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研究生： 劉濱鳳
Liu, Pin-Feng
論文名稱： 微膠囊相變化材料應用於建材之熱傳性能研究-以鋁蜂巢板建材為例
Thermal Performance of a Building Material Incorporating Micro-encapsulated Phase Change Material (mPCM)─The Aluminum Honeycomb Board as an Example
指導教授： 曾俊達
Tzeng, Chun-Ta
共同指導教授: 賴啟銘
Lai, Chi-Ming
學位類別： 博士
Doctor
系所名稱： 規劃與設計學院 - 建築學系
Department of Architecture
論文出版年： 2018
畢業學年度： 106
語文別： 中文
論文頁數： 85
中文關鍵詞： 微膠囊相變化材料 、熱能儲存 、熱舒適度
外文關鍵詞： Micro-encapsulated phase change materials, Heat storage, Thermal comfort
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    • 本研究關注到微膠囊相變化材料吸熱與放熱的物理特性，對於熱帶或亞熱帶地區的建築，能有降低空調用電量的效益，是本研究關注的議題；考量外牆及屋頂的結構特性，及微膠囊相變化材料的熱傳遞方式，本研究選用不同熔點之微膠囊相變化材料，與結構穩固並且導熱性能佳的鋁蜂巢板結合，製作單元複合式板材，以垂直放置視為建築外牆進行實驗並分析，探討其對於降低室內能源之效益。

    長年觀測台南氣候，計算出一天日射熱得大約為10小時，並且太陽熱得介於200 ~ 600 W/m2區間，因此本研究以正弦波拋物線變化來推估，每10分鐘為一單位，至第5小時分別達到熱得峰值200 W/m2、400 W/m2及600 W/m2，選用37 ℃及43 ℃之微膠囊相變化材料，並且分別製作成鋁蜂巢板複合建材，將製作完成的試體垂直擺放，視為建築外牆，觀測試體一天24小時中，其溫度和熱流數據，並評估其效能。

    臺灣位於亞熱帶氣候區，由實驗結果得知，熔點37 ℃及43 ℃微膠囊相變化材料應用於建材，熔點43 ℃微膠囊相變化材料試體尖峰轉移能力較佳，能有效減緩熱能傳遞進入室內，延後建築物用電高峰的時間，進一步降低室內能源消耗；熔點43 ℃微膠囊相變化材料試體折減係數較低，表示較有效減緩熱能傳遞進入室內，室內環境熱舒適度較好，進而達到提高室內熱舒適度，降低用電量的目的。

    The problem of carbon dioxide (CO2) emissions and energy depletion is getting worse and worse. In recent years, the issues of Energy saving and CO2 emission reduction are advocated to stop this vicious circle. The Micro-encapsulated Phase Change Material (mPCM) incorporates with the aluminum honeycomb board as a part of the exterior wall structure. The phase change material (PCM) would convert the thermal energy of the outdoor environment into the latent heat energy by the thermophysical properties of the material. The purpose is to reduce or maintain same level of power consumption by reducing and delaying the influence of the solar radiation on the indoor environment thermal comfort. Based on Taiwan climate data analysis, we picked three different peaks of the solar radiation and make use of the two melting points (i.e. 37℃ and 43℃ ) of mPCM as our experimental samples. In these experiment results, the mPCM with melting point at 43℃ has better ability of the time lag and decrement factor, which can effectively reduce and delay the influence of the solar radiation on the indoor environment thermal comfort, and further reduce the power consumption.

