| 研究生: |
黃信貿 Huang, Xin-Mao |
|---|---|
| 論文名稱: |
(Fe,Co,Cr)/Pt多層膜之磁性質研究 Study of the Magnetic Properties of (Fe,Co,Cr)/Pt Multilayers |
| 指導教授: |
張炎輝
Chang, Yen-Hwei |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 材料科學及工程學系 Department of Materials Science and Engineering |
| 論文出版年: | 2004 |
| 畢業學年度: | 92 |
| 語文別: | 中文 |
| 論文頁數: | 88 |
| 中文關鍵詞: | 磁性 、多層膜 、離子束濺鍍 、鈷鉻 |
| 外文關鍵詞: | magnetic, multilayer, ion beam sputter, Co-Cr |
| 相關次數: | 點閱:53 下載:1 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本研究以不同比例的Co、Cr熔製成磁性層靶材,與純白金非磁性層靶材,利用離子束濺鍍機,將磁性層與非磁性層交互濺鍍在矽基板上,改變製程條件如改變鍍膜層數,鍍膜厚度,添加Under-layer與熱處理等,製備出各種不同條件之磁性多層膜。
利用EDS,AES等分析薄膜元素組成,以XRD作結構分析,SEM、TEM觀察微結構,AFM觀察表面起伏狀態,SQUID,MOKE作磁性質的量測。
實驗結果顯示,以離子束濺鍍之薄膜,晶粒大小約只有7~8nm,然而添加Under-layer與熱處理有助於晶粒成長。未添加Under-layer薄膜之最佳矯頑磁力為靶材Cr15之濺鍍30層30秒(每層15.9A)的Hc = 84.8Oe,經熱處理可使矯頑磁力增加為111Oe。而添加Pt Under-layer後出現之最佳矯頑磁力為靶材Cr20之濺鍍30層30秒(每層16.5A)的Hc = 111.8Oe,經熱處理後可使矯頑磁力增加為157.9Oe。
Different composition of Co-Cr alloy targets were prepared as magnetic layer target, and pure Pt is prepared as spacer layer target. The magnetic layer and spacer layer was coated alternately on Si substrate by Ion Beam sputter. The experimental conditions such as the number of layers, the thickness of each layer, under-layer and heat treatment were the variables in this study.
The ratio of elements in the samples is measured by EDS and AES. The structure is analyzed by XRD. SEM and TEM observe the surface morphology and microstructure. The surface roughness of magnetic films was measured by AFM. The magnetic properties of magnetic films were determined by SQUID and MOKE.
The experimental results show that the grain sizes of the film are only 7~8nm, but the additive of under-layer and heat treatment will increase the grain sizes. The best coercivity of non-under-layer film is 84.8Oe for Cr1530s30L, and heat treatment will increase the coercivity to 111Oe. And the best coercivity of Under-layered film is 111.8Oe for PtCr2030s30L, heat treatment will increase the coercivity to 157.9Oe.
1. T.P. Nolan, Y. Hirayama, M. Futamoto, ”Improvement of Co71Cr19Pt10/Ti90Cr10 perpendicular recording media by independent optimization of film nucleation and growth processes”, J. Appl. Phys. 79(1996) 5359.
2. I.S. Lee, H. Ryu, H.J. Lee, T.D. Lee, “Role of a paramagnetic amorphous CoZr seed layer in CoCrPt/Ti perpendicular recording media”, J. Appl. Phys. 85(1999) 6133.
