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研究生: 王宣棫
Wang, Hsuan-Yu
論文名稱: TFT-LCD廢玻璃應用於營建板材之可行性研究
Feasibility of Using TFT-LCD Waste Glass as a Raw Material in the Production of Construction Panels.
指導教授: 黃忠信
Huang, Jong-Shin
學位類別: 碩士
Master
系所名稱: 工學院 - 土木工程學系
Department of Civil Engineering
論文出版年: 2018
畢業學年度: 106
語文別: 中文
論文頁數: 87
中文關鍵詞: TFT-LCD廢玻璃鹼激發無機聚合纖維水泥板高溫蒸壓養護
外文關鍵詞: TFT-LCD waste glass, alkali-activation, inorganic binder, fiber-reinforced construction panels, autoclave pressure
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  • 由於鹼激發膠結材屬常溫製造之無機聚合物,其原料與製程具低耗能、低汙染之優點,可取代傳統高耗能且高二氧化碳排放量之卜特蘭水泥膠結材,凡富含矽鋁質之天然礦物、工業副產品或廢棄物等,皆可能作為製造鹼激發膠結材之原料。其中,高科技產業TFT-LCD廢玻璃即為一含有高量SiO2之廢棄物,本研究嘗試將TFT-LCD廢玻璃作為鹼激發膠結材之原料,以取代現有營建板材製程中所使用之卜特蘭水泥,期能開發TFT-LCD廢玻璃資源化再利用之另一途徑,同時,降低營建板材之原料成本。
    常見營建板材中之纖維水泥板,乃是採用抄造及高溫蒸壓養護等特殊製程製成,因此,本研究採用常溫拌合廢玻璃粉體與鹼活化劑,搭配高溫養護或高溫蒸壓養護方式,製作鹼激發TFT-LCD廢玻璃膠結材試體,模擬並評估鹼激發廢玻璃膠結材,應用於現有纖維水泥板製程中之適用性。另外,本研究採用造紙廢紙渣與木纖維兩種廢棄纖維,將其分別添加於廢玻璃膠結材試體中,藉由試驗結果探討其對膠結材試體之增韌效果,期能獲得一低成本但功能佳之纖維物料,以取代現有纖維水泥板中之高成本外國進口纖維,進一步達到降低營建板材生產成本及廢棄物再利用之雙重目的。

    With the characteristics of low energy consumption process and environmental friendly raw materials, alkali-activated inorganic binders are made at room temperature and could be utilized to replace commercially available Portland cement binders, whose manufacturing results in high energy consumption and carbon dioxide emission. Natural minerals, industrial by-products or waste solids containing huge amounts of alumino-silicate can be used as a raw material in the production of alkali-activated inorganic binders. TFT-LCD glass with a high concentration of silicon dioxide, collected from high-technology industry, is treated as a solid waste in Taiwan. In the study, the feasibility of using TFT-LCD waste glass as a raw material in the production of alkali-activated inorganic binders and construction panels was evaluated. As expected, TFT-LCD waste glass can be reused as a raw material and the resulting alkali-activated TFT-LCD binders can be employed as a replacement for the Portland cement binders in fiber-reinforced construction panels.
    Fiber-reinforced construction panels are commonly produced by using a curing process of high temperature and saturated vapor pressure. Here, TFT-LCD waste glass powders were alkali-activated by mixing with an alkaline activator under a process of high temperature and high autoclave curing pressure to produce alkali-activated TFT-LCD inorganic binders and fiber-reinforced construction panels. The effects of alkaline activator, temperature and autoclave pressure on the properties of binders and construction panels were also investigated. In addition, the fibers added in fiber-reinforced construction panels are imported and very expensive. Hence, locally-available waste-paper fibers and wood fibers were introduced in the production of alkali-activated TFT-LCD inorganic binders and fiber-reinforced construction panels to reduce their cost. The enhancement of their toughness was studied by conducting a series of testing. Consequently, a locally available fiber for the replacement of the expensive imported fiber is proposed.

    摘要 I 誌謝 XIV 目錄 XVII 表目錄 XX 圖目錄 XXI 第一章 緒論 1 1.1 研究動機 1 1.2 研究目的 3 1.3 本文組織與內容 5 第二章 文獻回顧 7 2.1 廢玻璃現況 7 2.1.1 TFT-LCD廢玻璃 8 2.1.1.1 TFT-LCD廢玻璃之回收處理 9 2.1.1.2 TFT-LCD廢玻璃之再利用途徑 10 2.2 玻璃材料 11 2.2.1玻璃之成分與結構 11 2.2.2玻璃之侵蝕與縮聚 12 2.3 鹼激發膠結材 15 2.3.1 鹼激發膠結材之原理與發展 15 2.3.2 無機聚合物 16 2.3.3鹼激發膠結材之影響因素 18 2.4 鹼激發玻璃膠結材 22 2.4.1鹼激發玻璃膠結材之現況 22 2.4.2高溫蒸壓養護條件下之鹼激發玻璃膠結材 23 2.5 纖維水泥板 25 2.5.1 纖維水泥板之發展與種類 25 2.5.2 有機纖維水泥板之原料與製作 27 第三章 研究方法與試驗步驟 37 3.1 試驗規劃 37 3.2 試驗材料及儀器設備 38 3.2.1 試驗材料 38 3.2.2 試驗儀器設備 39 3.3 試驗變數與規劃 41 3.3.1 試驗變數定義 41 3.3.2試驗變數規劃 42 3.3.2.1高溫養護之變數規劃 43 3.3.2.2高溫蒸壓養護之變數規劃 43 3.3.3添加纖維之鹼激發玻璃膠結材變數規劃 44 3.4 試體製作 45 3.4.1 高溫養護之鹼激發膠結材 45 3.4.2 高溫蒸壓養護之鹼激發膠結材 47 3.4.3 添加纖維之鹼激發膠結材 48 3.5 試驗方法 48 3.5.1玻璃粉末材料試驗 48 3.5.2抗壓強度試驗 50 第四章 試驗結果與討論 57 4.1 高溫養護之鹼激發玻璃膠結材 57 4.1.1鹼當量對抗壓強度之影響 57 4.1.2養護時間對抗壓強度之影響 59 4.2高溫蒸壓養護下之鹼激發玻璃膠結材 60 4.2.1鹼當量對抗壓強度之影響 60 4.2.2養護時間對抗壓強度之影響 61 4.3 養護方式綜合比較 62 4.4 纖維種類及添加量對強度及工作性之影響 63 第五章 結論與建議 77 5.1 結論 77 5.2 建議 79 參考文獻 81  

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