| 研究生: |
劉哲儒 Liu, Che-Ju |
|---|---|
| 論文名稱: |
不同含浸材及添加物對碳/碳複合材料機械及磨耗性質的影響 N/A |
| 指導教授: |
陳瑾惠
Chern Lin, Jiin-Huey 朱建平 Ju, Chien-Ping |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 材料科學及工程學系 Department of Materials Science and Engineering |
| 論文出版年: | 2005 |
| 畢業學年度: | 93 |
| 語文別: | 中文 |
| 論文頁數: | 214 |
| 中文關鍵詞: | 碳/碳複合材料 、磨耗 |
| 外文關鍵詞: | carbon/carbon composites |
| 相關次數: | 點閱:41 下載:5 |
| 分享至: |
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碳/碳複合材料為碳纖維強化碳基材複合材料的簡稱,其優點包括在高溫下仍有高彈性係數及強度、低密度、機械疲勞抵抗力等,且在加工後製成的零件組遠比其他合金材料輕許多,如鋼鐵等。除此之外,碳/碳複合材料還擁有高比熱、自潤滑及低磨耗等優點。
本實驗主要研究PAN系碳纖維補強乾粉酚醛樹脂基材之碳/碳複合材料,並藉由改變含浸基材的不同、基材添加物與含浸時加入添加物的方式,在熱壓成型之後經由各種處理方式,包括穩定化、快速碳化、緻密化及石墨化處理,緻密化的處理採用液態含浸法來提升複材的基本性質。比較各製程的基本性質、機械性質及磨耗表現之影響。
在改變含浸基材的實驗結果發現,含浸基材為酚醛樹脂的系列試片,在基本性質、機械性質及磨耗表現都比含浸呋喃樹脂的系列試片要來的好。
在改變基材添加物方面及含浸時加入添加物的實驗結果發現,基材中添加5vol%石墨並改變含浸基材及添加物,包括含浸酚醛樹脂及煤焦瀝青,含浸煤焦瀝青的系列試片在撓曲強度、模數性質相近,而含浸基材添加石墨的試片其摩擦係數較穩定且磨耗量低;含浸酚醛樹脂的系列試片,含浸基材添加石墨的的撓曲強度及模數是最低,含浸基材無添加物及添加碳黑的試片磨耗曲線穩定,除含浸基材添加石墨有產生些微亮帶之外,試片磨耗量差異不大。
含浸基材的不同及在基材中添加添加物在基本性質、機械強度及磨耗表現上皆會呈現不同的改變。以基材添加5vol%石墨的碳/碳複合材料方面,含浸煤焦瀝青的系列試片其整體撓曲強度及模數最高;含浸酚醛樹脂系列的摩擦係數穩定;含浸煤焦瀝青添加石墨的磨耗量低且摩擦係數穩定。
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