| 研究生: |
蔡宗憲 Tsai, Zong-Xiang |
|---|---|
| 論文名稱: |
摻銅氧化鋅薄膜之光電特性探討 Study on the optical and electrical properties of copper-doped ZnO thin film |
| 指導教授: |
洪茂峰
Houng, Mau-Phon |
| 學位類別: |
碩士 Master |
| 系所名稱: |
電機資訊學院 - 微電子工程研究所 Institute of Microelectronics |
| 論文出版年: | 2009 |
| 畢業學年度: | 97 |
| 語文別: | 英文 |
| 論文頁數: | 60 |
| 中文關鍵詞: | 光致發光 、銅 、氧化鋅 |
| 外文關鍵詞: | Photoluminescence, Cu, ZnO |
| 相關次數: | 點閱:84 下載:5 |
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氧化鋅是一種具有直接寬能隙(3.37eV)的二六族化合物半導體,有相對較大的束縛能(60meV),因此在室溫下相對穩定;此外,藉由間接借由摻雜相異元素,產生各異的光電以及結構上的特性。這些因素促使氧化鋅被廣泛應用於光電元件,表面聲波元件等方面。
本實驗中利用磁控射頻濺鍍法成長氧化鋅和銅的夾層結構,再施快速熱處理,使之彼此擴散,以成長為一摻銅之氧化鋅薄膜。之後,使用各種量測儀器去探討其特性。在本實驗中可發現,隨著不同的退火溫度參數,在晶體結構上以及鍵結型態上均有改變。光學性質和電性上有著顯著改變伴隨著能隙的增減。再藉由光激發光光譜儀的量測,來推論摻銅造成氧化鋅性質改變的原因。
ZnO is group II-IV compound semiconductor with wide direct bandgap for 3.37eV. A relative stable under room temperature is attributed to larger binding energy 60meV. In addition, different electrical, optical, and structural properties could be manufactured by doping various elements, contributing to a wide application on optoelectronic devices and surface acoustic devices, and so on.
A multilayer structure consists of ZnO and Cu by RF magnetron sputtering technique in this experiment. Both materials were inter-diffused by rapid thermal annealing. Afterwards, characteristics of films fabricated in this experiment were investigated. Crystalline as well as bonding state changes with different thermal parameters of post-annealing. Transformations on both optical and electrical were of a considerable magnitude along wth variation of bandgap. PL was also applied to infer the mechanism that doping of Cu in ZnO.
[1] N. Horio, M. Hiramatsu, M. Nawata, K. Imaedab, T. Toriib, “Preparation of zinc oxide/metal oxide multilayered thin films for low-voltage varistors”, Vacuum, Vol. 51, pp.719-722, 1998.
[2] N. Jayadev, S.R. Sainkar, R.N. Karekar, R.C. Aiyer, “Formulation and characterization of ZnO:Sb thick-film gas sensors”, Thin Solid Films, Vol. 325, pp. 254-258, 1998.
[3] T.R. N.Kutty, N.Raghu, “Varistors based on polycrystalline ZnO:Cu”, Appl. Phys. Lett., Vol. 54, pp. 1796-1798, 1989.
[4] D.C. Look, “Recent advances in ZnO materials and devices”, Mater. Sci. Eng. B80, pp.383-387, 2001.
[5] R.Triboulet, J.Perrie J. Perrie`re, ” Epitaxial growth of ZnO films”, Prog. Cryst. Growth. Charact. Mater. ,Vol. 47, pp. 65-138, 2003.
[6] S. J. Pearton, D. P. Norton and T. Steiner, “Recent progress in processing and properties of ZnO”, Prog. Mater. Sci., Vol. 50, pp. 293-340, 2005.
[7] D.R. Sahu, Jow-Lay Huang, “Characteristics of ZnO–Cu–ZnO multilayer films on copper layer properties”, Appl. Surf. Sci., Vol. 253, pp.827–832, 2006.
[8] Ü. Özgür, Ya. I. Alivov, C. Liu, A. Teke, M. A. Reshchikov, S. Doğan, V. Avrutin, S.J. Cho and H. Morkoçd, “A comprehensive review of ZnO materials and devices”, J. Appl. Phys. ,Vol. 98, 041301, 2005.
[9] S. Chakrabarti, B. Doggett, R. O’Haire, E. McGlynn, M.O. Henry, A. Meaney and J.-P. Mosnier, “p-type conduction above room temperature in nitrogen-doped ZnO thin film grown by plasma-assisted pulsed laser deposition” Electron. Lett. Vol. 42, No.20, 2006.
[10] H. Y. Xu, H. Y. Xu, R. Mu, C. L. Shao, Y. M. Lu, D. Z. Shen, and X. W. Fan, “F-doping effects on electrical and optical properties of ZnO nanocrystalline films”, Appl. Phys. Lett., Vol. 86, 123107 , 2005.
