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研究生: 蔡文晟
Tsai, Wen-Cheng
論文名稱: 利用溶液壓印法製備的準二維鈣鈦礦微米線法布里-珀羅共振腔之雷射特性研究
Lasing Characteristics of Quasi-2D Perovskite Microwire Fabry-Pérot Resonators Produced by Solution Imprinting
指導教授: 徐旭政
Hsu, Hsu-Cheng
學位類別: 碩士
Master
系所名稱: 理學院 - 光電科學與工程學系
Department of Photonics
論文出版年: 2024
畢業學年度: 112
語文別: 英文
論文頁數: 95
中文關鍵詞: 準二維鈣鈦礦Fabry-Pérot 雷射楊氏干涉
外文關鍵詞: quasi-2D perovskites, Fabry-Pérot laser, Young's interference
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  • 準二維鈣鈦礦具有特殊的量子井結構以及非常高的量子產率,這對於雷射應用非常有益。然而,準二維鈣鈦礦中低維度相的形成可能會降低能量轉移效率。本研究發現,透過摻雜鈉離子作為有機間隔物能有效減少n=1相的形成,並且能夠抑制準二維鈣鈦礦中的非輻射複合損失。
    在本研究中,我們採用具有CD週期結構的PFPE模具,透過溶液壓印法製作了高品質的準二維鈣鈦礦微米線,進而建構Fabry-Pérot共振腔。透過這種簡單方法,我們能夠生產出具有低雷射閾值和高品質因子的Fabry-Pérot雷射。
    特別的是,透過角分辨的微光致發光光譜技術,可以觀察到微米線形成的Fabry-Pérot共振腔揭示了類似楊氏干涉實驗的現象。在這種情況下,微米線的兩個端點充當了雙縫實驗中雙縫的角色,從而推斷出Fabry-Pérot共振腔模式的奇偶性。

    Quasi-2D perovskites possess a unique quantum well structure and exhibit exceptionally high quantum yield, which is very beneficial for laser applications. However, forming low-dimensional phases in quasi-two-dimensional perovskites can reduce energy transfer efficiency. This study found that doping Na+ (sodium ions) as organic spacers can efficiently minimize the creation of the n=1 phase and curtail non-radiative recombination losses in quasi-2D perovskites.
    In this study, we used a PFPE mold with a CD periodic structure to create high-quality quasi-2D perovskite microwires through solution imprinting, thereby constructing a Fabry-Pérot resonator. Through this simple method, we were able to produce Fabry-Pérot lasers with low lasing thresholds and high-quality factors.
    Especially, by using angle-resolved μ-PL spectroscopy, it was observed that the formed microwire Fabry-Pérot resonator revealed phenomena similar to Young's interference experiment. In this context, the two ends of the microwire acted as the double slits in the experiment, thereby inferring the parity of the Fabry-Pérot resonance modes.

    摘要 I Abstract II 致謝 III Content IV List of Tables VII List of Figures VIII Chapter 1. Introduction 1 1.1 Preface 1 1.2 Historical Review 3 1.2.1 Perovskite 3 1.2.2 Two-dimensional Ruddlesden–Popper Perovskites 7 1.2.3 Quasi-2D Ruddlesden–Popper Perovskites Lasers Array 10 1.3 Motivation 12 Chapter 2. Background theories 13 2.1 Characteristics of Two-dimensional Perovskite 13 2.1.1 Crystal Structure 13 2.1.2 Photoluminescence 16 2.2 Manipulation of Quasi-2D Perovskite Phase Distribution 18 2.3 Fabry-Pérot lasers 20 2.4 Young’s Interference Experiment 22 Chapter 3. Experiment Process and Measurement 25 3.1 Preparation of Quasi-2D Perovskite 25 3.1.1 Precursor Solutions Preparation 25 3.1.2 Synthesis of Quasi-2D Perovskite Thin Films 26 3.2 Solution Growth of Quasi-2D Perovskite Confined By PFPE Templates 27 3.3 Analysis of the Morphologies 29 3.3.1 Scanning Electron Microscope (SEM) 29 3.3.2 X-ray Diffraction (XRD) 31 3.3.3 Grazing-Incident Wide-Angle X-Ray Scattering (GIWAXS) 33 3.4 Measurement of Optical Characteristics 34 3.4.1 Micro-Photoluminescence (μ-PL) System 34 3.4.2 Angle-resolved Photoluminescence (ARPL) 36 3.4.3 Time-Resolved Photoluminescence (TRPL) System 38 3.4.4 Optical Absorption System 41 Chapter 4. Result and Discussion 42 4.1 Manipulation of PEABr-based Quasi-2D Perovskite Phase Distribution 42 4.1.1 Absorption and PL Spectra 42 4.1.2 Absorption Spectra with Different NaBr Molar Ratios 44 4.1.3 Absorption and PL Spectra of Thin Films Varying in Different NaBr Concentrations 46 4.1.4 Excitation Power-dependent PL Spectra Analysis 48 4.1.5 Time-Resolved PL Measurement 50 4.1.6 XRD Analysis 52 4.2 PEABr-based Quasi-2D Perovskite Microwires 54 4.2.1 Morphology of Microwires 54 4.2.2 EDS Analysis 56 4.2.3 GIWAXS Analysis 57 4.2.4 PL Analysis of Microwire 59 4.2.5 Quasi-2D Perovskite Environmental Stability 60 4.2.6 Fabry-Pérot Mode Lasing 61 4.2.7 ARPL Analysis 70 Chapter 5. Conclusion and Future Work 73 5.1 Conclusion 73 5.2 Future Work 74 Reference 75 Appendix 81

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