本研究以溶膠-凝膠法成功製成鋁矽基質膠囊，將其應用於吸附核廠冷卻水中核種元素—Sr離子。本研究探討鋁矽系統中Al離子配位數、Na離子摻雜量及比表面積變化，對Sr離子吸附效率的影響。由NMR、EDXS、BET及批次吸附試驗結果得知，當結構中Al離子產生六配位數、陽離子摻雜量高皆有助於核種離子與膠囊材料進行離子交換，進而提高陽離子交換效率。
本研究第二部份則是將對Cs離子具有高吸附特性的天然絲光沸石，以吸附效率最高的膠囊(N1A1S1)包覆製成礦物膠囊。經吸附試驗結果與性質分析後，Sr離子吸附效率隨著礦物包覆量增加而降低，而Cs離子吸附效果則不受膠囊包覆影響。並將樣品進行Sr、Cs離子的離子競爭吸附試驗，在離子競爭下，N1A1S1膠囊對Sr離子的吸附效果可達95.8 mg/g，而若以同時去除Cs與Sr離子為目標，礦物膠囊N1A1S1_50樣品可作為雙離子吸附劑，其對Sr與Cs之吸附量分別可達68.9 mg/g與150.1 mg/g。吸附完成的礦物膠囊廢料，經高溫處理，得一無孔隙且具鍶鈉長石晶相結構之產物，有效達到離子封存之效果。

This study is devoted to developing a new type of encapsulating material applied for the decontamination of Sr2+ and Cs+ ions. Sodium aluminosilicate (NAS) xerogel was prepared via sol–gel process and will serve as encapsulating material to enclose natural mordenite powders. The as-obtained NAS xerogel exhibits slit-like shaped pores and a specific surface area of 46.3 m2/g. The batch experimental results show that NAS xerogel having adsorption effect for both Sr2+ and Cs+ ions and the uptake efficiency reached 72.7 mg/g and 117.4 mg/g, respectively. In the binary ionic environment, the uptake efficiency further increases to 95.8 mg/g and 126.3 mg/g for Sr2+ and Cs+ ions respectively.
In the second part of this study, NAS xerogel was used to enclose 50 wt.% of natural mordenite powders (NAS_50). Batch experimental results show that the overall specific surface area increased from 46.3 m2/g to 103.0 m2/g due to the highly porous feature of mordenite. The mordenite capsule showed that the overall uptake efficiency for Sr2+ ions slightly decreased from 72.7 mg/g down to 47.2 mg/g because of the low selective adsorption capability to Sr2+ of mordenite. Nevertheless, the coexistence of Sr2+ and Cs+ in solution still allows increasing the adsorption capacity up to 68.9 mg/g and 150.1mg/g for Sr2+ and Cs+, respectively.
Finally, NAS xerogel was again heat-treated up to 1300°С for 2 hours to carry out the ionic immobilization. The adsorbed Sr2+ ion was immobilized in NAS structure by forming Sr-feldspar phase.

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