3. H. Gong, M. Rao, D.E. Laughlin, D.N. Lambeth, “Highly oriented perpendicular Co-alloy media on Si(111) substrates”, J. Appl.Phys. 85 (1999) 4699
4. S.Iwasaki & H.Yamazaki, Proc 7 the Ann Conf. On Magnetism ,4PA-7(1975)
5. 金重勳,郭博成,郭志明,磁性技術手冊,台灣磁性技術協會(2000),191-197
6. J.C.Lodder, “Magnetic structures in Co-Cr media for perpendicular magnetic recording”, J.Magn.Magn.Mater.,159(1996)238-248
7. Shun-ichi Iwasaki, “Discoveries that guided the beginning of perpendicular magnetic recording”, J.Magn.Magn.Mater. , 235(2001)227-234
8. P.-L. Lu and S. H. Charap, IEEE Trans. Magn. MAG-30, (1994) p.4230
9. K. H. J. Buschow, Gary J. Long and Fernande Grandjean, “High Density Digital Recording”(1992), p 161
10. Y. Hoshi, M. Naoe, “Changes in Structure and Magnetic Properties of Co-Cr Films by Oblique Incident of Sputtered Particles”, IEEE Transaction on Magnetics, Vol 24, NO. 6, November 1988, p3015-3017
11. Masayuki Sagoi and Teisuo Inoue, “Effect of third-element additions on properties of Co-Cr-based films”, J. Appl. Phys. 67 (10), 15 May 1990, p5394-5398
12. K. Hono, B. Wong, and D.E. Laughlin, “Crystallography of Co--Cr bilayer magnetic thin films”, J. Appl. Phys. 68 (9), 1 November 1990, p4734-4740
13. K. Hono, Y. Maeda, S. S. Babu, and T. Sakurai, “Compositional inhomogeneities in sputtered Co-Cr magnetic thin films studied by atom probe field ion microscopy”, J. Appl. Phys. 76 (12), 15 December 1994, p8025-8031
14. Li Cheng-Zhang, J. C. Lodder, J. A. Szpunar, “The Development of Texture in Co-Cr Films”, IEEE Transaction on Magnetics, Vol 30, NO. 4, July 1994, p1373-1379
15. David J. Rogers, Yasushi Maeda, and Koji Takei, “Compositional Separation in Co-Cr Based Thin Film Magnetic Recording Media”, Scripta Metallurgica of Materialia, Vol 33, NO.10/11, 1995, pp1553-1561
16. Kannan M. Krishnana, “Enhanced saturation magnetization, electronic structure, and compositional segregation in epitaxially grown Co–Cr thin films”, Appl. Phys. Lett. 67 (15), 9 October 1995, p2238-2240
17. Y. Ikeda, Y. Sonobe, H. Uchida, T. Toyooka, “Characterization of a Thick Co-Cr Perpendicular Medium for a Merged MR Head”, Journal of Magnetism and Magnetic Materials 176, 1997, p13-19
18. Shigeki Nakagawa, and Masahiko Naoe, “Control of nano-structure of the initial growth layers of Co-Cr thin films deposited by facing targets sputtering”, Vacuum, Vol 51, NO. 4, 1998, p 595-599
19. Y. Hirayama, K. Ito, Y. Honda, N. Inaba, M. Futamoto, “Thermal stability of CoCr-alloy perpendicular magnetic”, Journal of Magnetism and Magnetic Materials 193, 1999, p253–257
20. Nobuyuki Inaba, Yasutaro Uesaka, and Masaaki Futamoto, “Compositional and Temperature Dependence of Basic Magnetic Properties of CoCr-Alloy Thin Films”, IEEE Transaction on Magnetics, Vol 36, NO. 1, January 2000, p54-60
21. G.W. Qina, K. Oikawaa, T. Ikeshojia, R. Kainumab, K. Ishida, “Magnetically induced phase separation in the Co-Cr binary system”, Journal of Magnetism and Magnetic Materials 234, 2001, L1-L5
22. M. Sagoi and T. Inoue, “Effect of third-element additions of Co-Cr- based films ”, J. Appl. Phys. vol. 67, no.10, 15 May (1990) , p6394-6398
23. K. Oikawa, G. W. Qin, O. Kitakami, Y. Shimada, K. Fukamichi, and K. Ishida, “Prediction of effectively elements for magnetically induced phase separation in Co-Cr-based magnetic recording media”, J. Appl. Phys., vol.79, no.5, 30 July(2001) , p 644-646
24. K. M. Kemner, V. G. Harris, V. Chakarian, Y. U. Idzerda, W. T. Elam, C. C. Kao, Y. C. Feng, D. E. Laughlin, and J. C. Woicik, “The role of Ta and Pt in segregation within Co-Cr-Ta and Co-Cr-Pt thin film magnetic recording media”, J. Appl. Phys., vol. 79, no.8, 12 April(1996) , p 5345-5347
