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研究生: 黃信貿
Huang, Xin-Mao
論文名稱: (Fe,Co,Cr)/Pt多層膜之磁性質研究
Study of the Magnetic Properties of (Fe,Co,Cr)/Pt Multilayers
指導教授: 張炎輝
Chang, Yen-Hwei
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2004
畢業學年度: 92
語文別: 中文
論文頁數: 88
中文關鍵詞: 磁性多層膜離子束濺鍍鈷鉻
外文關鍵詞: magnetic, multilayer, ion beam sputter, Co-Cr
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  •   本研究以不同比例的Co、Cr熔製成磁性層靶材,與純白金非磁性層靶材,利用離子束濺鍍機,將磁性層與非磁性層交互濺鍍在矽基板上,改變製程條件如改變鍍膜層數,鍍膜厚度,添加Under-layer與熱處理等,製備出各種不同條件之磁性多層膜。
      利用EDS,AES等分析薄膜元素組成,以XRD作結構分析,SEM、TEM觀察微結構,AFM觀察表面起伏狀態,SQUID,MOKE作磁性質的量測。
      實驗結果顯示,以離子束濺鍍之薄膜,晶粒大小約只有7~8nm,然而添加Under-layer與熱處理有助於晶粒成長。未添加Under-layer薄膜之最佳矯頑磁力為靶材Cr15之濺鍍30層30秒(每層15.9A)的Hc = 84.8Oe,經熱處理可使矯頑磁力增加為111Oe。而添加Pt Under-layer後出現之最佳矯頑磁力為靶材Cr20之濺鍍30層30秒(每層16.5A)的Hc = 111.8Oe,經熱處理後可使矯頑磁力增加為157.9Oe。

      Different composition of Co-Cr alloy targets were prepared as magnetic layer target, and pure Pt is prepared as spacer layer target. The magnetic layer and spacer layer was coated alternately on Si substrate by Ion Beam sputter. The experimental conditions such as the number of layers, the thickness of each layer, under-layer and heat treatment were the variables in this study.
      The ratio of elements in the samples is measured by EDS and AES. The structure is analyzed by XRD. SEM and TEM observe the surface morphology and microstructure. The surface roughness of magnetic films was measured by AFM. The magnetic properties of magnetic films were determined by SQUID and MOKE.
      The experimental results show that the grain sizes of the film are only 7~8nm, but the additive of under-layer and heat treatment will increase the grain sizes. The best coercivity of non-under-layer film is 84.8Oe for Cr1530s30L, and heat treatment will increase the coercivity to 111Oe. And the best coercivity of Under-layered film is 111.8Oe for PtCr2030s30L, heat treatment will increase the coercivity to 157.9Oe.

    摘 要 ………………………………………………………………...…I Abstract ………………………………………………………………...II 目 錄 ………………………………………………………………...III 圖 目 錄 ………………………………….…………………………..VI 表 目 錄 ……………………………………………………...……….IX 第 1 章 前言 …………………………………………………………..1 1-1 簡介 ………………………………………………..……………...1 1-2 研究動機 …………………………………………..……………...1 第 2 章 文獻回顧與理論基礎 …………..…………………………..3 2-1 磁性記錄、鈷鉻合金與多層膜 …………………………………...3 2-1-1 記錄媒體的分類 ……………………………..…..……………...3 2-1-2 Co-Cr系合金薄膜薄膜 …………………………....…………...6 2-1-3 多層膜之基本理論 …………….…………..…………...……...11 2-2 濺鍍理論 ……………………………………..…………….……13 2-2-1 濺鍍法 ……………………………..………………………….13 2-2-2 薄膜濺鍍率 ………………………..………………………….19 2-2-3 薄膜沈積 ………………………..…………………………….21 第 3 章 實驗流程與儀器 ………………..…………………………23 3-1 實驗流程 ………………………..……………………………….23 3-2 靶材製作 …………………………..…………………………….24 3-3 基板製備 ……………………..………………………………….26 3-4 薄膜濺鍍 ……………..………………………………………….27 3-5 熱處理 …………………..……………………………………….31 3-6 成份分析 ………………………..……………………….………31 3-6-1 EDS分析 …………………….………………………………..31 3-6-2 Auger成份縱深分析 ………………………….………………32 3-7 X光繞射分析 ……………………………….…………………..32 3-8 電子顯微鏡分析 ………………………..