本研究所使用之氮化鋁主要為本實驗室以不同鋁粉（包括Transmet、Ecka及遠洋等不同廠牌之鋁粉）經由燃燒合成而得（為進行比較，部分實驗亦使用合作公司提供之氮化鋁，代號為sample1、2、3、4）。本研究發現將實驗室合成之氮化鋁初產物進行乾式滾磨及濕式滾磨處理，於同樣滾磨時間下，乾式滾磨無法拆散部分團聚物，濕式滾磨則能有效將大部分團聚分散成單一顆粒（經四小時滾磨，乾式滾磨平均粒徑約為13 μm，濕式滾磨約為9 μm）。氮化鋁經滾磨後，吾人將之加入不同基材（包括液態環氧樹脂、固態環氧成型模料及室溫硫化縮合型灌封膠等），製作成氮化鋁/高分子複合材料進行流動性及熱傳導值探討及比較。於氮化鋁/液態環氧成型模料進行垂流法測試中，顯示出填充濕式滾磨後之氮化鋁皆較乾式滾磨粉體流動性佳，在符合要求之流動性下，固含量可填至78.3 wt%，甚至達到如同公司最佳產品sample1之固含量80 wt%，然而在不同複合材料測試中，發現不同氮化鋁會顯現出不一樣之流變行為，垂流法測試中，流動性最佳為sample1，而在環氧成型模料及矽橡膠中則為Transmet鋁粉合成之氮化鋁較佳，Transmet鋁粉合成之氮化鋁於環氧成型模料中不僅有最低之震盪力矩趨勢，而其熱傳導值（在相同的體積含量下）可從公司樣品2.45 W/m·K提升至9.11 W/m·K，應用於矽橡膠中（在合於要求流動性下）有最高固體添加量75 wt%，亦能將熱傳導值從0.3 W/m·K提升至1.66 W/m·K。

AlN used in this research is mainly obtained by combustion synthesis of different aluminum powders in the laboratory (including aluminum powders of different brands such as Transmet, Ecka, and Yuanyang). For comparison, some experiments also use the AlN from a cooperation company, codenamed sample1, 2, 3, and 4. This study found that the initial AlN product synthesized in the laboratory after dry milling and wet milling under the same milling time, part of the agglomerates after dry milling could not be dispersed, while wet milling could effectively disperse most of the agglomerates into single particles (after four hours milling, the average particle size of dry milling is about 13 μm, and the wet milling is about 9 μm). AlN after milling was added to different substrates (including liquid epoxy resin, solid epoxy molding compound, and room temperature vulcanization condensation type potting compound, etc.). Fabrication of AlN/polymer composites for comparison of fluidity and thermal conductivity. In the sagging method test of liquid epoxy resin, it is shown that the fluidity of AlN after wet milling is better than the dry milling product, and the solid content can be filled to 78.3 wt%, even reaching the best as sample1 80 wt%, However, in the testing of different composites, it was shown that AlN will have different rheological behaviors. In the sagging method test, the best fluidity is sample1, while in the epoxy molding compound and silicone rubber systems, AlN synthesized by Transmet aluminum powder is preferred. It not only has the lowest oscillation torque, but its thermal conductivity (under the same volume content) can be increased from 2.45 W/m·K to 9.11 W/m·K, and used in silicone rubber (under the required fluidity) also has a maximum solid content of 75 wt%, which can increase the thermal conductivity from 0.3 W/m·K to 1.66 W/m·K.

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