25. Y. Sonobe, Y. Ikeda, H. Uchida, and T. Toyooka, ”Ti underlayer effect on the recording characteristics of Co-Cr perpendicular media with weak and strong interparticle interactions”, J. Appl. Phys., vol.81, no.8, 15 April,(1997) , p 4667-4669
26. O. Kitakami, Y. Ogawa, H. Fujiwara, F. Kugiya, and M. Suzuki, “Influence os Initial Growth Layer and Ti Underlayer on Magnetic Properties and Recording Characteristics of Very Thin Films of Evaporated Co-Cr Media”, IEEE Trans. Magn., vol 25, no.3, May(1999) , p 2607-2611
27. T. Onoue, T. Asahi, K. Kuramochi, J. Kawaji, T. Homma, and T. Osaka, “CoCrPtTa and Co/Pd Perpendicular Magnetic Recording Media with Amorphous Underlayers”, IEEE Trans. Magn., vol.37, no.4, July(2001) , p 1592-1594
28. A. Sato, S. Nakagawa, and M. Naoe, “Co-Cr-Ta Perpendicular Magnetic Recording Media Using Pt Seed Layer”, IEEE Trans. Magn., vol. 36, no. 5, , Sept.(2000) p 2387-2389
29. D. J. Rogers, J. N. Chapman, J. P. C. Bernards, and S. B. Luitjens, “Determination of local composition in Co-Cr films deposited at different substrate temperatures”, IEEE Trans. Magn., Sept.(1989) , p 4180-4182
30. Y. Uchiyama, H. Sato, and Y. Kitamoto, “Effect of substrate temperature on magnetic and microstructural properties of sputtered Co-Cr films with perpendicular magnetic anisotropy”, IEEE Tran. Magn., vol. 28, no.5, Sep(1992) , p 2010-2017
31. P. W. Jang, T. D. Lee, Y. H. Kim, and T. Kang, “Heat treatment effects of CoCr sputtered films”, IEEE Tran. Magn., vol. 26, no.5, Sep(1990) , p 1623-1625
32. N. Inaba, Y. Uesaka, and M. Futamoto, “Compositional and temperature dependence of basic magnetic properties of CoCr-alloy thin films”, IEEE Tans. Magn., vol. 36, no. 1, Jan.(2000) , p 54-59
33. A. Fartash, and H. Oesterreicher, “Magnetic properties of Co-Cr films and the effects of heat treatment”, J. Appl. Phys., vol. 66, no.7, 1 Oct.(1989) , p 3275-3281
34. M. Sato, Y. Onishi, and A. Nakaue, “Co-based alloy media with a high coercivity prepared by heat treatment after sputtering”, IEEE Tran. Magn., vol.29, no.6, Nov.(1993) , p 3685-3687
35. K. H. J. Buschow, Gary J. Long and Fernande Grandjean, “High Density Digital Recording” (1992) , p 340, p 463
36. Masud Mansuripur, “The Physical Principles of Magneto-Optical Recording” (1995) , p433-436
37. S. V. Vonsovskii, “Magnetism”, Keter Publishing House, Jerusalem (1974)
38. S. Gasiorowics, “Quantum Physics”, Wiley, New York (1974)
39. W. B. Zeper, H. W. van Kesteren, B. A. J. Jacobs, J. H. M. Spruit, and P. F. Carcia, J. Appl. Phys. 70 (1991) , p2264
40. C. J. Lin and H. V. Do, IEEE Trans. Magn., MAG-26, 1700 (1990)
41. F. J. A. den Broeder, D. Kuiper, A. P. van de Mosselaer, and W. Hoving, Phys. Rev. Lett. 60 (1988) , p2769
42. C. H. Lee, Hui He, F. Lamelas, W. Vavara, C. Uher and Roy Clarke, Phys. Rev. Lett.62 (1989) , p653
43. S. Araki, T. Takahata, and T. Shinjo, J. Magn. Soc. Of Japan, 13 (1989) , p339
44. J. Ferre, G. Penissard, C. Marliere, D. Renard, P. Beauvillain, and J. P. Renard, 56 (1990) , p1588
45. C. J. Lin, G. L. Gorman, C. H. Lee, R. F. C. Farrow, E. E. Marinero, H. V. Do, H. Notarys, J. Magn. Magn. Mater. 93 (1991) , p194
46. C. H. Lee, R. F. C. Farrow, C. J. Lin, E. E. Marinero, and C. J. Chien, Phys. Rev. B-42 (1990) , p11384
47. Donald L. Smith, “Thin Film Depositopn”, McGraw-Hill, Inc (1995) , p119
48. Donald L. Smith, “Thin Film Depositopn”, McGraw-Hill, Inc (1995) , p119
49. 莊達人,“VLSI製造技術”,高立圖書有限公司 (1999),p545
50. 林瑞陽,“真空濺鍍及其工業應用”,台大慶齡工業中心演講, 第四章 (1995)
51. John A. Thormton, “Influence of Apparatus Geometry and Deposition Conditions on the Structure and Topography of Thick Sputtered Coatings”, Journal of Vacuum Science Technology, Vol.11, No.4 (1974) , p666
52. John A. Thormton, “Influence of Substrate Temperature and Deposition Rate on Structure of Thick Sputtered Cu Coatings”, Journal of Vacuum Science Technology, Vol.12, No.4 (1975) , p830