……………………….32 3-8-1 掃瞄式電子顯微鏡(SEM)………………………...…………32 3-8-2 穿透式電子顯微鏡(TEM)…………………………………...33 3-9 AFM表面型態分析 ………………….………………………….33 3-10 磁性量測 ……………………………..………………………...36 第 4 章 結果與討論 …………………………………..……………37 4-1 基本性質量測 ……………………..…………………………….37 4-1-1 薄膜厚度與濺鍍率 ……………………………..…………….37 4-1-2 EDS成份分析 ………………………….………….………….39 4-1-3 Auger成份縱深分析 …………………….……………………41 4-2 結構分析 ………………..……………………………………….44 4-2-1 XRD結構分析 ……………….………………………….…….44 4-2-2 SEM表面觀察 ………………….…………………………..…53 4-2-3 TEM微結構觀察 ……………………………………………..56 4-2-4 AFM表面型態分析 …………………………………………..60 4-3 磁性質分析 ……………………..……………………………….66 4-3-1 合金成分與磁性質之關係 …………………..……………….66 4-3-2 多層膜之層數與磁性質之關係 ………..…………………….70 4-3-3 多層膜之單層厚度與磁性質之關係 ……………………..….74 4-3-4 多層膜之熱處理與磁性質之關係 …………………..……….78 第 5 章 結論 ………………………………………………………82 參 考 文 獻 …………………………………………………………..83

    1. T.P. Nolan, Y. Hirayama, M. Futamoto, ”Improvement of Co71Cr19Pt10/Ti90Cr10 perpendicular recording media by independent optimization of film nucleation and growth processes”, J. Appl. Phys. 79(1996) 5359.
    2. I.S. Lee, H. Ryu, H.J. Lee, T.D. Lee, “Role of a paramagnetic amorphous CoZr seed layer in CoCrPt/Ti perpendicular recording media”, J. Appl. Phys. 85(1999) 6133.
    3. H. Gong, M. Rao, D.E. Laughlin, D.N. Lambeth, “Highly oriented perpendicular Co-alloy media on Si(111) substrates”, J. Appl.Phys. 85 (1999) 4699
    4. S.Iwasaki & H.Yamazaki, Proc 7 the Ann Conf. On Magnetism ,4PA-7(1975)
    5. 金重勳,郭博成,郭志明,磁性技術手冊,台灣磁性技術協會(2000),191-197
    6. J.C.Lodder, “Magnetic structures in Co-Cr media for perpendicular magnetic recording”, J.Magn.Magn.Mater.,159(1996)238-248
    7. Shun-ichi Iwasaki, “Discoveries that guided the beginning of perpendicular magnetic recording”, J.Magn.Magn.Mater. , 235(2001)227-234
    8. P.-L. Lu and S. H. Charap, IEEE Trans. Magn. MAG-30, (1994) p.4230
    9. K. H. J. Buschow, Gary J. Long and Fernande Grandjean, “High Density Digital Recording”(1992), p 161
    10. Y. Hoshi, M. Naoe, “Changes in Structure and Magnetic Properties of Co-Cr Films by Oblique Incident of Sputtered Particles”, IEEE Transaction on Magnetics, Vol 24, NO. 6, November 1988, p3015-3017
    11. Masayuki Sagoi and Teisuo Inoue, “Effect of third-element additions on properties of Co-Cr-based films”, J. Appl. Phys. 67 (10), 15 May 1990, p5394-5398
    12. K. Hono, B. Wong, and D.E. Laughlin, “Crystallography of Co--Cr bilayer magnetic thin films”, J. Appl. Phys. 68 (9), 1 November 1990, p4734-4740
    13. K. Hono, Y. Maeda, S. S. Babu, and T. Sakurai, “Compositional inhomogeneities in sputtered Co-Cr magnetic thin films studied by atom probe field ion microscopy”, J. Appl. Phys. 76 (12), 15 December 1994, p8025-8031
    14. Li Cheng-Zhang, J. C. Lodder, J. A. Szpunar, “The Development of Texture in Co-Cr Films”, IEEE Transaction on Magnetics, Vol 30, NO. 4, July 1994, p1373-1379
    15. David J. Rogers, Yasushi Maeda, and Koji Takei, “Compositional Separation in Co-Cr Based Thin Film Magnetic Recording Media”, Scripta Metallurgica of Materialia, Vol 33, NO.10/11, 1995, pp1553-1561