[11] X.B. Wang, D.M. Li, F. Zeng and F. Pan, ”Microstructure and properties of Cu-doped ZnO films prepared by DC reactive magnetron sputtering”, J. Phys. D: Appl. Phys., Vol. 38, PP. 4104–4108, 2005.
[12] K. Sivaramakrishnan and T. L. Alford, ” Metallic conductivity and the role of copper in ZnO/Cu/ZnO thin films for flexible electronics”, Appl. Phys. Lett., Vol. 94, 052104, 2009.
[13] G. Müller, R. Helbig, “Über den Einbau von Kupfer in ZnO-Einkristallen” J. Phys. Chem. Solids, Vol. 32 pp.1971-1977 ,1971.
[14] Smits, F. M., "Measurements of Sheet Resistivity with the Four-Point Probe”, BSTJ, Vol. 37, p. 711, 1958.
[15] A. D. L. Humphris, M. J. Miles, and J. K. Hobbs “A mechanical microscope: High-speed atomic force microscopy”, Appl. Phys. Lett. , Vol. 86, 034106, 2005.
[16] Kaung-Way Chu, ”The Analysis for TiN Films on LEDs as Transparent Conductive Films”, thesis, Institute of Microelectronics, National Cheng Kung University, R.O.C. , 2003
[17] L. Stolt, J. Hedstrom, M. Ruckh, K.V. Velthaus, and h. W. Schock, “ZnO/CdS/CuInSe2 thin-film solar cells with improved performance”, Appl. Phys. Lett., Vol. 62, pp.597-599, 1993.
[18] S. Shionoya, W.M. Yen, Phosphor book, CRC Press, Boca Raton , FL,(1999), p255.
[19] K. Kobayahi, H. udaka, S. Matsushima, G. okada “Photoinduced charge transfer of Cu-doped ZnO film”, J. Mater. Sci. Lett., Vol. 13, pp. 103-104, 1994.
[20] JCPDS Card, International Centre for Diffraction Data, 2002
[21] U. Wahl, E. Rita, J.G. Correia, T. Agne,E. Alves, J.C. Soares, The ISOLDE Collaboratio, ”Lattice sites of implanted Cu and Ag in ZnO”, Superlattice. Microst., Vol. 39 , pp. 229–237, 2006.
[22] Yanfa Yan, K.-S. Ahn, S. Shet, T. Deutsch, M. Huda, S.H. Wei, J. Turner, M.M. Al-Jassim, “Band gap reduction of ZnO for photoelectrochemical splitting of water” Proc. of SPIE, Vol. 6650 , pp.66500H-1 – 66500H-9, 2007.
[23] M. Ferhat, A. Zaoui, and R. Ahuja, “Magnetism and band gap narrowing in Cu-doped ZnO”, Appl. Phys. Lett., Vol. 94, 142502, 2009.
[24] K.H. Kim, K.C. Park, and D.Y. Ma, “Structural, electrical and optical properties of aluminum doped zinc oxide films prepared by radio frequency magnetron sputtering”, J. Appl. Phys., Vol. 81, pp.7764-7772, 1997.
[25] Xingping Peng, Jinzhang Xu, Hang Zang, Boyu Wang, Zhiguang Wang, “Structural and PL properties of Cu-doped ZnO films”, J. Lumin., Vol. 128, pp.297–300, 2008.
[26] T. Karali, N. Can, L. Valberg, A.L. Stepanov,, P.D. Townsen, Ch. Buchal, R.A. Ganeev, A.I. Ryasnyansky, H.G. Belik,M.L. Jessett, C. Ong “Optical properties and luminescence of metallicnanoclusters in ZnO:Cu”, Physica B, Vol. 363, pp.88–95, 2005.
[27] T. Kryshtab, V.S. Khomchenko, V. B. Khachatryan, N.N. Roshchina, J.A. Andraca-Adame,O.S. Lytvynz, V.I. Kushnirenko, “Effect of doping on properties of Zno:Cu and Zno:Ag thin films”, J. Mater. Sci.: Mater. Electron., Vol. 18, pp.1115–1118, 2007.
[28] Yanfa Yan, M.M. Al-Jassim, and Su-Huai Wei, "Doping of ZnO by group-IB elements", Appl. Phys. Lett., Vol. 89, 181912, 2006.
[29] Akio Furukawa, Naoto Ogasawara, Ryoji Yokozawa, Takahiro Tokunaga, “Electron Trap Level of Cu-Doped ZnO”, Jpn. J. Appl. Phys., Vol. 47, pp. 8799–8801, 2008.
[30] C.X. Xu, X.W. Sun, X.H. Zhang, L. Ke, S.J. Chua, “Photoluminescent properties of copper-doped zinc oxide nanowires”, Nanotechnology, Vol. 15, , pp.856–861, 2004.
[31] M.Fox, Optical Properties of Solids, Oxford University Press, p.29, 2001.
[32] Z.-C. Jin, I. Hamberg and C.G. Granqvis, “Optical properties of sputter-deposited ZnO:Al thin films”, J. Appl. Phys., Vol. 64, 5117, 1988.