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研究生： 傅建銘
Fu, Chien-Ming
論文名稱： 交聯型含聚醚鏈段之單一鋰離子傳導高分子薄膜之製備與其特性分析
Preparation and Properties of Single Lithium-ion Conducting Polyelectrolytes with Crosslinked Polyether
指導教授： 郭炳林
Kuo, Ping-Lin
學位類別： 碩士
Master
系所名稱： 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年： 2007
畢業學年度： 95
語文別： 中文
論文頁數： 52
中文關鍵詞： 膠態高分子電解質 、VTF關係式 、單離子傳導體
外文關鍵詞： gelled polymer electrolytes, solid-state 7Li NMR, VTF relationship, single ion conductor
相關次數： 點閱：63  下載：1 
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    • 本研究製備之單鋰離子傳導薄膜係以含聚乙烯醚之環氧樹脂(PEGDE)與雙胺基聚烯醚(XTJ-500)、單胺基磺酸鋰鹽(AESA-Li)進行熱交鏈反應所得,製備之高分子薄膜具透明、柔軟及韌性。藉由FT-IR鑑定其反應與結構；由DSC及TGA分析其熱行為；solid-state 7Li MAS NMR分析鋰離子在單鋰離子傳導薄膜之環境互動變化；利用交流阻抗分析測量其離子傳導度。結果顯示離子傳導行為與溫度關係符合VTF關係式,表示離子傳導度與高分子鏈的活動力有關。另製備以無溶劑型單鋰離子傳導薄膜吸收適量PC後而得之膠態單鋰離子傳導薄膜,並由DSC與交流阻抗分析得知PC的加入能增加高分子鏈之活動力,導致離子傳導度提升。

    New crosslinked single lithium-ion conducting polyelectrolytes were successfully prepared based on poly(ethylene glycol) diglycidyl ether, polyoxyalkylene diamines and 2-aminoethanesulfonic acid lithium salt. The obtained films were transparent, tough, and flexible. The effects of introduced lithium sulfonate on the microstructure and ionic conductivity of these polyelectrolytes were investigated by means of Fourier transform infra-red (FT-IR) spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), a. c. impedance and solid-state nuclear magnetic resonance (NMR) measurements. The ionic conduction of solvent free single ion conductors followed VTF behavior, and affected significantly by the mobility of polymer chains. The introduction of PC plasticizer effectively increased the ionic conductivity of single ion conductors, ascribing the increase of ion mobility.

    壹、 中文摘要.........................................I 貳、 英文摘要........................................II 參、 誌謝...........................................III 肆、 總目錄..........................................IV 伍、 表目錄.........................................VII 陸、 圖目錄........................................VIII 柒、 主文.............................................1 第一章 緒論.............................................1 1-1 前言..................................................1 1-2 鋰離子二次電池的發展..................................2 1-3 高分子電解質..........................................4 1-4 無溶劑型高分子電解質..................................6 1-5 膠態高分子電解質.....................................11 1-6 研究動機.............................................13 第二章 實驗與儀器原理....................................14 2-1 交流阻抗分析.........................................14 2-1.1 基礎電路學簡介.....................................14 2-1.2 交流阻抗分析.......................................16 2-2 固態核磁共振光譜.....................................19 2-2.1魔術角旋轉..........................................20 第三章 實驗方法與步驟....................................23 3-1 實驗藥品.............................................23 3-2 儀器設備.............................................23 3-3 單鋰離子傳導薄膜之製備...............................24 3-3.1 AESA-Li之合成......................................24 3-3.2 無溶劑型單鋰離子傳導薄膜之製備.....................25 3-3.3 膠態單鋰離子傳導薄膜之製備.........................26 3-4 單鋰離子傳導薄膜之鑑定...............................26 3-4.1 傅立葉轉換紅外線光譜儀.............................26 3-4.2 微差式掃描熱卡計...................................27 3-4.3 熱重分析儀.........................................27 3-4.4 固態7Li魔術轉角核磁共振光譜........................27 3-4.5 交流阻抗分析.......................................27 第四章 結果與討論........................................29 4-1 無溶劑型單鋰離子傳導薄膜.............................29 4-1.1 單鋰離子傳導薄膜之製備與結構鑑定...................29 4-1.1-1 AESA-Li結構之鑑定................................29 4-1.1-2 傅立葉轉換紅外線光譜.............................30 4-1.2 熱行為分析.........................................30 4-1.2-1 DSC..............................................30 4-1.2-2 熱重分析法.......................................32 4-1.3 固態7Li魔術轉角核磁共振光譜........................32 4-1.4 離子傳導度.........................................34 第五章 結論..............................................36 參考文獻.................................................37 圖表結果.................................................44 自述.....................................................52

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