    目錄 .................................................. I 表目錄 ...............................................III 圖目錄 ................................................IV 第一章 緒論 .............................................1 1-1 研究動機與目的 ......................................1 1-1-1 研究動機 ..........................................1 1-1-2 研究目的 ..........................................2 1-2 研究範圍與方法 ......................................3 1-2-1 研究範圍 ..........................................3 1-2-2 研究方法 ..........................................4 1-3 研究流程 ............................................5 第二章 文獻回顧 .........................................7 2-1 前言 ...............................................7 2-2 熱傳原理與特性 ......................................8 2-2-1 熱傳原理 ..........................................8 2-2-2 熱傳特性 .........................................11 2-3 微膠囊相變化材料(mPCM)之發展 ........................12 2-3-1 相變化材料(PCM)之定義 ............................12 2-3-2 微膠囊相變化材料(mPCM)之發展 ......................14 2-4 微膠囊相變化材料應用之相關研究 .......................16 2-4-1 微膠囊相變化材料應用於鋁蜂巢板之相關研究 ...........16 2-4-2 微膠囊相變化材料應用於建築之相關研究 ...............17 2-5 小結 ..............................................21 第三章 微膠囊相變化材料應用於建材熱傳性能實驗建構 .........23 3-1 前言 ..............................................23 3-2 微膠囊相變化材料應用於建材熱傳性能實驗規劃 ............24 3-2-1 微膠囊相變化材料應用於建材實驗環境訂定 .............24 3-2-2 微膠囊相變化材料應用於建材實驗步驟 .................27 3-3 微膠囊相變化材料應用於建材熱傳性能實驗基礎因子建置 ....33 3-3-1 微膠囊相變化材料應用於室內建材實驗基礎因子理論 ......33 3-3-2 微膠囊相變化材料垂直放置實驗實驗基礎因子 ...........34 3-4 小結 ..............................................38 第四章 微膠囊相變化材料應用於垂直建材成果彙整 .............39 4-1 前言 ..............................................39 4-2 微膠囊相變化材複合建材於熱得峰值200 W/m2 實驗 ........40 4-2-1 熔點37 ℃微膠囊相變化材料複合建材實驗 ..............40 4-2-2 熔點43 ℃微膠囊相變化材料複合建材實驗 ..............45 4-3 微膠囊相變化材料複合建材於熱得峰值400 W/m2 實驗 ......50 4-3-1 熔點37 ℃微膠囊相變化材料複合建材實驗 ..............50 4-3-2 熔點43 ℃微膠囊相變化材料複合建材實驗 ..............55 4-4 微膠囊相變化材料複合建材於熱峰值得600 W/m2 實驗 ......60 4-4-1 熔點37 ℃微膠囊相變化材料複合建材實驗 ..............60 4-4-2 熔點43 ℃微膠囊相變化材料複合建材實驗 ..............65 4-5 小結 ..............................................70 第五章 微膠囊相變化材料應用於建材熱傳性能分析 .............71 5-1 前言 ..............................................71 5-2 微膠囊相變化材料複合建材於熱得峰值200 W/m2 實驗 ......72 5-3 微膠囊相變化材料複合建材於熱得峰值400 W/m2 實驗 ......73 5-4 微膠囊相變化材料複合建材於熱得峰值600 W/m2 實驗 ......74 5-5 相同熔點微膠囊相變化材料複合建材 .....................75 第六章 結論及建議 ......................................77 6-1 結論 ..............................................77 6-2 建議 ..............................................79 參考文獻 ...............................................81

    中文論文【CS】
    CS01　周琪，鋁蜂巢板內置微膠囊相變化材料之動態熱傳特性，國立成功大學土木工程學系碩士論文，2015
    CS02　李承叡，PU微膠囊包覆混合正烷類相變化材料的製備及其吸放熱性探討，中國文化大學化學工程與材料工程學系碩士論文，2012
    CS03　楊雯欣，懸浮聚合法製備相轉移材料微膠囊，國立中央大學化學工程與材料工程研究所碩士論文，2007
    CS04　林敬堯，石膏板內添加微膠囊相變化材料之溫控現象實驗研究，台南科技大學機械工程研究所碩士論文，2009

    一般出版品【CB】
    CB01　林廣台、李世榮 著，熱傳遞，新科技書局，1989
    CB02　張有雄、張枝成、戴昌賢 著，熱傳遞學，全華科技圖書股份有限公司，1988
    CB03　J.P. Holman 著，楊春欽、毛迪 譯，熱傳遞學(第六版)，科技圖書股份有限公司，1988
    CB04　蔡豐欽 著，熱傳遞，高立圖書有限公司，1992

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    網際網路【CH】
    CH01　交通部中央氣象局網站https://www.cwb.gov.tw/V7/
    CH02　Microtek Laboratories INC. https://www.microteklabs.com/

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