    16. Kannan M. Krishnana, “Enhanced saturation magnetization, electronic structure, and compositional segregation in epitaxially grown Co–Cr thin films”, Appl. Phys. Lett. 67 (15), 9 October 1995, p2238-2240
    17. Y. Ikeda, Y. Sonobe, H. Uchida, T. Toyooka, “Characterization of a Thick Co-Cr Perpendicular Medium for a Merged MR Head”, Journal of Magnetism and Magnetic Materials 176, 1997, p13-19
    18. Shigeki Nakagawa, and Masahiko Naoe, “Control of nano-structure of the initial growth layers of Co-Cr thin films deposited by facing targets sputtering”, Vacuum, Vol 51, NO. 4, 1998, p 595-599
    19. Y. Hirayama, K. Ito, Y. Honda, N. Inaba, M. Futamoto, “Thermal stability of CoCr-alloy perpendicular magnetic”, Journal of Magnetism and Magnetic Materials 193, 1999, p253–257
    20. Nobuyuki Inaba, Yasutaro Uesaka, and Masaaki Futamoto, “Compositional and Temperature Dependence of Basic Magnetic Properties of CoCr-Alloy Thin Films”, IEEE Transaction on Magnetics, Vol 36, NO. 1, January 2000, p54-60
    21. G.W. Qina, K. Oikawaa, T. Ikeshojia, R. Kainumab, K. Ishida, “Magnetically induced phase separation in the Co-Cr binary system”, Journal of Magnetism and Magnetic Materials 234, 2001, L1-L5
    22. M. Sagoi and T. Inoue, “Effect of third-element additions of Co-Cr- based films ”, J. Appl. Phys. vol. 67, no.10, 15 May (1990) , p6394-6398
    23. K. Oikawa, G. W. Qin, O. Kitakami, Y. Shimada, K. Fukamichi, and K. Ishida, “Prediction of effectively elements for magnetically induced phase separation in Co-Cr-based magnetic recording media”, J. Appl. Phys., vol.79, no.5, 30 July(2001) , p 644-646
    24. K. M. Kemner, V. G. Harris, V. Chakarian, Y. U. Idzerda, W. T. Elam, C. C. Kao, Y. C. Feng, D. E. Laughlin, and J. C. Woicik, “The role of Ta and Pt in segregation within Co-Cr-Ta and Co-Cr-Pt thin film magnetic recording media”, J. Appl. Phys., vol. 79, no.8, 12 April(1996) , p 5345-5347
    25. Y. Sonobe, Y. Ikeda, H. Uchida, and T. Toyooka, ”Ti underlayer effect on the recording characteristics of Co-Cr perpendicular media with weak and strong interparticle interactions”, J. Appl. Phys., vol.81, no.8, 15 April,(1997) , p 4667-4669
    26. O. Kitakami, Y. Ogawa, H. Fujiwara, F. Kugiya, and M. Suzuki, “Influence os Initial Growth Layer and Ti Underlayer on Magnetic Properties and Recording Characteristics of Very Thin Films of Evaporated Co-Cr Media”, IEEE Trans. Magn., vol 25, no.3, May(1999) , p 2607-2611

    27. T. Onoue, T. Asahi, K. Kuramochi, J. Kawaji, T. Homma, and T. Osaka, “CoCrPtTa and Co/Pd Perpendicular Magnetic Recording Media with Amorphous Underlayers”, IEEE Trans. Magn., vol.37, no.4, July(2001) , p 1592-1594
    28. A. Sato, S. Nakagawa, and M. Naoe, “Co-Cr-Ta Perpendicular Magnetic Recording Media Using Pt Seed Layer”, IEEE Trans. Magn., vol. 36, no. 5, , Sept.(2000) p 2387-2389
    29. D. J. Rogers, J. N. Chapman, J. P. C. Bernards, and S. B. Luitjens, “Determination of local composition in Co-Cr films deposited at different substrate temperatures”, IEEE Trans. Magn., Sept.(1989) , p 4180-4182
