近年來，土壤及地下水有機污染事件層出不窮，又以油品污染為大宗，其中MTBE具有高水溶性極低土壤吸附性，容易隨著地下水傳輸而擴大污染範圍。為有效降低污染影響，必須針對影響標的提出整治方針，土壤及地下水整治技術中，現地化學氧化法可處理地表下污染區域而不受地面結構物之干擾，能節省復育時程及開挖或抽取後處理之成本，相較於其他整治技術較為有效且快速。
本研究以過氧化氫及過硫酸鈉作為氧化劑，利用不同煉鋼爐碴摻配成鐵系環境資材進行催化，藉以產生高氧化電位之自由基•OH及•SO4-，應用於去除土壤及地下水中有機污染物。由於自由基具反應活性大、存在時間短、濃度低等特性，一般需透過間接量測求出自由基的釋出率。本研究使用之化學探針pCBA同時對•OH及•SO4-有高反應速率，然而本研究選用之催化材使反應處於鹼性環境將影響pCBA測定，實驗透過修正移動相磷酸鹽緩衝溶液濃度為50 mM與有機溶劑成分為乙腈加1%冰醋酸可使pCBA量測之適用pH範圍廣泛。接續以鐵系環境資材催化過氧化氫及過硫酸鈉並以MTBE作為標的瞭解本系統去除污染物的能力。研究顯示鐵系環境資材催化過氧化氫進行類芬頓反應，因反應環境為高鹼雖不利於過氧化氫催化氧化，然而相較於試藥級鐵氧化物，鐵系環境資材具有多孔性質，且高溫產出過程可能使其具有較多的活化位置。另外，添加鐵系環境資材有助於進行異相催化，提升MTBE去除率。以過硫酸鈉為氧化劑，有利於鐵系環境資材進行催化反應，其中鐵系環境資材A催化過硫酸鈉有最佳的MTBE去除效果，反應24小時可將10 mg/L的MTBE完全去除。
過硫酸鹽反應進行擬一階反應進行模擬，發現藉由瞭解鐵的型態及pH值之反應速率常數可推估鐵系環境資材催化過硫酸鈉對去除污染物之反應速率。最後，研究利用化學探針降解率及MTBE去除率進行線性迴歸，發現兩者屬於高度正相關，並歸納出氧化活性推估至污染物降解之關聯性，期能藉由化學探針於整治污染物前先行篩選出具有催化過氧化氫及過硫酸鹽潛力之環境資材。

Chemical oxidation is a soil and groundwater remediation technology. It may treat subsurface contaminated area without interference of the structure, and is more effective and fast comparing to other remediation technologies. In this study, environmental iron-based materials which were mixed by steel slags will catalyze the H2O2 and Na2S2O8 decomposition, forming hydroxyl radicals (•OH) and sulfate radicals(•SO4-) with high oxidation capacity to destroy the organic pollutants. The pCBA was used as a chemical probe compound. Monitoring the change in pCBA removal rate provides an indirect measurement of the oxidation activity. MTBE was used as the target pollutant to investigate its relationship between the oxidation activity and MTBE removal efficiency.
High pH environment will affect the detection of pCBA probe compound. However, it can be solved by the correction of mobile phase. In the catalytic oxidation reaction, the catalytic ability of environmental iron-based materials is greater than pure iron oxides because of their porous and greater activation position. Persulfate oxidation systems increased the oxidation activity and MTBE removal rate under wider pH range when compared to hydrogen peroxide oxidation systems. Using environmental iron-based material A to induce Na2S2O8 results in having the best MTBE removal efficiency, it can degrade 10 mg/L MTBE completely after reaction in 24 hours. In this study, pCBA removal rate and MTBE removal rate was positively correlated, and these chemical probes can be used to assess pollutant removal efficiency.

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