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研究生: 朱孫孝
Jhu, Sun-Siao
論文名稱: 以噴霧及電紡絲法製備二氧化矽超滑表面
Fabrication of Slippery Liquid-Infuse Porous/Textured SiO2 Surface by Spraying and Electrospinning
指導教授: 陳進成
Chen, Chin-Cheng
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2016
畢業學年度: 104
語文別: 中文
論文頁數: 107
中文關鍵詞: 超滑表面電紡絲雙疏表面
外文關鍵詞: Slippery Liquid Infused Porous Surface, Electrospinning, omniphobic surface
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  • 本研究主要探討如何以二氧化矽為材料製備具雙疏特性之超滑表面,並比較以不同結構粗糙基底製成之超滑表面其滑動效能隨時間的變化。首先製備以二氧化矽為材料之粗糙表面並以改質劑Trichloro(1H,1H,2H,2H-perfluorooctyl)silane將碳氟鍵官能基嫁接於二氧化矽表面,使之成為具低表面能之粗糙結構,再灌入低表面能之潤滑劑(Perfluoropolyether, Solvay, Fomblin M03)製成超滑表面。
    本研究以兩種方法製備不同結構之二氧化矽粗糙表面,第一種方法為二氧化矽粒子膠體溶液噴灑在塗佈於玻璃基板的矽膠層,以矽膠為黏著層黏著微米級二氧化矽粒子,經熱固化處理後得到具有二氧化矽粒子突起結構之粗糙表面,第二種方法為將二氧化矽前驅溶液經電紡絲法製備成二氧化矽之奈米纖維,並以此纖維交織構成的膜作為超滑表面之粗糙基底。
    實驗結果顯示將低表面能潤滑劑填入粗糙結構便可製成超滑表面,使水珠能夠在3∘,油酸能夠在5∘的滑動角滑動。在水流沖刷測試上,對不同平均粒徑二氧化矽粒子所構成之超滑表面,較小粒徑二氧化矽有較佳耐沖刷效果;而對不同平均粗細纖維所構成之超滑表面,較細的纖維有較佳耐沖刷效果。兩方法製備之超滑表面,以纖維製成之超滑表面有較佳耐沖刷效果。故由本實驗結果可知,較小粗糙度及高孔隙特性的基底構成之超滑表面在水流沖刷下具有較佳的耐久性。

    In this study, the water/oil-repellent Slippery Liquid Infused Porous Surface (SLIPS) with low sliding angle of water (<3∘) and oleic acid (<8∘) was fabricated by infusing the lubricant(Perfluoropolyether, Solvay, Fomblin M03) onto the fluorinated SiO2 textured substrates. The substrates were fabricated in two different ways. One is spraying the silica particle on the silicone gel and then curing the gel to bind the particle and form the texture substrate. Another method is fabricating the silica fiber mat by electrospinning as porous substrate. The substrates were modified by grafting the fluorinated coupling agent(Trichloro(1H,1H,2H,2H-perfluorooctyl)Silane) on the surface of SiO2 substrates. The lubricant was infused onto the modified textured substrate and form the SLIPS.
    The effect of the underlying substrates on their abilities to retain the lubricant under water flow(34cm/min) was investigated. By comparing the sliding angle of water droplet(10µl) on the washed SLIPS, the substrates with smaller surface roughness and more pores provides larger capillary force to entrap the lubricant, leading to better durability under water flow system.