    30. Y. Uchiyama, H. Sato, and Y. Kitamoto, “Effect of substrate temperature on magnetic and microstructural properties of sputtered Co-Cr films with perpendicular magnetic anisotropy”, IEEE Tran. Magn., vol. 28, no.5, Sep(1992) , p 2010-2017
    31. P. W. Jang, T. D. Lee, Y. H. Kim, and T. Kang, “Heat treatment effects of CoCr sputtered films”, IEEE Tran. Magn., vol. 26, no.5, Sep(1990) , p 1623-1625
    32. N. Inaba, Y. Uesaka, and M. Futamoto, “Compositional and temperature dependence of basic magnetic properties of CoCr-alloy thin films”, IEEE Tans. Magn., vol. 36, no. 1, Jan.(2000) , p 54-59
    33. A. Fartash, and H. Oesterreicher, “Magnetic properties of Co-Cr films and the effects of heat treatment”, J. Appl. Phys., vol. 66, no.7, 1 Oct.(1989) , p 3275-3281
    34. M. Sato, Y. Onishi, and A. Nakaue, “Co-based alloy media with a high coercivity prepared by heat treatment after sputtering”, IEEE Tran. Magn., vol.29, no.6, Nov.(1993) , p 3685-3687
    35. K. H. J. Buschow, Gary J. Long and Fernande Grandjean, “High Density Digital Recording” (1992) , p 340, p 463
    36. Masud Mansuripur, “The Physical Principles of Magneto-Optical Recording” (1995) , p433-436
    37. S. V. Vonsovskii, “Magnetism”, Keter Publishing House, Jerusalem (1974)
    38. S. Gasiorowics, “Quantum Physics”, Wiley, New York (1974)
    39. W. B. Zeper, H. W. van Kesteren, B. A. J. Jacobs, J. H. M. Spruit, and P. F. Carcia, J. Appl. Phys. 70 (1991) , p2264
    40. C. J. Lin and H. V. Do, IEEE Trans. Magn., MAG-26, 1700 (1990)
    41. F. J. A. den Broeder, D. Kuiper, A. P. van de Mosselaer, and W. Hoving, Phys. Rev. Lett. 60 (1988) , p2769
    42. C. H. Lee, Hui He, F. Lamelas, W. Vavara, C. Uher and Roy Clarke, Phys. Rev. Lett.62 (1989) , p653
    43. S. Araki, T. Takahata, and T. Shinjo, J. Magn. Soc. Of Japan, 13 (1989) , p339
    44. J. Ferre, G. Penissard, C. Marliere, D. Renard, P. Beauvillain, and J. P. Renard, 56 (1990) , p1588
    45. C. J. Lin, G. L. Gorman, C. H. Lee, R. F. C. Farrow, E. E. Marinero, H. V. Do, H. Notarys, J. Magn. Magn. Mater. 93 (1991) , p194
    46. C. H. Lee, R. F. C. Farrow, C. J. Lin, E. E. Marinero, and C. J. Chien, Phys. Rev. B-42 (1990) , p11384
    47. Donald L. Smith, “Thin Film Depositopn”, McGraw-Hill, Inc (1995) , p119
    48. Donald L. Smith, “Thin Film Depositopn”, McGraw-Hill, Inc (1995) , p119
    49. 莊達人,“VLSI製造技術”,高立圖書有限公司 (1999),p545
    50. 林瑞陽,“真空濺鍍及其工業應用”,台大慶齡工業中心演講, 第四章 (1995)
    51. John A. Thormton, “Influence of Apparatus Geometry and Deposition Conditions on the Structure and Topography of Thick Sputtered Coatings”, Journal of Vacuum Science Technology, Vol.11, No.4 (1974) , p666
    52. John A. Thormton, “Influence of Substrate Temperature and Deposition Rate on Structure of Thick Sputtered Cu Coatings”, Journal of Vacuum Science Technology, Vol.12, No.4 (1975) , p830

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