞： | solid state, SHG |
| 相關次數： | 點閱：55 下載：0 |
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本論文利用助熔劑長晶法，成功合成出四個新穎的硫族光學非線性化合物，我們藉由能量散佈光譜(EDS)初步計算晶體成分比例、單晶X光繞射(XRD)量測晶體結構、粉末X光繞射(PXRD)確認純相製備、拉曼散射光譜(Raman)量測晶體振動型態、傅立葉紅外線光譜(FTIR)量測晶體可穿透範圍、紫外光可見光光譜(UV-visible)量測晶體能隙、粉末二倍頻(PSHG)量測晶體非線性係數。
Four new compounds have been synthesized through solid state reactions using a KBr and CsI flux to promote crystal growth.
The compounds have nonlinear optical potential because of non-centrosymmetric structures. The absorbing wavelengths are in the range of UV-Vis, and they have good transmission in the range of IR.We Examine the SHG signals , and found they have good nonlinear optical property.
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