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研究生: 廖桓儀
Liao, Huan-I
論文名稱: 氧化鈰與氧化鉻共同添加鍶鋇鈮陶瓷之結構與燒結行為
Structure and Sintering Behavior of Ceria and Chromia Co-Doped Strontium Barium Niobate Ceramics
指導教授: 方滄澤
Fang, Tsang-Tse
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2007
畢業學年度: 95
語文別: 中文
論文頁數: 139
中文關鍵詞: 燒結行為陶瓷鍶鋇鈮
外文關鍵詞: Structure and Sintering Behavior, SBN, Strontium Barium Niobate
相關次數: 點閱:86下載:2
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  • 在光電材料中,鍶鋇鈮單晶因其具有很高的線性光電係數、高的焦電係數以及良好的光折射效應 (photorefractive effect) ,故已有部分應用在工業上。儘管鍶鋇鈮單晶的成長技術及其性質已廣泛被研究,但因價格與製造上的困難故應用上有其限制所在,因此開發鍶鋇鈮多晶陶瓷乃必然趨勢。
    本實驗在鍶鋇鈮陶瓷中共添加Ce2O3、Cr2O3,探討其燒結行為及顯微結構。在單獨添加Ce2O3時,由於Ce離子取代部分Sr、Ba離子占據在A位置,產生電荷補償機制為Nb離子空缺,因此使得緻密化速率上升。然而共添加Ce2O3、Cr2O3 時,緻密化速率先在0.5%添加量時快速上升,而後隨著添加量下降。顯微結構方面在單獨添加Ce2O3時產生嚴重的異常晶粒成長,而在共同添加後晶粒成長的現象被抑制了。

    In photoelectric materials,strontium barium niobate ( SBN ) ceramic has very high linear electro-optical coefficient、 high pyroelectric coefficient and good photorefractive effect. Though the properties of the single crystal,SBN, has been intensively studied, high cost and difficult fabrication have limited its practical use. Hence,it is necessary to develop strontium barium niobate ceramic.

    SBN co-doped Ce2O3 、Cr2O3 is investigated into the sintering behavior and the microstructure. SBN doped Ce2O3 produces the charge compensation due to the Ce ions which replace a part of Sr、Ba ions in the B site. The charge compensation defect is Nb ion vacancy and cause the densification rate increasing .When SBN co-doped Ce2O3 、Cr2O3, the densification rate is increased at 0.5 mole% additive and decreased with more additive. Discontinuous grain growth occurs when SBN only doped Ce2O3 ,and grain growth is inhibited when SBN co-doped Ce2O3 、Cr2O3 .

    目錄 中文摘要.................................................Ⅰ 英文摘要.................................................Ⅱ 致謝....................................................III 目錄......................................................i 表目錄...................................................iv 圖目錄....................................................v 第一章 緒論 ...............................................1 1-1 前言............................................... 1 1-2 研究目的........................................... 2 第二章 文獻回顧與理論基礎.................................3 2-1 陶瓷製程與燒結......................................3 2-1-1 粉末顆粒大小對於生胚結構的影響..................3 2-1-2 燒結............................................8 2-1-3反應燒結........................................16 2-1-4擴散性相變化(Diffuse phase transition, DPT)......18 2-2鍶鋇鈮結構..........................................21 2-3 SBN的陶瓷製程......................................28 2-3-1 SBN合成機構....................................30 2-3-2 SN與BN合成SBN的反應機構模型. ................31 2-4 SBN性質............................................33 2-4-1 SBN介電性質....................................33 2-4-2 SBN光學性質....................................43 2-5 SBN燒結行為........................................46 2-5-1 SBN單相燒結行為................................46 2-5-2 SBN單相燒結之顯微結構演進與控制................54 2-6 SBN單純添加Cr之性質...... .........................59 2-6-1電荷補償缺陷(charge-compensated defect) .........59 2-6-2單相燒結行為和顯微結構...... ...................62 第三章 實驗方法及步驟....................................66 3-1實驗藥品............................................66 3-2製備粉末與試片......................................66 3-3性質的量測..........................................68 3-3-1 X光繞射分析....................................68 3-3-2密度量測........................................68 3-3-3 SEM顯微結構觀察................................69 3-4 膨脹儀數據分析.....................................70 3-4-1緻密化速率計算..................................70 3-4-2燒結活化能計算..................................72 第四章 結果與討論........................................74 4-1 SBN單純添加Ce之性質................................74 4-1-1單相燒結行為與電荷補償缺陷......................74 4-1-2顯微結構........................................94 4-2 SBN共同添加Ce,Cr之性質.............................99 4-2-1單相燒結行為....................................99 4-2-2電荷補償缺陷與結構分析.........................119 4-2-2顯微結構............ ..........................121 4-3燒結活化能與晶格常數之關係.........................127 第五章 結論.............................................128 參考文獻 .............................................130

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