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研究生: 洪崑智
Hung, Kuen-Chih
論文名稱: 石墨烯薄膜之成長及製備壓力感測器與特性研究
Growth of Graphene and it Fabrication,Characteristics Measurement of Graphene Thin-Film Pressure Sensor
指導教授: 高騏
Gau, Chie
學位類別: 碩士
Master
系所名稱: 工學院 - 航空太空工程學系
Department of Aeronautics & Astronautics
論文出版年: 2012
畢業學年度: 100
語文別: 中文
論文頁數: 76
中文關鍵詞: 石墨烯壓力感測器
外文關鍵詞: Graphene, Pressure Sensor
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  • 自從2004年石墨烯(Graphene)被發現以來,是近幾年發展迅速的新興材料,由於其獨特的材料特性,石墨烯在機械性質、化學穩定度、熱傳導及高載子遷移率等方面都有相當出色的表現。
    本研究利用酒精催化化學氣相沉積(Alcohol Catalytic Chemical Vapor Deposition , ACCVD)的方式在鎳箔上成長數層石墨烯,並探討通入碳源氣體的時間及快速降溫的效果,對於層數上的影響,並且利用溼蝕刻的方式,將數層石墨烯從鎳箔轉移到其他基板上,以利後續的元件製作。
    實驗結果顯示,在最佳化的參數下,可以在鎳箔上成長出高覆蓋率及大面積(公分等級)的數層石墨烯。所製備之石墨烯壓力感測器,當薄膜材料受到壓力變化而變形時,其電阻值也會因而改變,電阻值與壓力呈線性的關係,並顯示不同成長時間的軟板薄膜材料之壓阻特性。

    Graphene was discovered since 2004, Graphene material which was developed quickly in recent years, due to its unique material characteristics, graphene such as in mechanical properties, chemical stability, thermal conductivity and high carrier mobility has excellent performance.
    In this study, using alcohol catalytic chemical vapor deposition method (ACCVD) to grow of few layer graphene on Ni foil, and the layers effects of carborn source time and rapid cooling will be discussed, and few layer graphene from Ni foil will be transferred to other substrate by wet etching method, in order to manufacture devices.
    According to the results, in the optimization of parameters we can grow high coverage and large area (Centimeter scale). Fabrication of graphene thin-film pressure sensor when thin-film material is deformed by pressure changes, and therefore its resistance changed, showing a linear variation between the pressure and the resistance with piezoresistive characteristics of different Growth time flexible thin-film materials.

    口試合格簽名頁 中文摘要 英文摘要 致謝 目錄 I 表目錄 IV 圖目錄 V 第一章 序論 1 1.1研究背景與前言 1 1.2低維度奈米碳材的發展 3 1.3壓力感測器介紹 4 第二章 石墨烯發展概論 6 2.1石墨烯的製程方法 6 2.1-1膠帶剝離法 6 2.1-2熱裂解磊晶成長於碳化矽 7 2.1-3氧化石墨烯還原法 7 2.1-4 化學氣相沉積法(CVD 8 2.2石墨烯的轉移 12 2.3石墨烯的成長機制 13 2.4石墨烯在拉曼光譜的分析 14 第三章 實驗製程與量測分析 16 3.1成長石墨烯與分析 16 3.1-1實驗材料 16 3.1-2利用酒精催化劑化學氣相沉積成長石墨烯 16 3.1-3石墨烯的成長製程 16 3.1-4石墨烯的量測分析 17 3.2 石墨烯薄膜之壓力感測器製程與分析 19 3.2-1實驗設備 19 3.2-2實驗材料與石墨烯轉移方法 20 3.2-3壓力感測器製程介紹 21 3.2-4壓力感測器量測 22 第四章 實驗結果與討論 23 4.1 石墨烯薄膜各種製程參數研究 23 4.1-1 不同成長時間之石墨烯影響 23 4.1-2 不同製程溫度之石墨烯影響 28 4.2 壓力感測器量測分析 28 4.2-1不同薄膜材料之壓力感測器分析 28 第五章 結論 32 參考文獻 33

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