    中文摘要 I Extent Abstract III 誌謝 XIV 目錄 XVI 圖目錄 XXI 表目錄 XXV 第一章 緒論……………………………………………………………...1 1-1前言……………………………………………………………………….1 1-2研究動機………………………………………………………………….2 第二章 文獻回顧……………………………………………………….4 2-1液體的潤濕行為………………………………………………………….4 2-1-1潤濕行為……………………………………………...…...4 2-1-2靜態接觸角(Young's model)…….……………………..5 2-1-3動態滑動角………………………………………………..6 2-2粗糙表面對潤濕行為的影響……………………………...7 2-2-1蓮花效應 ……….…………………………………………....7 2-2-2溫佐模型(Wenzel's model)……………………………......9 2-2-3卡西-巴斯特模型(Cassie and Baxter's model)……………11 2-2-4過渡狀態之潤濕模型………..………………………………13 2-2-5超疏水/疏油表面…………………….……………………….15 2-3 超滑表面………………………………………………....16 2-3-1超滑表面的基本原理………………………………………..16 2-3-2超滑表面的設計條件………..……………………………..17 2-3-3超滑表面的製備方法……………………………………..19 2-3-4超滑表面的應用研究……………………………………..23 2-4 靜電紡絲……………………………………………………... 27 2-4-1靜電紡絲原理及過程…….…………………………......27 2-4-2電噴霧……………………….……………………………..30 2-4-3電噴霧原理及過程……………..……………………….…30 2-4-4以靜電紡絲法製備金屬氧化物奈米纖維……..…………32 2-5 溶膠凝膠法…………………………………………………….34 2-5-1 PH值對溶膠凝膠反應的影響………….…………………..36 2-5-2溶膠凝膠系統之凝膠化現象…………….…………………37 第三章 實驗方法與儀器……………………………..…………………...41 3-1實驗藥品……………………………………………………..……...41 3-2實驗設備………………………………………………………..…..45 3-3分析方法……………………………………………………………47 3-3-1掃描式電子顯微鏡(Scanning Electron Microscopy, SEM)……………………………………………………………….47 3-3-2傅立葉紅外線光譜儀 (Fourier-Transform Infrared Spectrometer,FTIR) ………………………………………………50 3-3-3接觸角量測儀(Contact angle meter) …………..……………….51 3-3-4水流沖刷測試……………………………………………………52 3-4 實驗步驟……………………………………………………53 3-4-1粗糙表面製備…………………………….……………………….53 3-4-1-1以噴霧法製備二氧化矽粒子構成之粗糙表面…………………53 3-4-1-2以電紡絲法製備二氧化矽纖維構成之粗糙表面……………...54 3-4-2二氧化矽表面改質……………………………………..……..55 3-4-3浸潤潤滑劑製得超滑表面………………………………….55 3-4-4水流沖刷測試……..…………………………………………55 第四章 結果與討論………………………………………………...56 4-1 以噴霧法製備低表面能之二氧化矽粗糙表面……………….……57 4-1-1二氧化矽粒子之化學組成分析……………..…………………....57 4-1-2以不同濃度二氧化矽溶膠溶液噴塗於矽膠層之粗糙表面特性…..…………………………………………..……………………….....60 4-1-3不同改質劑濃度對粗糙表面特性影響………….…………..64 4-1-4不同二氧化矽覆蓋率之低表面能粗糙表面特性………………66 4-2 以噴霧法製備之二氧化矽超滑表面……………………...………70 4-2-1超滑表面與低表面能粗糙表面之滑動性比較………………70 4-2-2粗糙表面之表面特性對超滑表面穩定性的影響…………...72 4-2-3毛細作用力對超滑表面穩定性的影響………………….…74 4-2-4不同粒徑二氧化矽粒子所製備之低表面能粗糙表面…......76 4-2-5不同粒徑二氧化矽粗糙表面製成之超滑表面比較…...…79 4-2-6噴霧法製備之二氧化矽超滑表面之耐沖刷測試..…………80 4-3 以電紡絲法製備二氧化矽粗糙表面…………………….….…82 4-3-1前驅溶液濃度對二氧化矽纖維型態的影響……….………82 4-3-2電壓對二氧化矽纖維平均粗細的影響…………….…….…85 4-3-3前驅物進料流率對二氧化矽纖維平均粗細的影響……....86 4-3-4二氧化矽纖維之化學組成分析…………………………..…88 4-3-5 不同平均粗細之二氧化矽纖維構成之低表面能粗糙.....90 4-4以電紡絲法製備之二氧化矽超滑表面……………….…92 4-4-1 以不同平均粗細二氧化矽纖維構成之超滑表面………..92 4-4-2 不同平均粗細二氧化矽纖維製備之超滑表面在水流沖刷下其穩定性之比較…………………………………….…………………………..93 4-5粒子與纖維構成之超滑表面之耐沖刷性比較……………………95 第五章 結論…………………………………………………………….97 第六章 未來展望…………………………………………………….100 6-1 二氧化矽纖維表面含未水解氧烷基之解決方法…………….…100 6-2 超滑表面應用於靜電集塵器之測試……..…………………..…101 參考文獻……………………………………………………………104

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